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公开(公告)号:ES2051973T3
公开(公告)日:1994-07-01
申请号:ES89122748
申请日:1989-12-09
Applicant: BASF AG
Inventor: HARTMANN HEINRICH DR , DENZINGER WALTER , KROENER MICHAEL DR , SENDHOFF NORBERT DR , FREUDENBERG ENRIQUE DR
Abstract: Process for preparing stable water-in-oil emulsions of hydrolysed polymers of N-vinylamides of the formula in which R and R denote H or C1-C6-alkyl, by polymerising compounds of the formula I, alone or mixed with other monoethylenically unsaturated monomers, in the form of water-in-oil emulsions to give water-in-oil polymer emulsions, and subsequently hydrolysing the polymers, the hydrolysis of the polymers in the form of water-in-oil polymer emulsions being carried out in the presence of acids or bases and from 1 to 30% by weight, based on the polymers, of emulsifiers which are obtainable by reacting (A) C10- to C22-fatty alcohols with epichlorohydrin in the molar ratio 1:0.5 to 1:1.5 to give glycidyl ethers, (B) reacting the glycidyl ethers with (1) saturated C2- to C6-alcohols containing 2 to 6 OH groups or (2) monoethers thereof with C10- to C22-fatty alcohols, in the glycidyl ether:(1) or (2) molar ratio of from 1:0.5 to 6, in the presence of acids or bases, and (C) alkoxylating the reaction products from (B) using at least one C2- to C4-alkylene oxide in the molar ratio 1:1 to 6. The polymer emulsions obtainable in this way are used as dewatering, retention and flocculating agents in the production of paper and paper products.
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公开(公告)号:DE58907576D1
公开(公告)日:1994-06-01
申请号:DE58907576
申请日:1989-12-09
Applicant: BASF AG
Inventor: HARTMANN HEINRICH DR , DENZINGER WALTER , KROENER MICHAEL DR , SENDHOFF NORBERT DR , FREUDENBERG ENRIQUE DR
Abstract: Process for preparing stable water-in-oil emulsions of hydrolysed polymers of N-vinylamides of the formula in which R and R denote H or C1-C6-alkyl, by polymerising compounds of the formula I, alone or mixed with other monoethylenically unsaturated monomers, in the form of water-in-oil emulsions to give water-in-oil polymer emulsions, and subsequently hydrolysing the polymers, the hydrolysis of the polymers in the form of water-in-oil polymer emulsions being carried out in the presence of acids or bases and from 1 to 30% by weight, based on the polymers, of emulsifiers which are obtainable by reacting (A) C10- to C22-fatty alcohols with epichlorohydrin in the molar ratio 1:0.5 to 1:1.5 to give glycidyl ethers, (B) reacting the glycidyl ethers with (1) saturated C2- to C6-alcohols containing 2 to 6 OH groups or (2) monoethers thereof with C10- to C22-fatty alcohols, in the glycidyl ether:(1) or (2) molar ratio of from 1:0.5 to 6, in the presence of acids or bases, and (C) alkoxylating the reaction products from (B) using at least one C2- to C4-alkylene oxide in the molar ratio 1:1 to 6. The polymer emulsions obtainable in this way are used as dewatering, retention and flocculating agents in the production of paper and paper products.
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公开(公告)号:DE59005019D1
公开(公告)日:1994-04-21
申请号:DE59005019
申请日:1990-12-21
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE DR , LINHART FRIEDRICH DR , TRESCH RAINER , HARTMANN HEINRICH DR , DENZINGER WALTER , KROENER MICHAEL DR , SENDHOFF NORBERT DR
Abstract: In a process for making paper, paperboard and cardboard, paper pulps containing interfering materials are dehydrated in the presence of polymers which, as characteristic constituents, contain copolymerised units of the formulae … … with R and R = H or C1- to C3-alkyl, and have K values of at least 130, the polymers containing less than 10 mol% of units of formula II.
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公开(公告)号:DE4007311A1
公开(公告)日:1991-09-12
申请号:DE4007311
申请日:1990-03-08
Applicant: BASF AG
Inventor: HARTMANN HEINRICH DR , MOENCH DIETMAR DR , DENZINGER WALTER , KROENER MICHAEL DR , SENDHOFF NORBERT DR , FREUDENBERG ENRIQUE DR
Abstract: Hydrolysed polymers (I), in powder form, contg vinylamine units of formula are obtd by hydrolysing polymerisates (II) contg polymerised N-vinylformamide units as powder in inert suspending agent in presence of acid or base then isolating (I), water content of (II) at beginning of hydrolysis being 6-90 wt%. USE/ADVANTAGE - (I) particles, treated with finely divided inorganic solids, as dewatering, retention, or flocculating agent in mfr of paper (claimed). (II) particles are substantially homogenously hydrolysed, whereas in process of US4623699 hydrolysing agent diffuses only slowly into hard (II) particle, leaving core of unhydrolysed polyvinyl formamide, and (I) dissolve more rapidly in water.
