公开(公告)号：EP1036070A4

公开(公告)日：2001-01-31

申请号：EP97947607

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  KLOTTER KEVIN A ,  MUELLER MICHAEL ,  MUNDINGER KLAUS ,  PERKINS SARAH A ,  PHILLIPPI MARTIN A ,  SCHOLTISSEK MARTIN ,  SCHOENHERR MICHAEL ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02 ,  C07D265/30 ,  C01B3/00 ,  C07D211/26 ,  C07D211/34 ,  C07D295/12 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/3925 ,  D06L4/12

Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.

公开(公告)号：EP0950016A4

公开(公告)日：2002-08-14

申请号：EP97948441

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： CHOY CLEMENT K ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  GARABEDIAN ARAM JR ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  PHILLIPPI MARTIN A ,  SMITH WILLIAM L

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/04 ,  C11D17/08 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C07D211/26 ,  C07D211/34 ,  C07D265/12 ,  C07D295/12 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  C11D17/041 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

Abstract: The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula (I) wherein A is a saturated ring formed by five atoms in addition to the N1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R1 bound to the N1 atom of the Formula (I) structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3CN where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, and wherein Y is a generally anionic counterion and Z is in the range of 0 to 10. Additional, adjunct materials commonly found in liquid cleaning and bleaching compositions can be added.

Abstract translation: 本发明提供了含有具有式I结构的化合物的液体清洗或漂白组合物，其中A是除了N1原子以外的五个原子形成的饱和环，五个饱和环原子是四个碳原子和一个杂原子， 包括（a）C1-24烷基或其烷氧基为C2-4的烷氧基化烷基，（b）C4-24环烷基，（c）C7-24烷芳基，（d） ）重复或不重复的烷氧基或烷氧基化醇，其中烷氧基单元是C 2-4，或（e）-CR 2 R 3 CN，其中R 2和R 3各自为H，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基 或烷氧基化醇，其中烷氧基单元为C 2-4，R 2和R 3取代基各自为H，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4， 并且其中Y是通常为阴离子的抗衡离子，Z在0至10的范围内。另外， 通常可以添加在液体清洗和漂白组合物中发现的辅助材料。

公开(公告)号：EP0951438A4

公开(公告)日：2002-08-14

申请号：EP97948373

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： CASELLA VICTOR M ,  BROECKEL ULRICH ,  CHOY CLEMENT K ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  HUESTIS SUSAN P ,  KLOTTER KEVIN A ,  BLONDEAU SARAH A ,  PETERSON DAVID ,  PETRIN MICHAEL J ,  PHILLIPPI MARTIN A ,  SIBERT WILLIAM P ,  SCHOENHERR MICHAEL ,  SEELMANN-EGGEBERT HANS PETER ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/12 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/06 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  B29C59/00 ,  B29C67/00 ,  C07D211/26 ,  C07D211/34 ,  C07D265/12 ,  C07D295/12 ,  C07D295/26 ,  C11D7/38 ,  D04H1/64

CPC classification number: C07D295/15 ,  C11D3/3925 ,  C11D3/3935 ,  C11D17/06 ,  D06L4/12 ,  D06L4/17

Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of formula (I), wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.

公开(公告)号：EP0948455A4

公开(公告)日：2002-03-13

申请号：EP97950668

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

Abstract: The invention comprises heterocyclic cationic activators with the structure of Formula (I) that are capable of forming a peroxyimidic acid with a source of active oxygen in aqueous solution or being in a peroxyimidic form wherein A, R1, R2, R3, Y, and Z are as defined in the disclosure. The activators of Formula (I) are admixed with another compound selected from anionic species either capable of forming a peracid with a source of active oxygen in aqueous solution, or being in a peracid form, or a non-ionic polarizable activator and suitable counterion.

