Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing an alkali metal from an alkali metal amalgam by electrolysis using an anode containing an alkali metal amalgam, a solid electrolyte having alkali ion conductivity, and a cathode being a molten alkali metal. SOLUTION: The method for producing an alkali metal from an alkali metal amalgam includes the alkali metal amalgam being an anode moved by being stirred under atmospheric pressure or under a pressure slightly higher than atmospheric pressure. COPYRIGHT: (C)2011,JPO&INPIT
Abstract:
The invention relates to a method for the production of isocyanates R-NCO by anodic oxidation of formamides of the general formula (I), wherein R is hydrogen or an arbitrary organic radical, wherein the electrolytic solution comprises at least one conductor salt in addition to the formamide (I).
Abstract:
Process for removing absorptive from the liquid comprises contacting the liquid with an absorbent containing a porous metal organic supporting material, where the supporting material removes the liquid and contains a metal ion co-coordinative bond and spined organic compound.
Abstract:
The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
Abstract:
The invention relates to a method for the production of isocyanates R-NCO by anodic oxidation of formamides of the general formula (I), wherein R is hydrogen or an arbitrary organic radical, wherein the electrolytic solution comprises at least one conductor salt in addition to the formamide (I).
Abstract:
Process for preparing primary amines having a cyclopropyl unit and a primary amino group bound to an aliphatic or cycloaliphatic carbon atom (amine A) by cathodically reducing oximes having a cyclopropyl unit or oxime derivatives in which the hydrogen atom in the oxime group has been replaced by an alkyl or acyl group (oxime O) at a temperature of from 50 to 100° C. in an essentially anhydrous electrolyte solution in a divided electrolysis cell.
Abstract:
The present invention relates to suspensions for odor reduction comprising a porous metal-organic framework material in a liquid, and also atomizer and methods for odor reduction using the suspensions. The invention likewise relates to the use of the suspensions for odor reduction.
Abstract:
The invention relates to a method for the electrolytic oxidative alkoxylating cleavage of 1,2-diarylethane derivatives by electrolytically oxidizing the respective 1,2-diarylethane derivative in a solvent containing the alcohol required for alkoxylation, electrolytic oxidation being performed on a diamond electrode. The inventive method makes it possible to especially produce diaryl derivatives when a 1,2-diarylethane derivative in which the two aryl radicals are directly bonded to each other is used as a substrate.