公开(公告)号：EP1612230A4

公开(公告)日：2007-04-04

申请号：EP04724148

申请日：2004-03-29

Applicant: DAICEL CHEM

Inventor： ENDO TOSHIO ,  NAKAMOTO MASANOBU

IPC: C08G63/08 ,  C08G18/42 ,  C08G63/90

CPC classification number: C08G63/08 ,  C08G18/4269 ,  C08G63/90

Abstract: An object of the present invention is to provide a lactone-based polyester polyol containing a low-molecular-weight compound in a small amount and to provide a high-quality polyurethane resin. The present invention provides a lactone-based polyester polyol having a cyclic lactone content of 0.05% by weight or less, and provides a process for producing a lactone-based polyester polyol, wherein the process comprises a first step of adding a cyclic lactone, a low-molecular-weight polyol and/or a polycarboxylic acid, and an esterification catalyst to a reaction system and making ring-opening addition or esterification of the cyclic lactone to proceed until conversion of the cyclic lactone reaches a predetermined level; and a second step of continuously feeding the reaction mixture to a thin-film evaporator and subjecting the reaction mixture to evaporation in the form of thin film, thereby removing a low-molecular-weight compound from the system.

公开(公告)号：EP1632469A4

公开(公告)日：2006-10-04

申请号：EP04745777

申请日：2004-06-04

Applicant: DAICEL CHEM

Inventor： NAKAMOTO MASANOBU ,  ITO MASAAKI

IPC: C07C67/00 ,  C07C67/10 ,  C07B61/00 ,  C07C69/003 ,  C07C69/54

CPC classification number: C07C67/10 ,  C07C69/54

Abstract: A process for producing a lactone polyester/unsaturated monomer represented by the structural formula (1), characterized by reacting a carboxylated, radical-polymerizable, unsaturated monomer with a cyclic lactone in the presence of water added in an amount of 1 to 50 parts by weight per 100 parts by weight of the sum of the carboxylated, radical-polymerizable, unsaturated monomer and the cyclic lactone with the aid of an acid catalyst at ordinary pressure and subsequently conducting a dehydration reaction under vacuum so as to remove low-boiling matters to thereby form an ester linkage between the carboxylated, radical-polymerizable, unsaturated monomer and a lactone oligomer which is a by-product of a reaction initiated by the water added and reduce the hydroxy value to 5.0 mg-KOH/g or lower. Thus, a carboxy-terminated lactone polyester/unsaturated monomer of practical quality can be produced at low cost. Formula (1) (In the formula, R1, R2, R3, R4, R5, R6, and R7 each represents hydrogen or a substituent selected among C1-10 (un)substituted alkyl, (un)substituted aryl, (un)substituted alkoxycarbonyl, (un)substituted alkoxy, (un)substituted aryloxy, and halogeno; n is an integer of 1 to 7; and m is an integer of 1 to 100.)

Abstract translation: 一种方法产生结构式（1）的不饱和内酯衍生的聚酯单体：其中R 1，R 2，R 3，R 4，R 5，R 6和R 7各自表示选自氢原子， 取代或未取代的具有1-10个碳原子的烷基，取代或未取代的芳基，取代或未取代的烷氧基羰基，取代或未取代的烷氧基，取代或未取代的芳氧基和卤素原子; n表示1〜7的整数， m表示1〜100的整数，使用含羧基的自由基聚合性不饱和单体与环状内酯，使用酸性催化剂，在常压下，在1〜50重量份的水的存在下，向100重量份的 含羧基的可自由基聚合的不饱和单体和环状内酯的总量; 并在减压下进行脱水以除去低沸点组分，以在副产的水引发的内酯低聚物和含羧基的可自由基聚合的不饱和单体之间形成酯键，从而将羟值降低至5.0mg KOH / g以下 。 可以以低成本生产具有实际质量的具有末端羧基的不饱和内酯衍生的聚酯单体。

公开(公告)号：JP2004359656A

公开(公告)日：2004-12-24

申请号：JP2003194609

申请日：2003-06-06

Applicant: Daicel Chem Ind Ltd ,  ダイセル化学工業株式会社

Inventor： NAKAMOTO MASANOBU ,  ITO MASAAKI

IPC: C07C67/00 ,  C07B61/00 ,  C07C67/10 ,  C07C69/003 ,  C07C69/54

CPC classification number: C07C67/10 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an unsaturated monomer bearing carboxy terminal group for lactonic polyester with practical product quality in low cost.
SOLUTION: A radical-polymerizable unsaturated monomer bearing a carboxy group and a cyclic lactone are allowed to react with each other in the presence of water in an amount of 1-50 pts.wt. per 100 pts.wt. of the radial-polymerizable monomer bearing carboxy group and the cyclic lactone in total by using an acidic catalyst under normal pressure, followed by boiling under reduced pressure (reaction) to produce the unsaturated monomer for the lactonic polyester represented by structural formula (1).
COPYRIGHT: (C)2005,JPO&NCIPI

公开(公告)号：JP2000219843A

公开(公告)日：2000-08-08

申请号：JP2197999

申请日：1999-01-29

Applicant: DAICEL CHEM

Inventor： TAKAI HIDEYUKI ,  NAKAMOTO MASANOBU

IPC: C09D133/02

Abstract: PROBLEM TO BE SOLVED: To obtain an anticorrosive coating composition which solves the problem of the compatibility of an acrylic resin having excellent weather resistance with an epoxy resin or the like and has an excellent gloss holding property, by compounding an epoxy resin, a curing agent and a specific acrylic resin. SOLUTION: This anticorrosive coating composition comprises (A) an epoxy resin (an epoxy resin having two or more epoxy groups in the molecule and having an epoxy equivalent of preferably 150-600, more preferably 180-450, concretely a bisphenol type epoxy resin or the like), (B) a curing agent (a known epoxy resin curing agent, such as a polyamine-based curing agent), and (C) an acrylic resin having an acid value of >=15 [preferably an acrylic resin containing a monomer having a carboxyl group or a carboxyl group and a hydroxyl group (for example, acrylic acid or methacrylic acid) and further containing styrene in an amount of

