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公开(公告)号:BRPI0402414B1
公开(公告)日:2014-12-09
申请号:BRPI0402414
申请日:2004-06-21
Applicant: EVONIK DEGUSSA GMBH
Inventor: KORTH KARSTEN DR , ALBERT PHILIPP DR , PIETER REIMUND DR , KLOCKMANN OLIVER DR , HASSE ANDRE , DESCHLER ULRICH DR , WITZSCHE SUSANN , KIEFER INGO
Abstract: New organosilicon compounds (I) are mercapto-, thiocyanato- and mono- and polysulfanyl-(ar)alkyl- and (alk)aryl-silanes, in which (each) silicon atom has 1-3 long-chain alk(en)oxy-, aryloxy, aralkoxy or tri(alk(en)yl, aralkyl or aryl)-siloxy substituents and 0-2 alkyl substituents, and mixtures of these. New organosilicon compounds are mercapto-, thiocyanato- and mono- and polysulfanyl-(ar)alkyl- and (alk)aryl-silanes of formula (I) and mixtures are claimed. [Image] R : R'O or 1-12 C alkyl; R' : 12-24 C monovalent alkyl or alkenyl, aryl, aralkyl or R''' 3Si; R''' : 1-30 C alkyl or alkenyl, aralkyl or aryl; R'' : (un)saturated aliphatic, aromatic or mixed aliphatic/aromatic divalent 1-30 C hydrocarbon group; and X : SH or SCN with n = 1 and m = 1, or S with n = 2 and m = 1-14. Independent claims are also included for the following: (1) preparation of (I); (2) rubber mixes containing rubber, filler, optionally other ancillaries and also compound(s) (I).
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公开(公告)号:AT353904T
公开(公告)日:2007-03-15
申请号:AT05017816
申请日:2005-08-17
Applicant: DEGUSSA
Inventor: KORTH KARSTEN DR , ALBERT PHILIPP DR , WOLF DORIT DR , SEEBALD STEFFEN DR , PIETER REIMUND DR , ALIG ALFRED
IPC: C07F7/18
Abstract: Mercaptoorganyl(alkoxysilanes) are produced by hydrogenating bis(alkoxysilylorganyl) polysulfides at less than 190[deg]C and less than 100 bar with hydrogen and a transition metal catalyst without the addition of water, alcohol, dihydrogen sulfide.
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公开(公告)号:AT325798T
公开(公告)日:2006-06-15
申请号:AT04025248
申请日:2004-10-23
Applicant: DEGUSSA
Inventor: KORTH KARSTEN DR , ALBERT PHILIPP DR , KIEFER INGO
IPC: C07F7/18
Abstract: Preparation of (mercaptoorganyl)alkoxysilanes (I) comprises reacting alkali metal sulfide with a mixture of (haloorganyl)alkoxysilane (II) and (haloorganyl)halosilane (III) in an alcohol with exclusion of air and at elevated pressure.
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公开(公告)号:DE102010031321A1
公开(公告)日:2012-01-19
申请号:DE102010031321
申请日:2010-07-14
Applicant: EVONIK DEGUSSA GMBH
Inventor: JUST ECKHARD , ALBERT PHILIPP DR
Abstract: Die Erfindung betrifft ein Verfahren zur Herstellung von 2-(Cyclohex-3-enyl)ethyl-silan, indem ein Silan mit mindestens einer Si-H-Bindung an 4-Vinylcyclohex-1-en addiert wird, wobei die Addition ohne Gegenwart eines Katalysators erfolgt, bevorzugt besteht die Addition aus der Umsetzung von 4-Vinylcyclohex-1-en mit einem Silan mit mindestens einer Si-H-Bindung. Ferner betrifft die Erfindung die Verwendung der katalysatorfrei hergestellten 2-(Cyclohex-3-enyl)ethyl-silane.
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公开(公告)号:DE502007000471D1
公开(公告)日:2009-04-16
申请号:DE502007000471
申请日:2007-01-29
Applicant: EVONIK DEGUSSA GMBH
Inventor: KORTH KARSTEN DR , HASSE ANDRE , ALBERT PHILIPP DR , KLOCKMANN OLIVER
IPC: C08K5/54
Abstract: Rubber mixes contain (A) styrene-butadiene rubber(s), (B) filler(s) and (C) organo(alkyl polyether silane) polysulfides with 1-12 sulfide groups and 2 substituted silyl-hydrocarbyl groups, in which each silyl groups has 1-3 substituents containing 2-9 (14-29 carbon) alkyl-polyether groups and 0-2 substituents selected from alkyl, alk(en)oxy, (alkyl)aryloxy and aralkyloxy groups. Rubber mixes contain (A) styrene-butadiene rubber(s), (B) filler(s) and (C) organo(alkyl polyether silane) polysulfides of formula (I): [(X)(X')(X")Si-R'] 2-S) m (I); X : an alkyl-polyether group O-((CR") 2) w-O-) tAlk with 14-29 C; t, w : 2-9; R" : H, phenyl or alkyl; Alk : branched or linear, (un)saturated, aliphatic, aromatic or mixed aliphatic/aromatic monovalent 10-25 C hydrocarbyl; X' : branched or linear alkyl, alkoxy or 2-25 C alkenyloxy, 6-35 C aryloxy, branched or linear 7-35 C alkylaryloxy or aralkyloxy or X; X" : branched or linear alkyl or alkoxy, 2-25 C alkenyloxy, 6-35 C aryloxy, branched or linear 7-35 C alkylaryloxy or aralkyloxy or X; R' : optionally substituted, branched or linear, (un)saturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent 1-30 C hydrocarbyl; m : 1-12 . An independent claim is included for production of this rubber mix by mixing the cited components.
