公开(公告)号：WO2007131948A3

公开(公告)日：2008-02-07

申请号：PCT/EP2007054554

申请日：2007-05-11

Applicant: BASF AG ,  PUETTER HERMANN ,  SCHUBERT MARKUS ,  RICHTER INGO ,  MUELLER ULRICH ,  TRUKHAN NATALIA

Inventor： PUETTER HERMANN ,  SCHUBERT MARKUS ,  RICHTER INGO ,  MUELLER ULRICH ,  TRUKHAN NATALIA

IPC: C25B3/12

CPC classification number: C25B3/12

Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

Abstract translation: 本发明涉及一种用于制备包含配位的至少两个的至少一种金属有机化合物，包括（a）氧化中的至少一种的存在下相应的含有金属的阳极中的反应介质中的至少一种金属离子的至少之一中的步骤的多孔金属有机骨架 第一有机化合物，其中所述第一有机化合物和任选取代的单 - ，双 - 或多环饱和或未饱和烃基，其中至少两个环碳原子被选自下组的杂原子取代由选自N，O和S的取代， 形成所述至少一个金属离子和第一含有机化合物的中间体反应产物; 和（b）反应，该反应与至少其协调结合到所述至少一种金属离子，其中，二，三或四羧酸的第二有机化合物导出的第二有机化合物中间体在设定温度。

公开(公告)号：WO2004094439A3

公开(公告)日：2005-02-17

申请号：PCT/EP2004004045

申请日：2004-04-16

Applicant: BASF AG ,  MAASE MATTHIAS ,  GRIESBACH ULRICH ,  RICHTER INGO

Inventor： MAASE MATTHIAS ,  GRIESBACH ULRICH ,  RICHTER INGO

IPC: C07F9/28 ,  C07F9/50

CPC classification number: C07F9/28 ,  C07F9/5036

Abstract: The invention relates to the electrochemical production of mono-, bis- and trisacylphosphines and mono-,bis- and trisacylphosphinoxides.

Abstract translation: 电化学制备单 - 和二 - 和Trisacylphosphinen和单 - 和双和trisacylphosphine氧化物。

公开(公告)号：CA2617556A1

公开(公告)日：2007-02-08

申请号：CA2617556

申请日：2006-07-31

Applicant: BASF AG

Inventor： GERLACH TILL ,  RICHTER INGO ,  GRIESBACH ULRICH ,  PUETTER HERMANN

IPC: C25B3/23 ,  C07C41/50 ,  C07C43/303

Abstract: Process for preparing 1,1,4,4,-tetraalkoxybut-2-ene derivatives of the gener al formula (I), in which the radicals R1 and R2 independently of one another ar e hydrogen, C1 to C6 alkyl, C6 to C12 aryl such as phenyl, for example, or C5 to C12 cycloalkyl, or R1 and R2, together with the double bond to which they ar e attached, are a C6 to C12 aryl radical such as, for example, phenyl, phenyl substituted one or more times by C1 to C6 alkyl, by halogen or by alkoxy, or a mono- or poly-unsaturated C5 to C12 cycloalkyl radical, and R3 and R4 independently of one another are hydrogen, methyl, trifluoromethyl or nitril e, in which process 1,4-dialkoxy-1,3-butadienes of the formula (II), in which t he radicals R1, R3 and R4 are assigned the same definition as in formula (I), a re electrochemically oxidized in the presence of a C1 to C6 alkyl alcohol.

公开(公告)号：DE102005036687A1

公开(公告)日：2007-02-08

申请号：DE102005036687

申请日：2005-08-04

Applicant: BASF AG

Inventor： RICHTER INGO ,  PUETTER HERMANN ,  GRIESBACH ULRICH ,  GERLACH TILL

IPC: C25B3/23 ,  C07C43/303

Abstract: Process for preparing 1,1,4,4-tetraalkoxybut-2-ene derivatives of the general formula (I), where the radicals R 1 and R 2 are each, independently of one another, hydrogen, C 1 -C 6 -alkyl, C 6 -C 12 -aryl, such as phenyl, or C 5 -C 12 -cycloalkyl or R 1 and R 2 together with the double bond to which they are bound form a C 6 -C 12 -aryl radical, such as phenyl, a phenyl radical substituted by one or more C 1 -C 6 -alkyl groups, halogen atoms or alkoxy groups or a monounsaturated or polyunsaturated C 5 -C 12 -cycloalkyl radical, R 3 , R 4 are each, independently of one another, hydrogen, methyl, trifluoromethyl or nitrile, which comprises electrochemically oxidizing 1,4-dialkoxy-1,3-butadiene of the formula II where the radicals R 1 , R 3 and R 4 have the same meanings as in the formula I, in the presence of a C 1 -C 6 -alkyl alcohol.

公开(公告)号：DE102004035860A1

公开(公告)日：2006-02-16

申请号：DE102004035860

申请日：2004-07-23

Applicant: BASF AG

Inventor： RICHTER INGO ,  GRIESBACH ULRICH ,  BECKER MICHAEL ,  KESSINGER ROLAND

IPC: C25B3/23 ,  C07C43/305

Abstract: Preparation of 2-alkyne-1-acetal compounds (I) comprises electro-chemically oxidizing alcohol compounds (II) in the presence of 1-6C alkyl alcohol (A) or substance. Preparation of 2-alkyne-1-acetal compounds of formula (I) comprises electro-chemically oxidizing alcohol compounds (II) of formula (R 1>-C?=C-CH 2-OH) in the presence of 1-6C alkyl alcohol (A) or substance. R 1>1-20C alkyl, 2-20C alkenyl, 2-20C alkenyl, 3-12C cycloalkyl, 4-20C cycloalkyl-alkyl, 4-10C aryl (all optionally substituted with hydroxy, halo, 1-6C alkoxy, (1-6C alkoxy)-carbonyl, carboxyl or nitrile) or H; and R 2>, R 3>1-6C alkyl or a group of formula (R 1>-C?=C-CH 2-). [Image].

