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    3.
    发明专利
    未知

    公开(公告)号：DE102007052640A1

    公开(公告)日：2009-05-07

    申请号：DE102007052640

    申请日：2007-11-05

    Applicant: UNIV ALBERT LUDWIGS FREIBURG ,  BASF SE

    Inventor： RUDOLPH JENS ,  SCHMIDT-LEITHOFF JOACHIM ,  PACIELLO ROCCO ,  BREIT BERNHARD ,  SMEJKAL TOMAS

    IPC: C07B41/06 ,  B01J31/18 ,  C07C47/00 ,  C07C51/373 ,  C07C59/185 ,  C07F9/00 ,  C07F9/66 ,  C07F9/90 ,  C07F9/94

    Abstract: The present invention relates to a process for the hydroformylation of compounds of the formula (I), where X is C, P(Rx), P(O—Rx) S or S(═O), where Rx is H, alkyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl; A is a divalent bridging group having from 1 to 4 bridging atoms; and R1 is H, alkyl, alkenyl, alkynyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl; or salts thereof; in which the compound of the formula (I) is reacted with carbon monoxide and hydrogen in the presence of a catalyst comprising a complex of a metal of transition group VIII with a compound of the formula (II), where Pn is a pnicogen atom; W is a divalent bridging group having from 1 to 8 bridging atoms; R2 is a functional group capable of forming an intermolecular, noncovalent bond with the group —X(═O)OH; R3, R4 are each alkyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl; a, b, c are each 0 or 1; and Y1, Y2 and Y3 are each O, S, NRa or SiRbRc; and also compounds of the formula (II.a), where W′ is a divalent bridging group having from 1 to 5 bridging atoms between the flanking bonds, Z is O, S, S(═O), S(═O)2, N(RIX) or C(RIX)(RX); and RI to RX are each, independently of one another, H, halogen, nitro, cyano, amino, alkyl, etc.; or two radicals RI, RII, RIV, RVI, RVIII and RIX together represent the second part of a double bond.

    PROCEDIMIENTO PARA SINTESIS ASIMETRICA.
    5.
    发明专利
    PROCEDIMIENTO PARA SINTESIS ASIMETRICA. 未知

    公开(公告)号：ES2333336T3

    公开(公告)日：2010-02-19

    申请号：ES04803259

    申请日：2004-11-24

    Applicant: BASF SE

    Inventor： JAKEL CHRISTOPH ,  VOLLAND MARTIN ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  BREIT BERNHARD ,  SEICHE WOLFGANG

    IPC: C07F9/58 ,  C07B53/00 ,  C07F9/6571

    Abstract: Procedimiento para la obtención de compuestos quirales a través de la conversión de un compuesto proquiral, que contiene, al menos, un doble enlace insaturado etilénicamente, con un sustrato, en presencia de un catalizador quiral, que comprende, al menos, un complejo de metal de transición con ligandos, que presentan, respectivamente, un grupo que contiene átomos pnicógenos o átomos pseudopnicógenos y, al menos, un grupo funcional apto para formar un enlace intermolecular no covalente, asimismo, el complejo presenta ligandos dimerizados a través de enlaces intermoleculares no covalentes.

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