公开(公告)号：WO2007131948A3

公开(公告)日：2008-02-07

申请号：PCT/EP2007054554

申请日：2007-05-11

Applicant: BASF AG ,  PUETTER HERMANN ,  SCHUBERT MARKUS ,  RICHTER INGO ,  MUELLER ULRICH ,  TRUKHAN NATALIA

Inventor： PUETTER HERMANN ,  SCHUBERT MARKUS ,  RICHTER INGO ,  MUELLER ULRICH ,  TRUKHAN NATALIA

IPC: C25B3/12

CPC classification number: C25B3/12

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

Abstract translation: 本发明涉及一种用于制备包含配位的至少两个的至少一种金属有机化合物，包括（a）氧化中的至少一种的存在下相应的含有金属的阳极中的反应介质中的至少一种金属离子的至少之一中的步骤的多孔金属有机骨架 第一有机化合物，其中所述第一有机化合物和任选取代的单 - ，双 - 或多环饱和或未饱和烃基，其中至少两个环碳原子被选自下组的杂原子取代由选自N，O和S的取代， 形成所述至少一个金属离子和第一含有机化合物的中间体反应产物; 和（b）反应，该反应与至少其协调结合到所述至少一种金属离子，其中，二，三或四羧酸的第二有机化合物导出的第二有机化合物中间体在设定温度。

公开(公告)号：CA2651948A1

公开(公告)日：2007-11-22

申请号：CA2651948

申请日：2007-05-11

Applicant: BASF AG

Inventor： PUETTER HERMANN ,  TRUKHAN NATALIA ,  MUELLER ULRICH ,  RICHTER INGO ,  SCHUBERT MARKUS

IPC: C25B3/13

Abstract: The present invention relates to a process for preparing a porous metal o rganic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least on e anode containing metal corresponding to the at least one metal ion in a re action medium in the presence of at least a first organic compound, where th e first organic compound is an optionally substituted monocyclic, bicyclic o r polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N , O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermedia te at a prescribed temperature with an at least second organic compound whic h coordinates to the at least one metal ion, where the second organic compou nd is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

公开(公告)号：CA2648145A1

公开(公告)日：2007-10-25

申请号：CA2648145

申请日：2007-04-12

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  TRUKHAN NATALIA ,  SCHUBERT MARKUS

IPC: C01G1/02 ,  C01F5/02 ,  C01F7/02 ,  C01F7/30 ,  C01G23/053 ,  C01G25/02 ,  C04B35/04 ,  C04B35/053 ,  C04B35/10 ,  C04B35/111 ,  C04B35/48 ,  C04B35/486 ,  C04B38/00

Abstract: The present invention relates to a method for producing a metal oxide by heating a porous metal-organic framework material, the framework material comprising at least one at least bidentate organic compound bound to at least one metal ion by coordination, and the metal ion being selected from the metals comprising groups 2 to 4 and 13 of the Periodic Table of the Elements, above the complete decomposition temperature of the framework material, and also to metal oxides obtainable by this method, and to the use thereof.