公开(公告)号：EP0968130A4

公开(公告)日：2002-08-14

申请号：EP97953040

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G ,  MITCHELL JAMES D

IPC: C07D295/14 ,  C01B13/02 ,  C07D295/02 ,  C07D295/15 ,  C11D1/62 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/00 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C07D211/26 ,  C07D211/34 ,  C07D265/12 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/02 ,  C11D3/3925 ,  C11D3/3947 ,  D06L4/12 ,  D06L4/17

Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butylmorpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is coctacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.

Abstract translation: 腈活化剂如N-烷基铵乙腈活化剂与活性氧源一起作为清洁和漂白组合物。 本发明优选的活化剂实例包括N-甲基吗啉鎓乙腈，N-丁基吗啉乙腈，N-己基吗啉乙腈和N-辛基吗啉鎓乙腈的盐。 特别优选的活化剂实施方案是N-甲基吗啉乙腈盐。 腈和活性氧反应形成漂白剂，该漂白剂用于制品上的污渍。 将经处理的污渍与致密气体接触，以提供基本上非水性污渍去除。 一个实施方案是其中将腈和活性氧设置在致密二氧化碳中的组合物。

公开(公告)号：HU9800642A2

公开(公告)日：1998-07-28

申请号：HU9800642

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALRED G

IPC: C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C07D295/14 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.

公开(公告)号：AU5686998A

公开(公告)日：1998-06-22

申请号：AU5686998

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G ,  MITCHELL JAMES D

IPC: C07D295/14 ,  C01B13/02 ,  C07D295/02 ,  C07D295/15 ,  C11D1/62 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/00 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butyl morpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is contacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.

公开(公告)号：CZ9700622A3

公开(公告)日：1997-07-16

申请号：CZ62297

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

公开(公告)号：TR9600485A2

公开(公告)日：1996-12-21

申请号：TR9600485

申请日：1996-06-07

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

公开(公告)号：AT250046T

公开(公告)日：2003-10-15

申请号：AT96917033

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.

公开(公告)号：CZ62297A3

公开(公告)日：1997-07-16

申请号：CZ62297

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.

公开(公告)号：CA2196902A1

公开(公告)日：1996-12-19

申请号：CA2196902

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C07D451/02 ,  C07D205/04 ,  C07D209/08 ,  C07D203/12

Abstract: Bleaching compositions are provided that comprise a nitrile containing compound that has the nitrile bonded to a quaternary nitrogen through a methylene unit (where one or both of the normal hydrogens can be substituted), and two of the quaternary nitrogen bonds are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrile for bleaching applications. Particularly preferred nitrile containing compounds are N-alkyl morpholinium acetonitrile salts.

公开(公告)号：CO4700549A1

公开(公告)日：1998-12-29

申请号：CO96029441

申请日：1996-06-06

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  LAFAYETTE D FOLAND ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L

IPC: C07D295/14 ,  C07D295/15 ,  C11D1/62 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

Abstract: Un compuesto que tiene la estructura de la Fórmula 1A o la Fórmula 1Bdonde A es un anillo saturado formado por una cantidad de átomos además del átomo N1, los átomos del anillo saturado incluyen por lo menos a un átomo de carbono y por lo menos a uno de los átomos O, S y N, el sustituyente R1, enlazado al átomo N1 de la estructura de la Fórmula 1A incluye tanto a (a) C1-24 alquilo o alquilo alcoxilado donde el alcoxi es C2-4, (b) un C4-24 cicloalquilo, (c) un C7-24 alcarilo, (d) un alcoxi o alcohól alcoxilado de repetición o no de retición, donde la unidad alcoxi es C2-4, o (e) -CR2R3C-N donde R2 y R3 de cada H, un C1-24 alquilo, cicloalquilo o alcarilo, o un alcoxi o alcohol alcoxilado de repetición o no de repetición donde la unidad alcoxi es C2-4, los sustituyentes R2 y R3 son cada uno H, un C1-24 alquilo, cicloalquilo o alcarilo, o un alcoxi o alcohol alcoxilado de repetición o no de repetición donde la unidad alcoxi es C2-4, el grupo de enlace R4 incluye a un grupo polioxialquileno con entre 1 o 24 unidades de oxialquileno, donde uno o más átomos de oxígeno pueden reemplazarse por un átomo de azufre o un grupo alquileno con entre 1 y 24 átomos de carbono, e Y es por lo menos un contra ión.

公开(公告)号：BR9606441A

公开(公告)日：1997-09-30

申请号：BR9606441

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.