Abstract:
PROBLEM TO BE SOLVED: To simplify a production method for a material usable as a radical crosslinking agent for a high-absorbent material.SOLUTION: A method for producing a crosslinked hydrogel is provided, in which a polyalcohol A is reacted with an ethylenically unsaturated carboxylic acid B in the presence of an esterification catalyst C, a polymerization inhibitor D, and optionally a solvent E which forms an azeotrope with water under the formation of an ester F. Optionally, at least a part of water produced is removed from a reaction mixture, optionally the reaction mixture is neutralized, and the solvent E is removed by distillation, and/or stripped using a gas which is inert under reaction conditions. The reaction mixture from one of the steps, optionally an additional monoethylenically unsaturated compound N, and optionally a copolymerizable hydrophilic monomer M are polymerized in the presence of a radical initiator K and optionally a graft base L. Optionally, the reaction mixture obtained is subjected to post crosslinking, drying, pulverization, and/or screening.
Abstract:
A method for producing dicarboxylic acids by oxidation of cycloaliphatic alcohols, cycloaliphatic ketones, or mixtures thereof with nitric acid, in that the reaction and separation of the components is performed in a fractionation or rectification column.
Abstract:
Process for producing dicarboxylic acid, comprises oxidation of cycloaliphatic alcohols and/or cycloaliphatic ketone with nitric acid, where the reaction and the separation of the components are carried out in a fractionating-, reaction-, and/or rectification-column.
Abstract:
A multicoat system on a substrate, comprising at least one radiation-curable coating system (F) and at least one elastic intercoat (D) which is located between substrate and radiation-curable coating system (F) and has a glass transition temperature (Tg) of −20° C. or less.
Abstract:
A multicoat system on a substrate, comprising at least one radiation-curable coating system (F) and at least one elastic intercoat (D) which is located between substrate and radiation-curable coating system (F) and has a glass transition temperature (Tg) of −20° C. or less.
Abstract:
The present invention relates to novel mixtures of (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O-CH2-CH2- PO is independently at each instance O-CH2-CH(CH3)- or O-CH(CH3)-CH2- BO is independently at each instance O-CH2-CH(CH2-CH3)- or O-CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these ester mixtures and the use of reaction mixtures thus obtainable.
Abstract:
Process for producing dicarboxylic acid comprises oxidation of cycloaliphatic alcohols and/or cycloaliphatic ketone with nitric acid, where the reaction and the separation of the components are carried out in a fractionating-, reaction-, and/or rectification-column.
Abstract:
The present invention relates to a process for producing a coating substrate by applying at least one coating composition to the substrate and then curing it to give a coating film on the substrate, to the coated substrates obtained by this process, and to a coating composition.
Abstract:
The present invention relates to a process for producing a coating substrate by applying at least one coating composition to the substrate and then curing it to give a coating film on the substrate, to the coated substrates obtained by this process, and to a coating composition.