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公开(公告)号:ES2250943T3
公开(公告)日:2006-04-16
申请号:ES04013567
申请日:2004-06-09
Applicant: DEGUSSA
Inventor: KORTH KARSTEN DR , ALBERT PHILIPP DR , PIETER REIMUND DR , KLOCKMANN OLIVER DR , HASSE ANDRE , DESCHLER ULRICH DR
Abstract: Compuestos orgánicos de silicio de la fórmula general I estando excluido el (3-tiocianato-propil)-tris- (trimetilsiloxi)silano, en la que los R son iguales o diferentes y significan un grupo R''O o un grupo alquilo de C1-C12, los R'' son iguales o diferentes y significan un grupo alquilo o alquenilo de C12-C24, ramificado o sin ramificar, un grupo arilo, un grupo aralquilo, univalentes, o R''''''3Si, con R¿¿¿ igual a un grupo alquilo o alquenilo de C1-C30, ramificado o sin ramificar, un grupo aralquilo o un grupo arilo, R¿¿ es un grupo hidrocarbilo bivalente de C1-C30, ramificado o sin ramificar, saturado o insaturado, alifático, aromático o alifático / aromático mixto, X es SH con n = 1 y m = 1, SCN con n = 1 y m = 1 o S con n = 2 y m = 1-14 y mezclas de ellos.
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公开(公告)号:AT321057T
公开(公告)日:2006-04-15
申请号:AT04024808
申请日:2004-10-19
Applicant: DEGUSSA
Inventor: KORTH KARSTEN DR , ALBERT PHILIPP DR , KIEFER INGO
IPC: C07F7/18
Abstract: Production of mercaptoorganyl alkoxysilanes comprises reacting an alkali metal hydrogen sulfide with a mixture of haloorganyl alkoxysilane and haloorganyl halosilane in an alcohol under pressure in a sealed vessel in the absence of oxygen.
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公开(公告)号:MY139418A
公开(公告)日:2009-09-30
申请号:MYPI20055961
申请日:2005-12-16
Applicant: EVONIK DEGUSSA GMBH
Inventor: HASSE ANDRE , ALBERT PHILIPP DR , KLOCKMANN OLIVER DR , KORTH KARSTEN DR , PIETER REIMUND DR
Abstract: 36 ABSTY ACT RUBBER MIXTURES RUBBER MIXTURES COMPRISING RUBBER, FILLERS, OPTIONALLY FURTHER RUBBER AUYILIAR@ES AND AT LEAST ONE 5 ORGANOSILANE OF THE GENERAL FORMULA T RIR2R3SIR4-SH (T) WHEREIN R' IS METHYL OR ETHYL, 10 R2 IS METHOXY, ETHOXY OR, -0-(Y-O),-X WHERE Y @ A BRANCHED OR UNBRANCHED, SATURATED OR UNSATURATED DIVALENT HVDROCARBON GROUP, X IS A CL- TO C9-ALKVI GROUP AND M @ 1-40, 15 R3 IS MELHVL, ETHYL OR R2, AND R4 IS A BRANCHED OR UNBRANCHED, SATURATED OR UNSATURATED, ALIPHATIC, AROMATIC OR MIXED 20 ALIPHATIC/AROMATIC DIVALENT C1-CI2 HYDROCARBON GROUP. THE RUBBER MIXTURES ACCORDING TO THE INVENTION ARE PREPARED BY MIXING RUBBER, FILLER, OPTIONAILY FURTHER RUBBER AUXILIARIES AND AT LEAST ONE ORGANOSILANE OF THE GENERAL FORMULA I. THE RUBBER MIXTLIR(@S CAN BE USED FOR 25 THE PROD'LICTION OF SHAPED ARTICLES.
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公开(公告)号:MY138113A
公开(公告)日:2009-04-30
申请号:MYPI20060241
申请日:2006-01-19
Applicant: EVONIK DEGUSSA GMBH
Inventor: KLOCKMANN OLIVER DR , ALBERT PHILIPP DR , HASSE ANDRE , KORTH KARSTEN DR , PIETER REIMUND DR
Abstract: THE INVENTION PROVIDES MERCAPTOSILANES OF THE GENERAL FORMULA I WHEREIN R1 IS AN ALKYL POLYETHER GROUP -O-(R5-O) M-R6. THEY ARE PREPARED BY A PROCEDURE IN WHICH A SILANE OF THE GENERAL FORMULA II IS SUBJECTED TO A CATALYSED REACTION WITH AN ALKYL POLYETHER R1-H, R7-OH BEING SPLITOFF, THE MOLAR RATIO OF THE ALKYL POLYETHERS R1-H TO THE SILANE OF THE GENERAL FORMULA II IS AT LEAST 0.5 AND R7-OH IS SEPARATED OFF FROM THE REACTION MIXTURE CONTINUOUSLY OR DISCONTINUOUSLY. THEY CAN BE USED IN SHAPED ARTICLES.
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公开(公告)号:DE502005000378D1
公开(公告)日:2007-03-29
申请号:DE502005000378
申请日:2005-08-17
Applicant: DEGUSSA
Inventor: KORTH DR , ALBERT PHILIPP DR , WOLF DORIT DR , SEEBALD STEFFEN DR , PIETER REIMUND DR , ALIG ALFRED
IPC: C07F7/18
Abstract: Mercaptoorganyl(alkoxysilanes) are produced by hydrogenating bis(alkoxysilylorganyl) polysulfides at less than 190[deg]C and less than 100 bar with hydrogen and a transition metal catalyst without the addition of water, alcohol, dihydrogen sulfide.
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