公开(公告)号：AU2005297591A1

公开(公告)日：2006-04-27

申请号：AU2005297591

申请日：2005-10-10

Applicant: UHDE GMBH ,  DEGUSSA

Inventor： LANGANKE BERND ,  BUKER KARSTEN ,  HAUSMANN RALF ,  SCHIRRMEISTER STEFFEN ,  GEISSELMANN ANDREAS ,  MARKOWZ GEORG

IPC: B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J23/58 ,  B01J37/02 ,  C07C67/055

Abstract: Synthesis reactor (I) for preparing vinyl acetate monomer by catalytically reacting gaseous ethylene, acetic acid and oxygen or oxygen containing gas, is a barrier reactor. (I) comprises several reaction chambers in which the catalytic synthesis takes place, where the free conduit in each reaction chamber has dimension less than 2000 mu m and the wall of the chambers is coated with catalysts and is indirectly cooled. An independent claim is also included for a catalyst used in (I) comprising a palladium content of 0.5-10 (preferably 0.8-5) wt.%.

公开(公告)号：SG182196A1

公开(公告)日：2012-07-30

申请号：SG2012043378

申请日：2005-10-10

Applicant: EVONIK DEGUSSA GMBH

Inventor： BUEKER KARSTEN ,  SCHIRRMEISTER STEFFEN ,  LANGANKE BERND ,  MARKOWZ GEORG ,  HAUSMANN RALF ,  GEISSELMANN ANDREAS

Abstract: 15The invention relates to a synthesis reactor and to a method for producing vinyl acetate, in which gaseous ethylene and acetic acid, in addition to oxygen or gases containing oxygen, react catalytically. The inventive synthesis reactor is a wall reactor, in which the catalytic synthesis takes place in a plurality of reaction chambers, whose free flow cross-sections measure less than 2000 pm, preferably 1000 pm and whose indirectly cooled walls are coated with a palladium-gold catalyst.

公开(公告)号：SG182195A1

公开(公告)日：2012-07-30

申请号：SG2012043360

申请日：2005-10-10

Applicant: EVONIK DEGUSSA GMBH

Inventor： BUEKER KARSTEN ,  SCHIRRMEISTER STEFFEN ,  LANGANKE BERND ,  MARKOWZ GEORG ,  HAUSMANN RALF ,  GEISSELMANN ANDREAS

Abstract: 15The invention relates to a synthesis reactor and to a method for producing vinyl acetate, in which gaseous ethylene and acetic acid, in addition to oxygen or gases containing oxygen, react catalytically. The inventive synthesis reactor is a wall reactor, in which the catalytic synthesis takes place in a plurality of reaction chambers, whose free flow cross-sections measure less than 2000 pm, preferably 1000 pm and whose indirectly cooled walls are coated with a palladium-gold catalyst.

公开(公告)号：CA2584173A1

公开(公告)日：2006-04-27

申请号：CA2584173

申请日：2005-10-10

Applicant: DEGUSSA ,  UHDE GMBH

Inventor： BUEKER KARSTEN ,  HAUSMANN RALF ,  SCHIRRMEISTER STEFFEN ,  GEISSELMANN ANDREAS ,  LANGANKE BERND ,  MARKOWZ GEORG

IPC: B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J23/58 ,  B01J37/02 ,  C07C67/055

Abstract: Synthesis reactor (I) for preparing vinyl acetate monomer by catalytically reacting gaseous ethylene, acetic acid and oxygen or oxygen containing gas, is a barrier reactor. (I) comprises several reaction chambers in which the catalytic synthesis takes place, where the free conduit in each reaction chamber has dimension less than 2000 mu m and the wall of the chambers is coated with catalysts and is indirectly cooled. An independent claim is also included for a catalyst used in (I) comprising a palladium content of 0.5-10 (preferably 0.8-5) wt.%.

公开(公告)号：DE102004050585A1

公开(公告)日：2006-04-20

申请号：DE102004050585

申请日：2004-10-15

Applicant: DEGUSSA ,  UHDE GMBH

Inventor： BUEKER KARSTEN ,  SCHIRRMEISTER STEFFEN ,  LANGANKE BERND ,  GEISELMANN ANDREAS ,  MARKOWZ GEORG ,  HAUSMANN RALF

IPC: C07C69/15 ,  C07C67/055

Abstract: Synthesis reactor (I) for preparing vinyl acetate monomer by catalytically reacting gaseous ethylene, acetic acid and oxygen or oxygen containing gas, is a barrier reactor. (I) comprises several reaction chambers in which the catalytic synthesis takes place, where the free conduit in each reaction chamber has dimension less than 2000 mu m and the wall of the chambers is coated with catalysts and is indirectly cooled. An independent claim is also included for a catalyst used in (I) comprising a palladium content of 0.5-10 (preferably 0.8-5) wt.%.