Abstract translation: 本发明包括具有式（I）结构的杂环阳离子活化剂，其能够与水溶液中的活性氧源形成过氧亚氨酸，或者是过氧亚氨酸形式，其中A，R 1，R 2，R 3，Y和Z 如本公开所定义。 式（I）的活化剂与选自阴离子物质的另一种化合物混合，所述阴离子物质能够与水溶液中的活性氧源形成过酸，或者呈过酸形式，或者非离子可极化活化剂和合适的平衡离子。

公开(公告)号：EP0968130A4

公开(公告)日：2002-08-14

申请号：EP97953040

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G ,  MITCHELL JAMES D

IPC: C07D295/14 ,  C01B13/02 ,  C07D295/02 ,  C07D295/15 ,  C11D1/62 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/00 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C07D211/26 ,  C07D211/34 ,  C07D265/12 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/02 ,  C11D3/3925 ,  C11D3/3947 ,  D06L4/12 ,  D06L4/17

Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butylmorpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is coctacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.

Abstract translation: 腈活化剂如N-烷基铵乙腈活化剂与活性氧源一起作为清洁和漂白组合物。 本发明优选的活化剂实例包括N-甲基吗啉鎓乙腈，N-丁基吗啉乙腈，N-己基吗啉乙腈和N-辛基吗啉鎓乙腈的盐。 特别优选的活化剂实施方案是N-甲基吗啉乙腈盐。 腈和活性氧反应形成漂白剂，该漂白剂用于制品上的污渍。 将经处理的污渍与致密气体接触，以提供基本上非水性污渍去除。 一个实施方案是其中将腈和活性氧设置在致密二氧化碳中的组合物。

公开(公告)号：EP0944609A4

公开(公告)日：2000-03-08

申请号：EP97948371

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KLOTTER KEVIN A ,  MUELLER JOSEF ,  MUELLER MICHAEL ,  MUENDINGER KLAUS ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHAEFER WOLFGANG ,  SCHUERMANN GREGOR ,  WIDDER RUDI ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39 ,  C07D211/26 ,  C07D211/34 ,  C07D295/12

CPC classification number: C07D295/15 ,  C11D3/3925

Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.

公开(公告)号：AU746382B2

公开(公告)日：2002-04-18

申请号：AU5451098

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： CHOY CLEMENT K ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  GARABEDIAN ARAM JR ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  PHILLIPPI MARTIN A ,  SMITH WILLIAM L

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/04 ,  C11D17/08 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D295/12 ,  C07D211/26 ,  C07D211/34

Abstract: The invention provides liquid cleaning or bleaching compositions containing compounds having the structure of Formula I wherein A is a saturated ring formed by five atoms in addition to the N1 atom, the five saturated ring atoms being four carbon atoms and a heteroatom, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3CN where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, and wherein Y is a generally anionic counterion and Z is in the range of 0 to 10. Additional, adjunct materials commonly found in liquid cleaning and bleaching compositions can be added.

公开(公告)号：PL346365A1

公开(公告)日：2002-02-11

申请号：PL34636597

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  KLOTTER KEVIN A ,  MUELLER MICHAEL ,  MUNDINGER KLAUS ,  PERKINS SARAH A ,  PHILLIPPI MARTIN A ,  SCHOLTISSEK MARTIN ,  SCHOENHERR MICHAEL ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02 ,  D06L4/12 ,  C11D7/38 ,  C07D265/30 ,  C07D295/12 ,  C07D211/26 ,  C07D211/34

Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.

公开(公告)号：AU742769B2

公开(公告)日：2002-01-10

申请号：AU5445698

申请日：1997-11-18

Applicant: CLOROX CO ,  BASF AG

Inventor： ANNEN ULRICH ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KLOTTER KEVIN A ,  MULLER JOSEF ,  MULLER MICHAEL ,  MUNDINGER KLAUS ,  PHILLIPPI MARTIN A ,  RULAND ALFRED ,  SCHAFER WOLFGANG ,  SCHURMANN GREGOR ,  WIDDER RUDI ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D265/12 ,  C07D291/00 ,  C07D295/15 ,  C11D3/39 ,  C07D295/12 ,  C07D211/26 ,  C07D211/34

Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.

公开(公告)号：HU9800642A2

公开(公告)日：1998-07-28

申请号：HU9800642

申请日：1996-06-03

Applicant: CLOROX CO

Inventor： ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALRED G

IPC: C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C07D295/14 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D1/58 ,  C11D1/62

Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.