METHOD FOR SEPARATING SUBSTANCE MIXTURES BY MEANS OF MULTIPHASE POLYMER FILMS

    公开(公告)号:CA2774213A1

    公开(公告)日:2011-04-07

    申请号:CA2774213

    申请日:2010-09-27

    Applicant: BASF SE

    Abstract: The present invention relates to a method for separating substance mixtures by means of a non-porous polymer film, comprising (a) at least one inorganic or metal-organic phase, and (b) at least one organic polymer phase, wherein the polymer film can be obtained by polymerizing at least one monomer comprising at least one first polymerizable monomer segment A1, comprising at least one metal or semi-metal M, and at least one second polymerizable organic monomer segment A2, connected to the polymerizable monomer segment A1 by means of a covalent chemical bond, under polymerization conditions, under which both the polymerizable monomer segment A1 and the polymerizable organic monomer segment A2 polymerize while breaking the covalent chemical bond between A1 and A2. The present invention further relates to the use of the above polymer films for permeating, gas separating, or pervaporating.

    POROUS FILM MATERIAL, COMPRISING AT LEAST ONE CARBONACEOUS SEMIMETAL OXIDE PHASE, AND THE USE THEREOF AS A SEPARATOR MATERIAL FOR ELECTROCHEMICAL CELLS

    公开(公告)号:CA2763963A1

    公开(公告)日:2011-01-06

    申请号:CA2763963

    申请日:2010-06-30

    Applicant: BASF SE

    Abstract: The present invention relates to a novel porous film material comprising at least one carbonaceous semimetal oxide phase, and to a method for the production thereof. The invention further relates to the use of said porous film materials as a separator layer or for producing such separator layers in electrochemical cells, in particular in lithium ion cells, and especially in lithium ion secondary cells. The porous film material according to the invention comprises: a) at least one carbonaceous (semi)metal oxide phase A of silicon, aluminum, titanium, or zircon, comprising hydrocarbon groups covalently boded to the (semi)metal; b) optionally one or more organic polymer phases B, wherein the inorganic (semi)metal oxide phase A forms substantially continuous phase domains in which the pore phase present in the film material and the optionally present organic polymer phase(s) B are embedded, wherein the average distance between two phase boundaries of adjacent domains of identical phases is a maximum of 50 nm, preferably a maximum of 10 nm, in particular preferably a maximum of 5 nm, and especially a maximum of 2 nm.

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