公开(公告)号：WO03006528A8

公开(公告)日：2004-04-08

申请号：PCT/EP0207409

申请日：2002-07-04

Applicant: BASF AG ,  SCHMID MARKUS ,  CHOWDHRY MUBARIK MAHMOOD ,  KRISTEN MARC OLIVER ,  MECKING STEFAN ,  HELD ANKE ,  LINDNER EKKEHARD ,  SUNJUK MAHMOUD ,  WEGNER PETER

Inventor： SCHMID MARKUS ,  CHOWDHRY MUBARIK MAHMOOD ,  KRISTEN MARC OLIVER ,  MECKING STEFAN ,  HELD ANKE ,  LINDNER EKKEHARD ,  SUNJUK MAHMOUD ,  WEGNER PETER

IPC: C09K3/10 ,  B01J31/18 ,  B01J31/24 ,  C08G67/02 ,  C09D173/00 ,  C09J173/00

CPC classification number: B01J31/1815 ,  B01J31/18 ,  B01J31/24 ,  B01J2531/10 ,  B01J2531/20 ,  B01J2531/80 ,  B01J2531/824 ,  C08G67/02

Abstract: The invention relates to a method for producing aqueous copolymer dispersions of copolymers consisting of carbon monoxide and olefinically unsaturated compounds, by means of copolymerisation of carbon monoxide and olefinically unsaturated compounds in an aqueous medium in the presence of metallic complexes.

Abstract translation: 一种用于在金属配合物存在下，在水性介质中的一氧化碳和烯属不饱和化合物的共聚制备一氧化碳的共聚物，以及烯属不饱和化合物的水性共聚物分散体的过程。

公开(公告)号：DE10133042A1

公开(公告)日：2003-01-23

申请号：DE10133042

申请日：2001-07-11

Applicant: BASF AG

Inventor： SCHMID MARKUS ,  CHOWDHRY MUBARIK ,  KRISTEN MARK OLIVER ,  MECKING STEFAN ,  HELD ANKE ,  LINDNER EKKEHARD ,  SUNJUK MAHMOUD ,  WEGNER PETER

IPC: C09K3/10 ,  B01J31/18 ,  B01J31/24 ,  C08G67/02 ,  C09D173/00 ,  C09J173/00 ,  C09D5/02 ,  C08J3/02

Abstract: A process for preparation of aqueous copolymerizate dispersions from copolymerizates of carbon monoxide and olefinically unsaturated compounds by copolymerization of carbon monoxide and the olefinically unsaturated compounds in aqueous medium in the presence of metal complexes. A process for preparation of aqueous copolymerizate dispersions from copolymerizates of carbon monoxide and olefinically unsaturated compounds by copolymerization of carbon monoxide and the olefinically unsaturated compounds in aqueous medium in the presence of:- (a) metal complexes of formula (I), (b) a dispersion agent and optionally (c) a slightly water-soluble organic solvent. G = -(CRb2)r-, -(CRb2)s-Si(Ra)2-(CRb2)t-, -A-O-B- or -A-Z'(R )-B-; R = H, 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl, with functional groups based on groups IVA, VA or VIIA non-metallic elements, substituted 6-14C aryl, aralkyl with 1-20C alkyl and 6-14C aryl parts, heteroaryl, a long chain 5-30C residue, which has polar or charged end groups -N(Rb)2 and -Si(Rc)3 available, or a residue of formula (II) q = 0-20; A, B = an r'-, s-, or t-atomic component of a ring system, or, together with Z', a (r'+1)-, (s+1)- or (t+1)-atomic component of a heteroring; Ra = 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl, with functional groups based on groups IVA, VA or VIIA non-metallic elements, substituted 6-14C aryl, or aralkyl with 1-20C in the alkyl part and 6-14C in the aryl part; Rb = as Ra, and additionally H and -Si(Rc)3; Rc = 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl, or aralkyl with 1-20C in the alkyl part and 6-14C in the aryl part; r = 1-4; r' = 1 or 2; s, t = 0-2 provided that 1 , E = a non-metallic element from group VA; R -R = 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl with functional groups based on groups IVA, VA or VIA, or VIIA non-metallic elements, substituted 6-14C aryl, aralkyl with 1-20C alkyl in the alkyl part and 6-14C in the aryl part, or heteroaryl; L , L = formally charged or neutral ligands; X = mono- or multivalent anion; p, m, n = 0-4 and p = m \* n or a compound of formula (III) Rd-Rg = H or optionally branched 1-6C alkyl, or Re and Rf together = a 5- or 6-membered carbocyclic or hetero ring. The metal complex (a) is partially or wholly dissolved in the total amount of the olefinically unsaturated compounds and/or the organic solvent (c). Part or all of the olefinically unsaturated compounds and/or the organic solvent (c), in which the metal complex is dissolved , are present in the aqueous medium as disperse phase, with a mean drop diameter of