公开(公告)号：JPH11349863A

公开(公告)日：1999-12-21

申请号：JP17962998

申请日：1998-06-11

Applicant: DAICEL CHEM

Inventor： TAKAI HIDEYUKI ,  NAKAMOTO MASANOBU

IPC: C09D5/16 ,  C09D123/00 ,  C09D153/02 ,  C09D155/04

Abstract: PROBLEM TO BE SOLVED: To provide an antifouling coating compsn. properly improved in adhesion to a substrate surface having a low chemical activity by incorporating a compd. having carbon-carbon double bonds and functional groups other than double bond in the molecule into a coating compsn. to be applied to a substrate of which at least the surface layer is a polyolefin layer. SOLUTION: An antifouling coating compsn. improved esp. in adhesion to the surface of a substrate comprising polyethylene, polypropylene, or the like is provided. The compd. to be compounded pref. has polydiene-derived carbon- carbon double bonds, and a suitable compd. is polybutadiene, polyisoprene, a styrene-butadiene-styrene copolymer, or a styrene-isoprene-styrene copolymer having part of polydiene-derived carbon-carbon double bonds epoxidized. Amino, carboxy, and hydroxy groups, etc., are listed as the functional groups other than epoxy group. A vinyl chloride-vinyl acetate copolymer, an alkyd resin, etc., are used as the main film-forming components.

公开(公告)号：JP2001114864A

公开(公告)日：2001-04-24

申请号：JP29987299

申请日：1999-10-21

Applicant: DAICEL CHEM

Inventor： TAKAI HIDEYUKI ,  NAKAMOTO MASANOBU

IPC: B05D7/24 ,  C08G59/20 ,  C08G59/68 ,  C08J7/04 ,  C08K5/521 ,  C08L33/14 ,  C08L63/00 ,  C09D133/14 ,  C09D163/00

Abstract: PROBLEM TO BE SOLVED: To obtain a coating material composition capable of obtaining a coating film hardness, lubricating property and close adhesive property with a metal, plastic or the like as almost equivalent to those of the conventional products without using a silicone, and to provide its production method and a coating material using the same composition. SOLUTION: This cation-curing type resin composition is obtained by adding (c) 0.1-20 pts. mass phosphoric acid alkyl ester and (d) 0.5-30 pts. mass cationic polymerization initiator to 100 pts. mass resin component consisting of (a) 20-90 mass % epoxy resin having a cationic polymerization activity and (b) 80-10 mass % acrylic resin having a functional group capable of reacting with a cationic species.

公开(公告)号：JP2004352803A

公开(公告)日：2004-12-16

申请号：JP2003150190

申请日：2003-05-28

Applicant: Daicel Chem Ind Ltd ,  Sankyo Lifetech Co Ltd ,  ダイセル化学工業株式会社 ,  三共ライフテック株式会社

Inventor： ENDO TOSHIRO ,  NAKAMOTO MASANOBU ,  TAKESHIBA HIDEO ,  YAMAZAKI TAKAAKI ,  ICHIHASHI TETSUYA

IPC: C08L101/00 ,  C08L67/04

Abstract: PROBLEM TO BE SOLVED: To provide a hindered amine compound suitable as a light stabilizer for resins.
SOLUTION: The hindered amine compound is represented by formula(1) [wherein, R
1 , R
2 , R
n+1 and R
n+2 are each H, a (substituted) 1-10C alkyl or the like; X
1 to X
4 are each a (substituted) 1-10C alkyl or the like; Y
1 to Y
5 are each H, a (substituted) 1-10C alkyl or the like; Y
6 is H, a (substituted) 1-10C alkyl or the like; n is an integer of 1-7; m is an integer of 1-100; p is an integer of 1-10; and q is an integer of 1-100].
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供适合作为树脂的光稳定剂的受阻胺化合物。 解决方案：受阻胺化合物由式（1）表示[其中R 1，R 2，R 2，R 2， 和R n + 2 分别为H，（取代的）1-10C烷基等; X 1 至X 4 分别为（取代的）1-10C烷基等; Y 1 至Y 5 分别为H，（取代的）1-10C烷基等; Y 6是H，（取代的）1-10 C烷基等; n为1-7的整数; m为1-100的整数; p是1-10的整数; q为1-100的整数]。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JPH04292620A

公开(公告)日：1992-10-16

申请号：JP5703491

申请日：1991-03-20

Applicant: DAICEL CHEM

Inventor： YUGAWA TAKAO ,  NAKAMOTO MASANOBU

IPC: B01J37/00 ,  C07B37/00 ,  C08G63/08 ,  C08G63/78 ,  C08K5/09 ,  C08L67/00 ,  C08L67/04

Abstract: PURPOSE:To provide a polylactone polyol composition containing a protonic acid and/or a Lewis acid to promote the ring-opening polymerization of lactone and remarkably shorten the necessary reaction time. CONSTITUTION:The objective polylactone polyol composition contains one or more kinds of protonic acid and/or Lewis acid. The protonic acid is, e.g. acetic acid, propionic acid, linoleic acid, phthalic acid and dimethyl phosphite and preferably fatty acid. The Lewis acid is, e.g. aluminum trichloride and boron halide and the total amount of the acid to be added to the composition is 0.1-0.5%.