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公开(公告)号:DE59504125D1
公开(公告)日:1998-12-10
申请号:DE59504125
申请日:1995-08-31
Applicant: BASF AG
Inventor: PENZEL ERICH DR , SEYFFER HERMANN DR , BECKMANN EBERHARD DR , SENDHOFF NORBERT DR
IPC: B05D7/24 , B65D65/40 , C08L67/00 , C08L67/02 , C09D133/20 , C09D167/00
Abstract: Prodn. of packaging material comprises coating a substrate with an aq. soln. or dispersion contg.: (A) a copolymerisate prepd. from: (a) 10-100 wt.% ethylenic 3-5C mono- or di-carboxylic acid, anhydride or hemi-ester; (b) 0-50 wt.% ethylenic cpd. contg. 1 or more sulphonic acid or sulphonate gps.; (c) 0-70 wt.% other monomers; and (B) a polyester; and opt. applying additional coating layers.
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公开(公告)号:DE4432080A1
公开(公告)日:1996-03-14
申请号:DE4432080
申请日:1994-09-09
Applicant: BASF AG
Inventor: PENZEL ERICH DR , SEYFFER HERMANN DR , BECKMANN EBERHARD DR , SENDHOFF NORBERT DR
IPC: B05D7/24 , B65D65/40 , C08L67/00 , C08L67/02 , C09D133/20 , C09D167/00 , B05D7/26 , B05D7/04 , B05D7/16 , D21H19/58 , D21H19/62 , B32B27/06 , B32B27/08 , B32B27/10 , B32B15/08
Abstract: Prodn. of packaging material comprises coating a substrate with an aq. soln. or dispersion contg.: (A) a copolymerisate prepd. from: (a) 10-100 wt.% ethylenic 3-5C mono- or di-carboxylic acid, anhydride or hemi-ester; (b) 0-50 wt.% ethylenic cpd. contg. 1 or more sulphonic acid or sulphonate gps.; (c) 0-70 wt.% other monomers; and (B) a polyester; and opt. applying additional coating layers.
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公开(公告)号:DE4131338A1
公开(公告)日:1993-03-25
申请号:DE4131338
申请日:1991-09-20
Applicant: BASF AG
Inventor: WIRTH THOMAS DR , SCHOEPKE HOLGER DR , SENDHOFF NORBERT DR , SEYFFER HERMANN DR
IPC: C08F283/02 , D02H5/02 , D06M13/02 , D06M13/244 , D06M13/248 , D06M13/272 , D06M15/263 , D06M15/507
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公开(公告)号:DE4002065A1
公开(公告)日:1991-08-01
申请号:DE4002065
申请日:1990-01-25
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE DR , LINHART FRIEDRICH DR , TRESCH RAINER , HARTMANN HEINRICH DR , DENZINGER WALTER , KROENER MICHAEL DR , SENDHOFF NORBERT DR
Abstract: In a process for making paper, paperboard and cardboard, paper pulps containing interfering materials are dehydrated in the presence of polymers which, as characteristic constituents, contain copolymerised units of the formulae … … with R and R = H or C1- to C3-alkyl, and have K values of at least 130, the polymers containing less than 10 mol% of units of formula II.
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公开(公告)号:DE3842820A1
公开(公告)日:1990-06-28
申请号:DE3842820
申请日:1988-12-20
Applicant: BASF AG
Inventor: HARTMANN HEINRICH DR , DENZINGER WALTER , KROENER MICHAEL DR , SENDHOFF NORBERT DR , FREUDENBERG ENRIQUE DR
Abstract: Process for preparing stable water-in-oil emulsions of hydrolysed polymers of N-vinylamides of the formula in which R and R denote H or C1-C6-alkyl, by polymerising compounds of the formula I, alone or mixed with other monoethylenically unsaturated monomers, in the form of water-in-oil emulsions to give water-in-oil polymer emulsions, and subsequently hydrolysing the polymers, the hydrolysis of the polymers in the form of water-in-oil polymer emulsions being carried out in the presence of acids or bases and from 1 to 30% by weight, based on the polymers, of emulsifiers which are obtainable by reacting (A) C10- to C22-fatty alcohols with epichlorohydrin in the molar ratio 1:0.5 to 1:1.5 to give glycidyl ethers, (B) reacting the glycidyl ethers with (1) saturated C2- to C6-alcohols containing 2 to 6 OH groups or (2) monoethers thereof with C10- to C22-fatty alcohols, in the glycidyl ether:(1) or (2) molar ratio of from 1:0.5 to 6, in the presence of acids or bases, and (C) alkoxylating the reaction products from (B) using at least one C2- to C4-alkylene oxide in the molar ratio 1:1 to 6. The polymer emulsions obtainable in this way are used as dewatering, retention and flocculating agents in the production of paper and paper products.
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10.
公开(公告)号:DE19533218A1
公开(公告)日:1997-03-13
申请号:DE19533218
申请日:1995-09-08
Applicant: BASF AG
Inventor: HAEBERLE KARL DR , FUCHS HORST , REICHERT JUERGEN DR , SENDHOFF NORBERT DR , LEITNER HEINZ
IPC: C08G18/08 , C08G18/80 , D06M15/263 , D06M15/333 , D06M15/507 , D06M15/564 , D06M15/568 , D06P1/00 , D06P1/22 , D06P1/52 , D06P1/54 , D06P3/60 , D06P3/85
Abstract: The claims concern the use of hydrophilic modified polyisocyanates (I) in combination with (a) sizes (II) cured with (I) for producing permanently sized yarns and (b) (II) and indigo for 1-stage sizing and dyeing of yarns or dyeing and printing of fabrics.
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