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    PREPARATIONOF BICYCLIC AMIDINE, DIAZACYCLOALKENE AND ITS PREPARATION
    1.
    发明专利
    PREPARATIONOF BICYCLIC AMIDINE, DIAZACYCLOALKENE AND ITS PREPARATION 失效

    公开(公告)号：JPH11228574A

    公开(公告)日：1999-08-24

    申请号：JP34004198

    申请日：1998-11-30

    Applicant: BASF AG

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER HEINZ-JOSEF DR ,  ELLER KARSTEN DR ,  WITZEL TOM DR

    IPC: C07D487/04 ,  C07D239/06 ,  C07D471/04

    Abstract: PROBLEM TO BE SOLVED: To produce the subject compound useful for the dehydrohalogenation of organic compounds or synthesis, etc., of polymers in high yield without requiring the use of an acidic catalyst by reacting a specific lactone with a specified diamine while removing water of reaction during the progress of the reaction. SOLUTION: A lactone represented by formula I [R and R are each H or the like; (m) is 2-12] (e.g. γ-butyrolactone) is reacted with a diamine represented by formula II [R and R are each H or the like; (n) is 2-12] (e.g. 1,3-diaminopropane), preferably in at least 1:1.5 initial molar ratio of the lactone to the diamine, preferably continuously over the total reactional time, preferably at 170-220 deg.C for 5-100 hr while eliminating water of reaction and preferably with the aid of an azeotropic agent to produce the objective compound represented by formula III e.g. 1,5-diazabicyclo[4.3.0]non-5-ene}.

    Production of beta-alkoxynitrile or gamma-alkoxyamine
    2.
    发明专利
    Production of beta-alkoxynitrile or gamma-alkoxyamine 审中-公开
    β-烷氧基硅烷或γ-羟基烷基胺的生产

    公开(公告)号：JPH11279135A

    公开(公告)日：1999-10-12

    申请号：JP1752499

    申请日：1999-01-26

    Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER HEINZ-JOSEF DR ,  ELLER KARSTEN DR ,  HENNE ANDREAS DR ,  LEBKUECHER ROLF DR

    IPC: B01J31/02 ,  C07B61/00 ,  C07C213/02 ,  C07C217/08 ,  C07C217/48 ,  C07C253/30 ,  C07C255/13 ,  C07C255/37

    CPC classification number: C07C213/02 ,  C07C253/30 ,  C07C217/08 ,  C07C217/48 ,  C07C255/13 ,  C07C255/37

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound by reaction between an α,β-unsaturated nitrile and an alcohol using a specific diazabicycloalkene as basic catalyst without the need of any prior separation or neutralization of the catalyst for the addition reaction.
    SOLUTION: This compound is obtained by reaction between an α,β-unsaturated nitrile (e.g. acrylonitrile) and a monohydric, dihydric or trihydric alcohol (e.g. methanol, ethanol, 2-ethylhexanol, 2-methoxyethanol, benzyl alcohol) at -20 to 200°C using a diazabicycloalkene of the formula (H may be substituted with a 1-20C alkyl, 6-20C aryl or 7-20C arylalkyl; (n) and (m) are each 1-6) as basic catalyst {e.g. 1,5-diazabicyclo[4.3.0]nonene-5(DBN), 1,8- diazabicyclo[5.4.0]undecene-7(DBU)}; wherein the amount of the catalyst to be used is pref. 0.05-5 wt.% based on the alcohol.
    COPYRIGHT: (C)1999,JPO

    Abstract translation: 要解决的问题：通过使用特定的二氮杂双环链烯烃作为碱性催化剂，通过α，β-不饱和腈和醇之间的反应获得目标化合物，而不需要任何预先分离或中和加成反应的催化剂。 溶液：该化合物通过α-β-不饱和腈（如丙烯腈）与一元二元或三元醇（如甲醇，乙醇，2-乙基己醇，2-甲氧基乙醇，苄醇）在-20〜200 （H可以被1-20C烷基，6-20C芳基或7-20C芳基烷基取代;（n）和（m）各自为1-6）作为碱性催化剂，例如 1,5-二氮杂双环[4.3.0]壬烯-5（DBN），1,8-二氮杂双环[5.4.0]十一碳烯-7（DBU）}; 其中所用的催化剂的量是优选的。 基于醇为0.05-5重量％。

    3.
    发明专利
    未知

    公开(公告)号：ES2185102T3

    公开(公告)日：2003-04-16

    申请号：ES98122408

    申请日：1998-11-26

    Applicant: BASF AG

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER HEINZ-JOSEF DR ,  ELLER KARSTEN DR ,  HENNE ANDREAS DR ,  LEBKUCHER ROLF DR

    IPC: B01J31/02 ,  C07B61/00 ,  C07C213/02 ,  C07C217/08 ,  C07C217/48 ,  C07C253/30 ,  C07C255/13 ,  C07C255/37

    Abstract: A process for the production of beta -alkoxy-nitriles which is carried out in the presence of a basic diazabicycloalkene catalyst. Production of beta -alkoxy-nitriles which involves reaction of alpha , beta -unsaturated nitriles with mono-, di- or tri- valent alcohols in the presence of a basic diazabicycloalkene of formula (1), at (-) 20-200 degrees C. n, m = 1-6; and where the 1-4 H atoms are optionally substituted by R -R ; R -R = 1-20C alkyl, 6-20C aryl or 7-20C arylalkyl. An Independent claim is also included for a production process of a gamma -alkoxy-amine by hydrogenation of the beta -alkoxy-nitrile in the presence of a hydrogenation catalyst and the catalyst of formula (1).

