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    탄소 원자 수 4 내지 20의 올레핀 함유 탄화수소 혼합물로부터의 올레핀의 이성질체화를 위한 촉매 및 방법
    1.
    发明公开
    탄소 원자 수 4 내지 20의 올레핀 함유 탄화수소 혼합물로부터의 올레핀의 이성질체화를 위한 촉매 및 방법 审中-公开
    用于从含有4至20个碳原子的含烯烃的烃混合物中异构化烯烃的催化剂和方法

    公开(公告)号：KR20180030997A

    公开(公告)日：2018-03-27

    申请号：KR20187003810

    申请日：2016-07-08

    Applicant: BASF SE

    Inventor： ISELBORN STEFAN ,  UFER ANDREAS JOERG

    IPC: B01J37/08 ,  B01J23/42 ,  B01J23/44 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

    CPC classification number: B01J23/42 ,  B01J21/04 ,  B01J23/44 ,  B01J23/96 ,  B01J35/0066 ,  B01J35/008 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/088 ,  B01J37/18 ,  B01J38/10 ,  C07C5/2556 ,  C07C2521/04 ,  C07C2523/44 ,  Y02P20/584 ,  C07C11/08

    Abstract: 본발명은, 담체물질로서의알루미나및 활성성분으로서의팔라듐또는백금을포함하는촉매에관한것으로서, 이는 a) 알루미나담체를, 활성성분인팔라듐또는백금의적어도하나의염을포함하는용액으로함침시키는단계; 및 b) 이렇게얻어진촉매를건조시키는단계에의해수득될수 있으며, c) 이렇게얻어진촉매를수소, 또는수소와적어도하나의불활성기체의혼합물로 1 내지 24 시간동안 30 내지 200℃의온도에서처리하는단계, 및 d) 그후, 이렇게환원된촉매를수소, 또는수소와적어도하나의불활성기체의혼합물의존재하에 1 시간내지 10 일동안 10 내지 100℃의온도에서유지시키는단계를특징으로한다. 본발명에따른촉매는 10 내지 150℃의온도및 1 내지 35 bar의압력에서, 탄소원자수 4 내지 20의올레핀함유탄화수소혼합물로부터올레핀을이성질체화하는방법, 예를들면 1-부텐에서 2-부텐으로의이성질체화에사용될수 있다.

    Abstract translation: 本发明涉及一种包括钯或铂氧化铝和活性成分的载体材料，其是氧化铝载体的步骤a），用包含钯或铂的活性成分的至少一种盐的溶液浸渍催化剂; 和b），这可以通过干燥所得催化剂来获得，c）本方法的步骤，从而获得氢的催化剂，或用惰性气体和氢的混合物为1至24小时，从30至200℃的至少一个温度 ，和d）随后，其特征在于在维持氢气由此还原的催化剂，或在至少一种惰性气体和氢的混合物的存在下的10〜100℃进行1小时至10天的温度的步骤。 在1至35巴和根据本发明所涉及的催化剂的温度的压力为10〜150℃，方法为从含烯烃的烃混合物的烯烃在4至20的碳原子数的异构化，例如，从1-丁烯至2-丁烯 ＆lt;

    3.
    发明专利
    未知

    公开(公告)号：DE50311896D1

    公开(公告)日：2009-10-22

    申请号：DE50311896

    申请日：2003-03-07

    Applicant: BASF SE

    Inventor： GERLACH TILL ,  FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HUELLMANN MICHAEL

    IPC: B01J23/755 ,  C07D295/02 ,  B01J23/70 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

    Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

    REACTOR FOR CARRYING OUT A THREE-PHASE REACTION OF A LIQUID PHASE AND A GASEOUS PHASE OVER A FIXED CATALYST BED
    4.
    发明专利
    REACTOR FOR CARRYING OUT A THREE-PHASE REACTION OF A LIQUID PHASE AND A GASEOUS PHASE OVER A FIXED CATALYST BED 未知

    公开(公告)号：CA2691642C

    公开(公告)日：2015-12-22

    申请号：CA2691642

    申请日：2008-06-20

    Applicant: BASF SE

    Inventor： BECHTEL MARCUS ,  HEPFER BENJAMIN ,  WILLE MICHAEL ,  DAISS ANDREAS ,  GEIER REINER ,  ISELBORN STEFAN ,  SAUTER JOHN

    IPC: B01J8/00 ,  B01D3/00 ,  B01J8/02 ,  C10G49/00

    Abstract: The invention relates to a reactor (R) for performing a three-phase reaction of a fluid phase (1) and a gaseous phase (2) on a packed bed catalyst (F), the packed bed catalyst (F) being disposed horizontally in the reactor (R) and the fluid phase (1) and the gaseous phase (2) being fed through the reactor (R) from the bottom to the top, using a mixing and distributing device (MV) across the packed bed catalyst (F), characterized in that the mixing and distributing device (MV) comprises a trough distributor (TV) for the fluid phase (1) having trough-shaped channels (K) and drain tubes (A) in the trough-shaped channels (K) for the fluid phase (1), and a distributor floor (B) disposed below and at a distance from the trough distributor (TV) in which vertical spouts (T) are disposed, having one or more openings (P1) for the inlet of the gaseous phase (2) and one or more openings (P2) disposed below the openings (P1) for the inlet of the gaseous phase, for the inlet of the fluid phase (1) into the spouts (T), and the number and size of the openings (P2) for the inlet of the fluid phase (1) being designed such that the fluid level on the distribution floor (B) is adjusted to be below the openings (P1) for the inlet of the gaseous phase (2) and above the openings (P2) for the inlet of the fluid phase (1) for a prescribed inlet flow of fluid.

    ISOMERIZATION OF LIGHT ALPHA-OLEFINS TO LIGHT INTERNAL OLEFINS
    9.
    发明专利
    ISOMERIZATION OF LIGHT ALPHA-OLEFINS TO LIGHT INTERNAL OLEFINS 未知

    公开(公告)号：CA2832325A1

    公开(公告)日：2012-11-01

    申请号：CA2832325

    申请日：2012-04-27

    Applicant: BASF SE

    Inventor： ISELBORN STEFAN ,  HESSE MICHAEL ,  MAKARCZYK PIOTR

    IPC: C07C5/23 ,  C07C5/25 ,  C07C11/02

    Abstract: The present invention relates to a process for isomerizing linear alpha-olefins having from 4 to 8 carbon atoms over a heterogeneous catalyst, wherein the catalyst comprises a hydrogenation metal and a selectivity promoter selected from among selenium and tellurium on a support, and also a process for preparing 1-olefins by a metathesis reaction of 2-olefins with ethene, wherein the 2-olefins are prepared by the above mentioned isomerization process.

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