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公开(公告)号:CA3014685A1
公开(公告)日:2017-08-24
申请号:CA3014685
申请日:2017-02-13
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI
IPC: C08F10/10 , C08F4/14 , C08F4/52 , C08F4/54 , C08F110/10
Abstract: The present invention relates to a process for preparing high- reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per homo- or copolymer chain end of at least 70 mol% which comprises polymerizing isobutene or an isobutene- comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, said complex comprising, as the donor, a mixture of at least two organic compounds with at least one ether function each.
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公开(公告)号:SG11202001000QA
公开(公告)日:2020-03-30
申请号:SG11202001000Q
申请日:2018-08-07
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI
IPC: C08F110/10 , C08F4/14
Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol%. The present invention further relates to novel isobutene polymers.
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公开(公告)号:CA3014684A1
公开(公告)日:2017-08-24
申请号:CA3014684
申请日:2017-02-13
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI
IPC: C08F10/10 , C08F4/14 , C08F4/54 , C08F110/10
Abstract: The present invention relates to a process for preparing high- reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol%, which comprises polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or an alkylaluminum halide-donor complex effective as a polymerization catalyst, wherein the aluminum trihalide or alkylaluminum halide is treated with at least one inorganic hydrate.
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公开(公告)号:CA3070031A1
公开(公告)日:2019-02-21
申请号:CA3070031
申请日:2018-08-07
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI
IPC: C08F110/10 , C08F4/14
Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol%. The present invention further relates to novel isobutene polymers.
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公开(公告)号:SG11201810402PA
公开(公告)日:2018-12-28
申请号:SG11201810402P
申请日:2017-07-14
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI , BERAZIANKA IVAN
Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
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公开(公告)号:CA3031140A1
公开(公告)日:2018-01-25
申请号:CA3031140
申请日:2017-07-14
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI , BERAZIANKA IVAN
Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol%. The present invention further relates to novel isobutene polymers.
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公开(公告)号:CA2789843C
公开(公告)日:2018-07-10
申请号:CA2789843
申请日:2011-02-10
Applicant: BASF SE
Inventor: KOENIG HANNAH MARIA , MUHLBACH KLAUS , KIEFER MATTHIAS , KOSTJUK SERGEI V , VASILENKO IRINA , FROLOV ALEXANDER
IPC: C08F10/10
Abstract: Preparation of high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 50 mol% and a polydispersity of preferably 1.05 to less than 3.5, by polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an aluminum trihalide-donor complex effective as a polymerization catalyst or of an alkylaluminum halide-donor complex, especially of an aluminum trichloride-donor complex, said complex comprising, as the donor, an organic compound with at least one ether function or a carboxylic ester function.
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公开(公告)号:RU2555400C2
公开(公告)日:2015-07-10
申请号:RU2012139361
申请日:2011-02-10
Applicant: BASF SE
Inventor: KENIG KHANNA MARIJA , MJUL BAKH KLAUS , KIFER MATTIAS , KOSTJUK SERGEJ V , VASILENKO IRINA
IPC: C08F10/10 , C08F4/14 , C08F210/10
Abstract: Изобретениеотноситсяк получениювысокореакционноспособныхгомополимеровилисополимеровизобутенас содержаниемконцевыхвинилиденовыхдвойныхсвязейнаконцеполиизобутеновыхцепейнеменее 50 мол.% израсчетанаотдельныеконцыцепейполиизобутеновыхмакромолекул. Изобутенилисодержащуюизобутенсмесьмономеровполимеризуютв присутствииактивногокатализатора. Вкачествекатализатораполимеризациииспользуюткомплекстригалогенидаалюминияи донораиликомплексгалогенидаалкилалюминияи донора. Доноромявляетсяорганическоесоединениес неменеечемоднойфункциональнойгруппойпростогоэфираилис функциональнойгруппойэфиракарбоновойкислоты. Описаныизобутеновыеполимерыобщейформулы I иформулы II.Техническийрезультат - получениевысокореакционноспособныхгомополимеровилисополимеровизобутенас узкиммолекулярно-массовымраспределением. 2 н. и 12 з.п. ф-лы, 30 пр.
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公开(公告)号:SG10201500721PA
公开(公告)日:2015-04-29
申请号:SG10201500721P
申请日:2011-02-10
Applicant: BASF SE
Inventor: KÖNIG HANNAH MARIA , MÜHLBACH KLAUS , KIEFER MATTHIAS , KOSTJUK SERGEI V , VASILENKO IRINA , FROLOV ALEXANDER
Abstract: The invention relates to the production of highly reactive isobutene homo or copolymers having a content of vinylidene double bonds per polyisobutene chain termination of at least 50 mol % and a polydispersity of preferably 1.05 to less than 3.5, wherein isobutene or a monomer mixture containing isobutene is polymerized in the presence of an aluminum trihalogenide donor complex acting as a polymerization catalyst, in particular an aluminum trichloride donor complex, comprising an organic compound having at least one ether function or a carboxylic acid ester function as the donor.
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公开(公告)号:SG11201806870WA
公开(公告)日:2018-09-27
申请号:SG11201806870W
申请日:2017-02-13
Applicant: BASF SE
Inventor: CORBERAN ROC ROSA , MUEHLBACH KLAUS , WETTLING THOMAS , KOSTJUK SERGEI V , VASILENKO IRINA , SHIMAN DMITRYI
IPC: C08F4/14 , C08F10/10 , C08F4/52 , C08F4/54 , C08F110/10
Abstract: The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 80 mol %. The present invention further relates to novel isobutene polymers.
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