公开(公告)号：CA2715712A1

公开(公告)日：2009-09-03

申请号：CA2715712

申请日：2009-02-26

Applicant: BASF SE

Inventor： MEISENBURG UWE ,  HOFER FRANK ,  SCHWALM REINHOLD ,  GRUBER NICK ,  KARRER LOTHAR

IPC: C07C67/08 ,  C07C67/54 ,  C07C69/54 ,  C09D133/06 ,  C09J133/06

Abstract: Disclosed is a method for producing (meth)acrylates of C10 alcohol mixtures by reacting (meth)acrylic acid with an isomer mixture of C10 alcohols comprising 2-propylheptanol as the main isomer and at least one of the C10 alcohols 2-propyl-4- methylhexanol, 2-propyl-5-methylhexanol, 2-isopropylheptanol, 2-isopropyl-4- methylhexanol, 2-isopropyl-5-methylhexanol, and/or 2-propyl-4,4-dimethylpentanol in the presence of at least one acid catalyst and at least one polymerization inhibitor and in the presence of a solvent forming an azeotrope along with water, removing the azeotrope by distillation and condensing the same such that the condensate is decomposed into an aqueous and an organic phase. According to said method, a) the esterification process is carried out in a reactor comprising a circulating evaporator, b) in the presence of a solvent, and c) the raw product is purified in a subsequent pure distillation process.

公开(公告)号：BR112013006497A2

公开(公告)日：2016-07-12

申请号：BR112013006497

申请日：2011-09-21

Applicant: BASF SE

Inventor： HOFER FRANK ,  BERGMANN HERMANN ,  PETZOLDT JOCHEN ,  BETTE VIRGINIE

IPC: C07C213/06 ,  C07C219/08

Abstract: processo para preparar ésteres (met)acrílicos de amino álcoois n,n-substituídos. a presente invenção diz respeito a um processo para preparar ésteres (met)acrílcios (f) de amino álcoois n,n-substituídos, pela transesterificação de amino álcoois n,n-substtituídos (i) em que y e z são cada um independentemente alquila c c~ 1~-c c~ 20~, cicloalquila c c~ 3~- c c~ 15~, arila ou y e z juntos com o átomo de nitrogênio que os conectam formam um radical heterocíclico saturado de 5 a 9 membros que opcionalmente tem oxigênio, enxofre, nitrogênio ou nitrogênio substituído com alquila c c~ 1~- c c~ 4~ como um outro heteroátomo, e x é alquileno c c~ 2~- c c ~ 20 ~que pode ser interrompido por 1 a 10 grupos óxi não adjacentes e/ou não substituído ou grupos alquila c c~ 1~- c c~ 4~imino substituídos pode metóxi, ou um cicloalquileno c c~ 3~- c c~ 15~ com pelo menos um éster (met) acrílico (d) na presença de pelo menos um catalisador heterogêneo (k), em que o catalisador heterogêneo (k) é usado sem nenhum solvente adicional e o teor de inibidores de polimerização na mistura de reação é

公开(公告)号：CA2811363A1

公开(公告)日：2012-03-29

申请号：CA2811363

申请日：2011-09-21

Applicant: BASF SE

Inventor： BETTE VIRGINIE ,  BERGMANN HERMANN ,  PETZOLDT JOCHEN ,  HOFER FRANK

IPC: C07C213/06 ,  C07C219/08

Abstract: The present invention relates to a process for preparing (meth)acrylic esters (F) of N,N-substituted amino alcohols, by transesterifying N,N-substituted amino alcohols (I) in which Y and Z are each independently C1-C20-alkyl, C3-C15-cycloalkyl, aryl, or Y and Z together with the nitrogen atom connecting them form a 5- to 9-membered saturated heterocyclic radical which optionally has oxygen, sulfur, nitrogen or C1-C4-alkyl-substituted nitrogen as a further heteroatom, and X is C2-C20-alkylene which may be interrupted by 1 to 10 nonadjacent oxy groups and/or unsubstituted or methoxy-substituted C1-C4-alkylimino groups, or C3-C15-cycloalkylene, with at least one (meth)acrylic ester (D) in the presence of at least one heterogeneous catalyst (K), wherein the heterogeneous catalyst (K) is used without any further solvent and the content of polymerization inhibitors in the reaction mixture is