公开(公告)号：AU5686998A

公开(公告)日：1998-06-22

申请号：AU5686998

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G ,  MITCHELL JAMES D

IPC: C07D295/14 ,  C01B13/02 ,  C07D295/02 ,  C07D295/15 ,  C11D1/62 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/00 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butyl morpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is contacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.

公开(公告)号：AU5360998A

公开(公告)日：1998-06-22

申请号：AU5360998

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：BR9713160A

公开(公告)日：2000-02-08

申请号：BR9713160

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：AU746352B2

公开(公告)日：2002-04-18

申请号：AU5360998

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C11D7/38 ,  C07D265/12 ,  C07D211/26 ,  C07D211/34

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：PH11997058671B1

公开(公告)日：2000-12-04

申请号：PH11997058671

申请日：1997-11-28

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06

Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.

公开(公告)号：EP0948455A4

公开(公告)日：2002-03-13

申请号：EP97950668

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  SUDBURY BARRY A ,  ZIELSKE ALFRED G

IPC: C07D295/14 ,  C07D295/15 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  D06L3/02 ,  H04B7/06 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/38618 ,  C11D3/3925 ,  C11D3/3947 ,  C11D3/42 ,  D06L4/12 ,  D06L4/17 ,  H04B7/0619

Abstract: The invention comprises heterocyclic cationic activators with the structure of Formula (I) that are capable of forming a peroxyimidic acid with a source of active oxygen in aqueous solution or being in a peroxyimidic form wherein A, R1, R2, R3, Y, and Z are as defined in the disclosure. The activators of Formula (I) are admixed with another compound selected from anionic species either capable of forming a peracid with a source of active oxygen in aqueous solution, or being in a peracid form, or a non-ionic polarizable activator and suitable counterion.

Abstract translation: 本发明包括具有式（I）结构的杂环阳离子活化剂，其能够与水溶液中的活性氧源形成过氧亚氨酸，或者是过氧亚氨酸形式，其中A，R 1，R 2，R 3，Y和Z 如本公开所定义。 式（I）的活化剂与选自阴离子物质的另一种化合物混合，所述阴离子物质能够与水溶液中的活性氧源形成过酸，或者呈过酸形式，或者非离子可极化活化剂和合适的平衡离子。

公开(公告)号：EP0968130A4

公开(公告)日：2002-08-14

申请号：EP97953040

申请日：1997-11-18

Applicant: CLOROX CO

Inventor： ALVAREZ VICENT E ,  ARBOGAST JAMES W ,  DELINE JAMES E ,  FOLAND LAFAYETTE D ,  KAARET THOMAS W ,  KLOTTER KEVIN A ,  PETRIN MICHAEL J ,  SMITH WILLIAM L ,  ZIELSKE ALFRED G ,  MITCHELL JAMES D

IPC: C07D295/14 ,  C01B13/02 ,  C07D295/02 ,  C07D295/15 ,  C11D1/62 ,  C11D3/28 ,  C11D3/386 ,  C11D3/39 ,  C11D3/395 ,  C11D3/42 ,  C11D7/54 ,  C11D17/00 ,  D06L3/02 ,  H04B7/06 ,  C01B3/00 ,  C07D211/26 ,  C07D211/34 ,  C07D265/12 ,  C11D7/38

CPC classification number: C07D295/15 ,  C11D3/02 ,  C11D3/3925 ,  C11D3/3947 ,  D06L4/12 ,  D06L4/17

Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butylmorpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is coctacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.

Abstract translation: 腈活化剂如N-烷基铵乙腈活化剂与活性氧源一起作为清洁和漂白组合物。 本发明优选的活化剂实例包括N-甲基吗啉鎓乙腈，N-丁基吗啉乙腈，N-己基吗啉乙腈和N-辛基吗啉鎓乙腈的盐。 特别优选的活化剂实施方案是N-甲基吗啉乙腈盐。 腈和活性氧反应形成漂白剂，该漂白剂用于制品上的污渍。 将经处理的污渍与致密气体接触，以提供基本上非水性污渍去除。 一个实施方案是其中将腈和活性氧设置在致密二氧化碳中的组合物。