Abstract:
A method is disclosed for transferring heat to a liquid F containing dissolved monomeric acrylic acid, acrylic acid oligomers obtained by Michael addition, and acrylic acid polymer with the help of an indirect heat exchanger to which the liquid F is fed at a temperature TF = 150°C and a heat transfer fluid W is fed at a temperature Tw > TF. In said method, gas bubbles or thin layers of liquid F bordering a gas phase are generated in the liquid F while said liquid F flows through the heat exchanger.
Abstract:
The invention relates to a method for cleaning an aqueous glyoxal solution comprising at least one acid by extractive acid separation, comprising the steps of: I) mixing an aqueous glyoxal solution with an ion exchanger solution, comprising 20 to 60 wt % of a tertiary amine and 80 to 40 wt % of an organic solvent immiscible with water at a dwell time of
Abstract translation:一种用于纯化的乙二醛水溶液,其含有至少一种酸,酸包括我步骤:a)用含有20至60重量的叔胺%和80〜40的离子交换溶液混合的乙二醛水溶液的提取分离方法 重量的非在<5分钟的停留时间的任何可与水混溶的有机溶剂和30〜100℃的温度下的%,用于在提取的乙二醛水溶液制备混合物从步骤I)中分离的混合物,II) 和加载的离子交换溶液和分离在30的温度下装载离子交换剂溶液至100℃,和iii)分离在的温度下叔胺和纯化的乙二醛水溶液和叔胺的分离所提取的乙二醛水溶液<30° C.
Abstract:
The invention relates to a method for producing isocyanates by converting the corresponding amine with phosgene in the gas phase, in the presence of an inert medium as applicable, wherein phosgene and amine are first vaporized and then overheated to reaction temperature, the overheated phosgene and amine are mixed and added to a reactor wherein the phosgene and the amine are converted to isocyanate, wherein the dwell time of the phosgene at temperatures greater than 300°C equals a maximum of 5 sec and/or the temperature of heat transfer surfaces in contact with the phosgene is 20 K above the phosgene temperature to be set at maximum. The invention further relates to a device for producing isocyanates by converting the corresponding amine with phosgene in the gas phase.
Abstract:
The present invention relates to a coat or coating to counteract crystalline deposits, said coat or coating being on a substrate and comprising a matrix composed of a binder system and ceramic particles and also boron nitride in particulate form, the boron nitride particles being embedded and essentially uniformly dispersed in the matrix; to a composition for producing such a coat or coating; to a process for producing such a coat or coating; to the use of a boron nitride composition as a material for coating surfaces coming into contact with salt-containing solutions; and also to a water treatment plant comprising components coming into contact with salt-containing water and provided at least partially with a coat comprising boron nitride.
Abstract:
Process for recovering cyclododecatriene (CDT) from a solution containing CDT and high boilers such as deactivated catalyst and polymers, which includes feeding the solution into a preheater and heating it, subsequently depressurizing it through a downstream pressure maintenance device and feeding the resulting two-phase mixture into a helical tube evaporator and there reducing the CDT content of the liquid phase by partial evaporation and discharging a gaseous product stream having an increased concentration of CDT.
Abstract:
In the production of a vicinal dioxo compound (I) by heterogeneous catalyzed gas phase oxidation of a vicinal dihydroxy compound (II) in presence of oxygen-containing gas over a copper-containing catalyst, the starting material (II) has a reduced overall content of trace elements (III), selected from sodium, chromium, iron, zinc, phosphorus, chlorine and sulfur, of less than 250 ppm.
Abstract:
A method of counteracting crystalline deposits on a surface includes applying a sprayable low-viscosity suspension including a binder system including at least one organosilicon constituent selected from the group consisting of alkylpolysiloxane, alkylsilicone resin and phenylsilicone resin; ceramic particles; hexagonal boron nitride particles; optionally, process additives; and at least one solvent to the surface and curing the suspension.