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公开(公告)号:JPH1081508A
公开(公告)日:1998-03-31
申请号:JP12823597
申请日:1997-05-19
Applicant: DEGUSSA
Inventor: KRAUSE HELMFRIED DR , ROTGERINK HANS LANSINK DR , TACKE THOMAS DR , PANSTER PETER DR , BURMEISTER ROLAND DR
IPC: B01J21/08 , B01J23/52 , B01J23/66 , B01J35/10 , B01J37/00 , C01B33/12 , C04B35/14 , C04B35/634 , C04B35/636 , C07B61/00 , C07C29/04 , C07C31/08 , C07C31/10 , C07C67/035 , C07C67/04 , C07C69/15 , C09C1/30
Abstract: PROBLEM TO BE SOLVED: To obtain compressed powder improved in purity, activity, selectivity, etc., by compressing powder obtained by drying a mixture of a specific silicon dioxide with methyl cellulose, microwax and/or polyethylene glycol and water and carrying out heat treatment of the compressed powder. SOLUTION: A volatile silicon compound is sprayed into a detonating gas frame comprising hydrogen and air to hydrolyze the silicon compound to afford silicon dioxide comprising >99.8wt.% SiO2 content and /g BET surface area, 0.5-1.3mL/g pure volume and 10-250N breakage strength and having
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公开(公告)号:BR9401145A
公开(公告)日:1994-11-01
申请号:BR9401145
申请日:1994-03-14
Applicant: DEGUSSA
Inventor: ALBERS PETER DR , BURMEISTER ROLAND DR , DELLER KLAUS DR , DESPEYROUX BERTRAND DR
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公开(公告)号:ES2099519T3
公开(公告)日:1997-05-16
申请号:ES94113926
申请日:1994-09-06
Applicant: DEGUSSA
Inventor: SCHUTZ PETER , BURMEISTER ROLAND DR , DESPEYROUX BERTRAND DR , MOSINGER HANS , KRAUSE HELMFRIED , DELLER KLAUS DR
Abstract: The invention relates to a moulded, activated fixed-bed Raney metal catalyst. The catalyst is obtained by moulding a powder of at least one catalyst alloy with a power of the pure catalyst metals with the addition of moulding aids and pore-forming materials and subsequent calcination at temperatures below 850 DEG C. During the calcination, the moulding aids and pore-forming materials burn. Alloy powder and metal powder sinter together in the course of this to give a mechanically stable and porous moulding. This moulding thus comprises the particles of the catalyst alloys which are bound by powder of the pure catalyst metals. It does not contain any catalytically inactive ceramic or vitreous binders. By leaching out the aluminium contained in the catalyst alloys using sodium hydroxide solution, the moulding is activated in a surface shell.
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公开(公告)号:AT148375T
公开(公告)日:1997-02-15
申请号:AT94113926
申请日:1994-09-06
Applicant: DEGUSSA
Inventor: SCHUETZ PETER , BURMEISTER ROLAND DR , DESPEYROUX BERTRAND DR , MOESINGER HANS , KRAUSE HELMFRIED , DELLER KLAUS DR
Abstract: The invention relates to a moulded, activated fixed-bed Raney metal catalyst. The catalyst is obtained by moulding a powder of at least one catalyst alloy with a power of the pure catalyst metals with the addition of moulding aids and pore-forming materials and subsequent calcination at temperatures below 850 DEG C. During the calcination, the moulding aids and pore-forming materials burn. Alloy powder and metal powder sinter together in the course of this to give a mechanically stable and porous moulding. This moulding thus comprises the particles of the catalyst alloys which are bound by powder of the pure catalyst metals. It does not contain any catalytically inactive ceramic or vitreous binders. By leaching out the aluminium contained in the catalyst alloys using sodium hydroxide solution, the moulding is activated in a surface shell.