公开(公告)号：AU2054402A

公开(公告)日：2002-05-06

申请号：AU2054402

申请日：2001-09-08

Applicant: DEGUSSA

Inventor： REISINGER MARTIN ,  HAUSMANN RALF ,  CHEN BAOSHU ,  TACKE THOMAS ,  STOCHNIOL GUIDO ,  PANSTER PETER

IPC: B01D53/86 ,  B01D53/94 ,  B01J23/40 ,  B01J23/63 ,  B01J27/053 ,  B01J37/02 ,  B01J37/14

Abstract: The invention relates to a high performance catalyst containing a layer on an inert carrier body comprising noble metals from the platinum group deposited on support materials. The catalyst is characterised in that, the layer comprises platinum deposited in a washcoat consisting of A1203 which is stabilized with lanthana (La203), ceria (CeO2), which is stabilized with zirconia (ZrO2) and praseodymium (Pr6011). The supprot is promoted by sulfur-containing compounds which come from at least one of following compounds: platinum sulfite (PtSO3), sulfuric acid (H2SO4), ammonium sulfate ((NH4)2SO4), titanium oxysulfate (TiOSO4), titanium sulfate (Ti2(SO4)3), and zirconium sulfate (Zr(SO4)2).

公开(公告)号：CA2426315A1

公开(公告)日：2002-05-02

申请号：CA2426315

申请日：2001-09-08

Applicant: DEGUSSA

Inventor： STOCHNIOL GUIDO ,  TACKE THOMAS ,  REISINGER MARTIN ,  HAUSMANN RALF ,  CHEN BAOSHU ,  PANSTER PETER ,  KREUZER THOMAS ,  MUSSMANN LOTHAR ,  LINDNER DIETER ,  HARRIS MICHAEL ,  LOX EGBERT

IPC: B01D53/86 ,  B01D53/94 ,  B01J23/40 ,  B01J23/63 ,  B01J27/053 ,  B01J37/02 ,  B01J37/14

Abstract: The invention relates to a high performance catalyst containing a layer on a n inert carrier body comprising noble metals from the platinum group deposited on support materials. The catalyst is characterised in that, the layer comprises platinum deposited in a washcoat consisting of Al203 which is stabilized with lanthana (La2O3), ceria (CeO2), which is stabilized with zirconia (ZrO2) and praseodymium (Pr6O11). The supprot is promoted by sulfur - containing compounds which come from at least one of following compounds: platinum sulfite (PtSO3), sulfuric acid (H2SO4), ammonium sulfate ((NH4)2SO4 ), titanium oxysulfate (TiOSO4), titanium sulfate (Ti2(SO4)3), and zirconium sulfate (Zr(SO4)2).

公开(公告)号：BR112013010907A2

公开(公告)日：2016-09-13

申请号：BR112013010907

申请日：2011-10-19

Applicant: EVONIK DEGUSSA GMBH

Inventor： TRIONFETTI CRISTIANO ,  FUCHS MANFRED ,  HAUSMANN RALF ,  RÖDER STEFAN

IPC: B01J31/02 ,  B01J31/10 ,  B01J31/12 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  C07C67/03 ,  C08G77/28

Abstract: processo para a preparação de catalisador com suporte e uso do catalisador para a esterificação de ácido graxos livres em óleo vegetal. a presente invenção refere-se a um processo para a preparação de um catalisador com suporte baseado no material inorgânico hidroxilado selecionado do grupo que consiste em sílica (sio~ 2~), alumina (al~ 2~o~ 3~), titânia (tio~ 2~), zircônia (zro~ 2~), óxido de lantânio (la~ 2~o~ 3~) ou misturas dos mesmos, caracterizado pelo fato de que o material inorgânico hidroxilado está em contato com compostos organossilíco selecionado do grupo que consiste na fórmula 1 isto é, [(ro) ysi-[(ro) ysi]y-o-si (ro) y] ou na fórmula 2 isto é, (ro) y-si-r^ 1^-s~ 2-4~-r^ 1^-si- (ro) y com r sendo alquila e r^ 1~ sendo um alquileno linear ou ramificado possuindo de 1 a 4 5 átomo de carbono e y sendo um número inteiro de 1 a 3.

公开(公告)号：SG149035A1

公开(公告)日：2009-01-29

申请号：SG2008093452

申请日：2005-10-10

Applicant: UHDE GMBH ,  EVONIK DEGUSSA GMBH

Inventor： BUEKER KARSTEN ,  SCHIRRMEISTER STEFFEN ,  LANGANKE BERND ,  MARKOWZ GEORG ,  HAUSMANN RALF ,  GEISSELMANN ANDREAS

Abstract: REACTOR AND METHOD FOR SYNTHESISING VINYL ACETATE IN THE GASEOUS PHASE The invention relates to a synthesis reactor and to a method for producing vinyl acetate, in which gaseous ethylene and acetic acid, in addition to oxygen or gases containing oxygen, react catalytically. The inventive synthesis reactor is a wall reactor, in which the catalytic synthesis takes place in a plurality of reaction chambers whose free flow cross-sections measure less than preferably and whose indirectly cooled walls are coated with a palladium-gold catalyst.