    4.
    发明专利
    未知

    公开(公告)号：DE19752935A1

    公开(公告)日：1999-06-02

    申请号：DE19752935

    申请日：1997-11-28

    Applicant: BASF AG

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER HEINZ-JOSEF DR ,  ELLER KARSTEN DR ,  WITZEL TOM DR

    IPC: C07D487/04 ,  C07D239/06 ,  C07D471/04

    Abstract: Preparation of bicyclic amidine derivatives with continual removal of water during reaction. Bicyclic amidine derivatives of formula (1) are prepared by reacting a lactone of formula (2) with a diamine of formula (3), during which water is removed while the reaction is taking place. Rx, Ry, Ra, Rb = independently H, or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl or 6-12C aryl, optionally substituted by OH, NH2, 1-4C alkylamino or SH; m, n = 2-12; a, b, x and y actually = number of carbon atoms in the R groups, which correspond to values of n+1 or m+1. Independent claims are also included for the following: (I) A diazacycloalkane of formula (4); (II) Preparation of diazacycloalkane (4); and (III) Use of diazacycloalkane (4) as an intermediate in production of bicyclic amines of formula (1). Rx, Ry, Ra, Rb = independently H, or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl or 6-12C aryl, optionally substituted by OH, NH2, 1-4C alkylamino or SH; m, n = 2-12; a, b, x and y actually = number of carbon atoms in the R groups, which correspond to values of n+1 or m+1.

    7.
    发明专利
    未知

    公开(公告)号：DE59804038D1

    公开(公告)日：2002-06-13

    申请号：DE59804038

    申请日：1998-11-24

    Applicant: BASF AG

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER DR ,  ELLER DR ,  WITZEL DR

    IPC: C07D487/04 ,  C07D239/06 ,  C07D471/04

    Abstract: Preparation of bicyclic amidine derivatives with continual removal of water during reaction. Bicyclic amidine derivatives of formula (1) are prepared by reacting a lactone of formula (2) with a diamine of formula (3), during which water is removed while the reaction is taking place. Rx, Ry, Ra, Rb = independently H, or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl or 6-12C aryl, optionally substituted by OH, NH2, 1-4C alkylamino or SH; m, n = 2-12; a, b, x and y actually = number of carbon atoms in the R groups, which correspond to values of n+1 or m+1. Independent claims are also included for the following: (I) A diazacycloalkane of formula (4); (II) Preparation of diazacycloalkane (4); and (III) Use of diazacycloalkane (4) as an intermediate in production of bicyclic amines of formula (1). Rx, Ry, Ra, Rb = independently H, or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl or 6-12C aryl, optionally substituted by OH, NH2, 1-4C alkylamino or SH; m, n = 2-12; a, b, x and y actually = number of carbon atoms in the R groups, which correspond to values of n+1 or m+1.

    9.
    发明专利
    未知

    公开(公告)号：DE59805686D1

    公开(公告)日：2002-10-31

    申请号：DE59805686

    申请日：1998-11-26

    Applicant: BASF AG

    Inventor： FRIEDRICH WOLFGANG ,  KNEUPER HEINZ-JOSEF DR ,  ELLER KARSTEN DR ,  HENNE ANDREAS DR ,  LEBKUECHER ROLF DR

    IPC: B01J31/02 ,  C07B61/00 ,  C07C213/02 ,  C07C217/08 ,  C07C217/48 ,  C07C253/30 ,  C07C255/13 ,  C07C255/37

    Abstract: A process for the production of beta -alkoxy-nitriles which is carried out in the presence of a basic diazabicycloalkene catalyst. Production of beta -alkoxy-nitriles which involves reaction of alpha , beta -unsaturated nitriles with mono-, di- or tri- valent alcohols in the presence of a basic diazabicycloalkene of formula (1), at (-) 20-200 degrees C. n, m = 1-6; and where the 1-4 H atoms are optionally substituted by R -R ; R -R = 1-20C alkyl, 6-20C aryl or 7-20C arylalkyl. An Independent claim is also included for a production process of a gamma -alkoxy-amine by hydrogenation of the beta -alkoxy-nitrile in the presence of a hydrogenation catalyst and the catalyst of formula (1).

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