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公开(公告)号:DE19619961A1
公开(公告)日:1997-11-20
申请号:DE19619961
申请日:1996-05-17
Applicant: DEGUSSA
Inventor: KRAUSE HELMFRIED DR , ROTGERINK HANS LANSINK DR , TACKE THOMAS DR , PANSTER PETER DR , BURMEISTER ROLAND DR
IPC: B01J21/08 , B01J23/52 , B01J23/66 , B01J35/10 , B01J37/00 , C01B33/12 , C04B35/14 , C04B35/634 , C04B35/636 , C07B61/00 , C07C29/04 , C07C31/08 , C07C31/10 , C07C67/035 , C07C67/04 , C07C69/15 , C09C1/30 , B01J2/22 , B01J31/04 , B01J27/182
Abstract: Pressings based on pyrogenic silica (SiO2) have an outside diameter of 0.8-20 mm, BET surface area of 30-400 m /g, pore volume of 0.5-1.3 ml/g, breaking strength of 10-250 N, composition > 99.8 wt.% SiO2 and
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公开(公告)号:DK0648534T3
公开(公告)日:1997-06-16
申请号:DK94113926
申请日:1994-09-06
Applicant: DEGUSSA
Inventor: BURMEISTER ROLAND DR , DELLER KLAUS DR , DESPEYROUX BERTRAND DR , SCHUETZ PETER , MOESINGER HANS , KRAUSE HELMFRIED
Abstract: The invention relates to a moulded, activated fixed-bed Raney metal catalyst. The catalyst is obtained by moulding a powder of at least one catalyst alloy with a power of the pure catalyst metals with the addition of moulding aids and pore-forming materials and subsequent calcination at temperatures below 850 DEG C. During the calcination, the moulding aids and pore-forming materials burn. Alloy powder and metal powder sinter together in the course of this to give a mechanically stable and porous moulding. This moulding thus comprises the particles of the catalyst alloys which are bound by powder of the pure catalyst metals. It does not contain any catalytically inactive ceramic or vitreous binders. By leaching out the aluminium contained in the catalyst alloys using sodium hydroxide solution, the moulding is activated in a surface shell.
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公开(公告)号:DE59401698D1
公开(公告)日:1997-03-13
申请号:DE59401698
申请日:1994-09-06
Applicant: DEGUSSA
Inventor: SCHUETZ PETER , BURMEISTER ROLAND DR , DESPEYROUX BERTRAND DR , MOESINGER HANS , KRAUSE HELMFRIED , DELLER KLAUS DR
Abstract: The invention relates to a moulded, activated fixed-bed Raney metal catalyst. The catalyst is obtained by moulding a powder of at least one catalyst alloy with a power of the pure catalyst metals with the addition of moulding aids and pore-forming materials and subsequent calcination at temperatures below 850 DEG C. During the calcination, the moulding aids and pore-forming materials burn. Alloy powder and metal powder sinter together in the course of this to give a mechanically stable and porous moulding. This moulding thus comprises the particles of the catalyst alloys which are bound by powder of the pure catalyst metals. It does not contain any catalytically inactive ceramic or vitreous binders. By leaching out the aluminium contained in the catalyst alloys using sodium hydroxide solution, the moulding is activated in a surface shell.
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公开(公告)号:BR9304860A
公开(公告)日:1994-05-31
申请号:BR9304860
申请日:1993-11-26
Applicant: DEGUSSA
Inventor: BURMEISTER ROLAND DR , DELLER KLAUS DR , DESPEYROUX BERTRAND DR
Abstract: The invention relates to a process for the uniform and reproducible shell impregnation of fixed-bed catalyst supports present as bulk material by application of impregnation solutions, divided into droplets, of catalytically active components to the catalyst supports circulated in a tank. By appropriate choice of the spray parameters, in particular of the drop-size spectrum, the amount of solvent and the amount of impregnation solution sprayed per tank revolution, the catalyst supports can be furnished with outstandingly uniform shells.
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公开(公告)号:DE19607494A1
公开(公告)日:1997-09-04
申请号:DE19607494
申请日:1996-02-28
Applicant: DEGUSSA
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公开(公告)号:DE4427574C2
公开(公告)日:1997-08-14
申请号:DE4427574
申请日:1994-08-04
Applicant: DEGUSSA
Inventor: DELLER KLAUS DR , KRAUSE HELMFRIED , BURMEISTER ROLAND DR
IPC: B30B11/00 , B01J21/04 , B01J21/06 , B01J21/08 , B01J35/02 , B01J37/00 , B28B3/00 , C01B33/12 , C04B35/14 , C04B35/628 , C04B35/632 , C04B35/636 , C04B38/00 , C07B61/00 , B01J2/22
Abstract: Compacts produced from a pyrogenically produced oxide, magnesium stearate, methyl cellulose and urea are mixed together in the presence of water, compacted, dried, comminuted to a powder, and the powder is pressed with an isostatic press to compacts and the compacts tempered. The resulting compacts have an outside diameter of 16 to 100 mm.
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