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公开(公告)号:KR20180008621A
公开(公告)日:2018-01-24
申请号:KR20177035937
申请日:2016-05-09
Applicant: BASF SE
Inventor: SCHAUB THOMAS , HUGUET SUBIELA NURIA , PACIELLO ROCCO , FRIES DONATA MARIA , MANZINI SIMONE
Abstract: 알켄, 이산화탄소, 및 [O] 기에직접결합된 2급또는 3급탄소원자를갖는알콕사이드로부터α,β-에틸렌계불포화카복실산염을제조하는촉매적방법이기재된다. 중간상 분리후 알코올부산물이증류제거된다. 상기방법은최소한의노력으로순수한α,β-에틸렌계불포화카복실산염을제공한다.
Abstract translation: 描述了由链烯烃,二氧化碳和具有与[O]基团直接键合的仲或叔碳原子的醇盐制备α,β-烯键式不饱和羧酸盐的催化方法。 分离中间相后,馏出醇副产物。 该方法以最小的努力提供纯的α,β-烯键式不饱和羧酸盐。
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公开(公告)号:SG11201609591PA
公开(公告)日:2016-12-29
申请号:SG11201609591P
申请日:2015-05-13
Applicant: BASF SE
Inventor: LIMBACH MICHAEL , JEVTOVIKJ IVANA , HUGUET SUBIELA NURIA , GORDILLO ALVARO , STIEBER SABINE CHANTAL EILEEN , LINDNER RONALD , BRU ROIG MIRIAM , LEJKOWSKI MICHAEL , KAGEYAMA TAKEHARU , SCHUNK STEPHAN A
Abstract: Catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt, comprising reacting an alkene and carbon dioxide in the presence of a carboxylation catalyst and releasing the α,β-ethylenically unsaturated carboxylic acid salt with a base, the carboxylation catalyst being a transition metal complex, which comprises a structurally constrained bidentate P,X ligand, wherein X is selected from the group consisting of P, N, O, and carbene, the P and X atom are separated by 2 to 4 bridging atoms, and wherein the bridging atoms are part of at least one 5- to 7-membered cyclic substructure. A further catalytic processes for preparing α,βethylenically unsaturated carboxylic acid derivatives from CO2 and an alkene is provided.
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公开(公告)号:AU2021243497A1
公开(公告)日:2022-10-20
申请号:AU2021243497
申请日:2021-03-23
Applicant: BASF SE
Inventor: ROHDE WOLFGANG , ADERMANN TORBEN , SCHIERLE-ARNDT KERSTIN , HUGUET SUBIELA NURIA , KEMPTER ANDREAS , GERKE BIRGIT
Abstract: The present invention relates to a process for the recovery of transition metals from battery materials comprising (0.1) providing a battery material which comprises oxidic nickel and/or cobalt compounds, (1.1) heating the battery material above 350 °C to yield a reduced material which contains nickel and/or cobalt in elemental form, (2.1) carbonylating the reduced material with carbon monoxide optionally in the presence of a reactive gas to yield a solid carbonylation residue and a volatile carbonyl which comprises nickel and/or cobalt carbonyl containing compounds, and (3.1) separating the volatile carbonyl from the solid carbonylation residue by evaporation.
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公开(公告)号:EP3294701A1
公开(公告)日:2018-03-21
申请号:EP16722636
申请日:2016-05-09
Applicant: BASF SE
Inventor: SCHAUB THOMAS , HUGUET SUBIELA NURIA , PACIELLO ROCCO , FRIES DONATA MARIA , MANZINI SIMONE
IPC: C07C51/25
Abstract: A catalytic process for preparing an α,β-ethylenically unsaturated carboxylic acid salt from an alkene, carbon dioxide and an alkoxide having a secondary or tertiary carbon atom directly bound to a [O-] group is described. The alcohol byproduct is distilled off after an intermediate phase separation. This provides pure α,β-ethylenically unsaturated carboxylic acid salt at minimum effort.
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