公开(公告)号：JP2008069156A

公开(公告)日：2008-03-27

申请号：JP2007242657

申请日：2007-09-19

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： KARRER LOTHAR ,  PAPE FRANK-FRIEDRICH ,  KNEUPER HEINZ-JOSEF DR ,  HULLMANN MICHAEL

IPC: C07C253/28 ,  C07D213/84 ,  B01J23/18 ,  B01J23/22 ,  B01J23/847 ,  B01J37/04 ,  C07B61/00 ,  C07C253/24 ,  C07C255/32 ,  C07C255/49 ,  C07C255/51

CPC classification number: B01J23/8472 ,  B01J23/18 ,  B01J23/22 ,  C07C253/28 ,  C07C255/51

Abstract: PROBLEM TO BE SOLVED: To provide a novel and improved method for producing an aromatic or a heteroaromatic nitrile from an aromatic or heteroaromatic hydrocarbon.
SOLUTION: Disclosed is a method for preparing an aromatic or a heteroaromatic nitrile represented by general formula (I) from an aromatic or heteroaromatic hydrocarbon in the presence of ammonia and oxygen or an oxygen-containing gas using a supported catalyst comprising 0.5 to 20 wt.% of vanadium oxide comprised of 2 to 30 particle fractions thereof with a mean diameter of each of the particle fractions mutually different by 10 to 80% and a support having bulk density of 0.6 to 1.2 kg/L.
COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：提供一种从芳族或杂芳族烃生产芳族或杂芳族腈的新颖和改进的方法。 解决方案：公开了一种在氨和氧或含氧气体存在下，使用负载型催化剂，由芳族或杂芳族烃在芳烃或杂芳族烃中制备由通式（I）表示的芳族或杂芳族腈的方法， 20重量％的氧化钒由2〜30个颗粒组分组成，每个颗粒级分的平均直径相互不同10至80％，而载体的体积密度为0.6至1.2kg / L。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：AT442198T

公开(公告)日：2009-09-15

申请号：AT03743852

申请日：2003-03-07

Applicant: BASF SE

Inventor： GERLACH TILL ,  FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HULLMANN MICHAEL

IPC: B01J23/00 ,  C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.