公开(公告)号：DE102004052041A1

公开(公告)日：2005-05-25

申请号：DE102004052041

申请日：2004-10-26

Applicant: BASF AG

Inventor： KLAS KATRIN ,  HEYDRICH GUNNAR ,  RICHTER INGO ,  HENKELMANN JOCHEM

IPC: C07C41/60 ,  C07C41/42 ,  C07C43/32

Abstract: Preparation of orthoformate esters (I) comprises reacting methyl orthoformate (II) and an alcohol (III) with at least 2 C atoms, in contact with a heterogeneous acidic catalyst (A). (A) is silicic acid; and aluminosilicate, or an oxide/mixed oxide of aluminum, zinc, zirconium and/or titanium.

公开(公告)号：CA2651948A1

公开(公告)日：2007-11-22

申请号：CA2651948

申请日：2007-05-11

Applicant: BASF AG

Inventor： PUETTER HERMANN ,  TRUKHAN NATALIA ,  MUELLER ULRICH ,  RICHTER INGO ,  SCHUBERT MARKUS

IPC: C25B3/13

Abstract: The present invention relates to a process for preparing a porous metal o rganic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least on e anode containing metal corresponding to the at least one metal ion in a re action medium in the presence of at least a first organic compound, where th e first organic compound is an optionally substituted monocyclic, bicyclic o r polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N , O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermedia te at a prescribed temperature with an at least second organic compound whic h coordinates to the at least one metal ion, where the second organic compou nd is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

公开(公告)号：CA2602077A1

公开(公告)日：2006-09-28

申请号：CA2602077

申请日：2006-03-23

Applicant: BASF AG

Inventor： RICHTER INGO ,  BOTTKE NILS ,  PUETTER HERMANN ,  GRIESBACH ULRICH

IPC: C07D307/32 ,  C07C41/50 ,  C07D307/88 ,  C07D307/89 ,  C25B3/23

Abstract: A process for the preparation of 2,5-dihydrofuran derivatives substituted in the 3- or 4-position, which in the 2- or in the 5-position or at both positions each carry a C 1 - to C 6 -alkoxy radical (DHF-alkoxy derivatives 1), or 1,1,4,4-tetraalkoxy-but-2-ene derivatives substituted in the 3- or 4-position, from 2-butene-1 ,4-diol derivatives of the general formula (I) in which the radicals R 1 and R 2 independently of one another are hydrogen, C 1 - to C 6 -alkyl, C 6 - to C 12 -aryl or C 5 - to C 12 -cycloalkylene or R 1 and R 2 , together with the double bond to which they are bonded, form a C 6 - to C 12 -aryl radical or a mono- or polyunsaturated C 5 - to C 12 -cycloalkyl radical, or from their mixture with 2,5-dihydrofuran derivatives substituted in the 3- position or 4-position, which in the 2- or in the 5-position carry a C 1 - to C 6 -alkoxy radical, by electro-chemical oxidation in the presence of a C 1 - to C 6 -monoalkyl alcohol.

公开(公告)号：DE10340738A1

公开(公告)日：2005-03-31

申请号：DE10340738

申请日：2003-09-04

Applicant: BASF AG

Inventor： HEYDRICH GUNNAR ,  RICHTER INGO ,  KRUG THOMAS

IPC: C07C29/80 ,  C07C41/50 ,  C07C41/58 ,  C07C43/303 ,  C07C45/71 ,  C07C45/82 ,  C07C27/26 ,  C07C43/30 ,  C07C47/37 ,  C07C31/04

Abstract: A process is proposed for distillatively working up an aqueous composition which comprises 1,1,2.2-tetramethoxyethane, glyoxal dimethyl acetal and methanol, wherein the workup of this composition is carried out in a dividing wall column to form low boiler, medium boiler and/or high boiler fractions, and a dividing wall is disposed in the longitudinal direction in the dividing wall column to form an upper common column region, a lower common column region, a feed section having rectifying section and stripping section and a withdrawal section having stripping section and rectifying section, and the aqueous composition is fed into the middle region of the feed section.

公开(公告)号：DE102005013631A1

公开(公告)日：2006-09-28

申请号：DE102005013631

申请日：2005-03-24

Applicant: BASF AG

Inventor： RICHTER INGO ,  PUETTER HERMANN ,  GRIESBACH ULRICH ,  BOTTKE NILS

IPC: C07D307/32 ,  C07D307/89 ,  C25B3/23

Abstract: A process for the preparation of 2,5-dihydrofuran derivatives substituted in the 3- or 4-position, which in the 2- or in the 5-position or at both positions each carry a C 1 - to C 6 -alkoxy radical (DHF-alkoxy derivatives 1), or 1,1,4,4-tetraalkoxy-but-2-ene derivatives substituted in the 3- or 4-position, from 2-butene-1 ,4-diol derivatives of the general formula (I) in which the radicals R 1 and R 2 independently of one another are hydrogen, C 1 - to C 6 -alkyl, C 6 - to C 12 -aryl or C 5 - to C 12 -cycloalkylene or R 1 and R 2 , together with the double bond to which they are bonded, form a C 6 - to C 12 -aryl radical or a mono- or polyunsaturated C 5 - to C 12 -cycloalkyl radical, or from their mixture with 2,5-dihydrofuran derivatives substituted in the 3- position or 4-position, which in the 2- or in the 5-position carry a C 1 - to C 6 -alkoxy radical, by electro-chemical oxidation in the presence of a C 1 - to C 6 -monoalkyl alcohol.