公开(公告)号：BR0210963A

公开(公告)日：2004-06-08

申请号：BR0210963

申请日：2002-07-04

Applicant: BASF AG

Inventor： SCHMID MARKUS ,  CHOWDHRY MUBARIK MAHMOOD ,  KRISTEN MARC OLIVER ,  MECKING STEFAN ,  HELD ANKE ,  LINDNER EKKEHRAD ,  SUNJUK MAHMOUD ,  WEGNER PETER

IPC: C09K3/10 ,  B01J31/18 ,  B01J31/24 ,  C08G67/02 ,  C09D173/00 ,  C09J173/00

Abstract: A process for preparation of aqueous copolymerizate dispersions from copolymerizates of carbon monoxide and olefinically unsaturated compounds by copolymerization of carbon monoxide and the olefinically unsaturated compounds in aqueous medium in the presence of metal complexes. A process for preparation of aqueous copolymerizate dispersions from copolymerizates of carbon monoxide and olefinically unsaturated compounds by copolymerization of carbon monoxide and the olefinically unsaturated compounds in aqueous medium in the presence of:- (a) metal complexes of formula (I), (b) a dispersion agent and optionally (c) a slightly water-soluble organic solvent. G = -(CRb2)r-, -(CRb2)s-Si(Ra)2-(CRb2)t-, -A-O-B- or -A-Z'(R )-B-; R = H, 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl, with functional groups based on groups IVA, VA or VIIA non-metallic elements, substituted 6-14C aryl, aralkyl with 1-20C alkyl and 6-14C aryl parts, heteroaryl, a long chain 5-30C residue, which has polar or charged end groups -N(Rb)2 and -Si(Rc)3 available, or a residue of formula (II) q = 0-20; A, B = an r'-, s-, or t-atomic component of a ring system, or, together with Z', a (r'+1)-, (s+1)- or (t+1)-atomic component of a heteroring; Ra = 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl, with functional groups based on groups IVA, VA or VIIA non-metallic elements, substituted 6-14C aryl, or aralkyl with 1-20C in the alkyl part and 6-14C in the aryl part; Rb = as Ra, and additionally H and -Si(Rc)3; Rc = 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl, or aralkyl with 1-20C in the alkyl part and 6-14C in the aryl part; r = 1-4; r' = 1 or 2; s, t = 0-2 provided that 1 , E = a non-metallic element from group VA; R -R = 1-20C alkyl, 3-10C cycloalkyl, 6-14C aryl with functional groups based on groups IVA, VA or VIA, or VIIA non-metallic elements, substituted 6-14C aryl, aralkyl with 1-20C alkyl in the alkyl part and 6-14C in the aryl part, or heteroaryl; L , L = formally charged or neutral ligands; X = mono- or multivalent anion; p, m, n = 0-4 and p = m \* n or a compound of formula (III) Rd-Rg = H or optionally branched 1-6C alkyl, or Re and Rf together = a 5- or 6-membered carbocyclic or hetero ring. The metal complex (a) is partially or wholly dissolved in the total amount of the olefinically unsaturated compounds and/or the organic solvent (c). Part or all of the olefinically unsaturated compounds and/or the organic solvent (c), in which the metal complex is dissolved , are present in the aqueous medium as disperse phase, with a mean drop diameter of

公开(公告)号：DE10322466A1

公开(公告)日：2004-12-02

申请号：DE10322466

申请日：2003-05-16

Applicant: BASF AG

Inventor： SCHMID MARKUS ,  CHOWDHRY MUBARIK MAHMOOD ,  PREISHUBER-PFLUEGL PETER ,  SAVA XAVIER ,  LINDNER EKKEHARD ,  SUNJUK MAHMOUD ,  WEGNER PETER

IPC: C08F10/00 ,  C08F110/06 ,  C08F2/08 ,  C08G67/02 ,  C08F4/00

Abstract: Process for preparing an aqueous polymer dispersion by polymerization of at least one olefinically unsaturated compound in an aqueous medium in the presence of at least one dispersant and a solid polymerization catalyst.