Abstract:
The invention relates to a method for producing one or more complexing agents, selected from methylglycinediacetic acid, glutamic acid diacetic acid, and salts thereof, by catalytically dehydrogenating N,N-bis-(2-hydroxyethyl)-alanine and/or N,N-bis-(2-hydroxyethyl)-glutamic acid or salts thereof in the presence of alkali hydroxide, a catalyst containing copper and zirconium dioxide being used, the activation of which is a reduction, characterized in that the precursor of the catalyst in question has a degree of crystallization K defined as (I) in the range of 0 to 50%.
Abstract:
The present invention relates to processes for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the feed gas stream a comprising propane, if appropriate steam and if appropriate and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, hydrogen, if appropriate carbon monoxide, carbon dioxide, steam and oxygen; C) the product gas stream b is cooled, if appropriate compressed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) the product gas stream c is contacted with a selective adsorbent which adsorbs propene selectively under the selected adsorption conditions to obtain a propene-laden adsorbent and a propene-depleted gas stream d2 comprising propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide; E) a propene-comprising gas stream e1 is released from the propane-laden adsorbent by pressure reduction and/or heating of the adsorbent.
Abstract:
The invention relates to a method for producing aminopolycarboxylates starting from the corresponding polyalkanol amines by means of oxidative dehydration in the presence of a catalyst containing 1 to 90 wt.% copper, with respect to the total weight of the catalyst, using a base. The method is characterized in that the polyalkanol amine is first partially reacted into a reaction mixture containing the aminopolycarboxylate at a temperature ranging from 140 to 180 °C until at least 10 to 90 mol% of the polyalkanol amine is reacted. The reaction is then continued at an increased temperature.
Abstract:
The present invention relates to processes for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the feed gas stream a comprising propane, if appropriate steam and if appropriate and an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, hydrogen, if appropriate carbon monoxide, carbon dioxide, steam and oxygen; C) the product gas stream b is cooled, if appropriate compressed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) the product gas stream c is contacted with a selective adsorbent which adsorbs propene selectively under the selected adsorption conditions to obtain a propene-laden adsorbent and a propene-depleted gas stream d2 comprising propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide; E) a propene-comprising gas stream e1 is released from the propane-laden adsorbent by pressure reduction and/or heating of the adsorbent.
Abstract:
The present invention relates to methods for removing carbon dioxide and, if appropriate, water from breathing air in closed or partially closed systems using a porous metal-organic framework material, such systems having at least one breathing apparatus and also their use and methods for regenerating the porous metal-organic framework material.
Abstract:
Procedimiento para la preparación de aminopolicarboxilatos a partir de las polialcanolaminas correspondientes mediante deshidrogenación oxidativa en presencia de un catalizador que contiene del 1 al 90 % en peso de cobre, con respecto al peso total del catalizador, con el uso de una base, caracterizado porque en primer lugar se lleva a cabo una reacción parcial de la polialcanolamina para dar una mezcla de reacción que contiene el aminopolicarboxilato a una temperatura en el intervalo de 140 a 180 °C, hasta que ha reaccionado al menos del 10 al 90 % en moles de la polialcanolamina, y porque a continuación se continúa la reacción a temperatura elevada
Abstract:
Módulo de enfriamiento/calentamiento por adsorción que contiene un sorbente sólido así como un agente de trabajo, en el que el sorbente contiene al menos un material estructural organometálico poroso que contiene al menos un compuesto orgánico al menos bidentado, unido por coordinación al al menos un ión metálico, caracterizado porque el agente de trabajo contiene agua.