Abstract:
Raney-Kupfer, das mit mindestens einem Metall aus der Gruppe Eisen und/oder Edelmetallen dotiert ist, wird als Katalysator bei der Dehydrierung von Alkoholen eingesetzt. Als erste Alternative wird ein Raney-Kupfer-Katalysator beschrieben bei dem die ursprüngliche Legierung mehr als 50% Kupfer enthält, sodaß der entgültige Katalysator mehr restliches Aluminium enthält als man normalerweise unter denselben Aktivierungsbedingunggen findet. Als zweite Alternative wird ein Raney-Kupfer-Katalysator offenbart bei dem die ursprüngliche Legierung in Luftatmosphäre bei Temperaturen höher als 500°C vor der Aktivierung calziniert wurde.
Abstract:
Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.
Abstract:
A shaped, activated, fixed-bed Raney metal catalyst prepared by a method comprising preparing a mixture of powders comprising at least one catalyst alloy of (1) at least one catalytically active Raney process metal, a leachable alloy component and optionally a promoter, (2) at least one binder containing at least one pure Raney metal and (3) a moistening agent. Shaping, calcining and activating said catalyst and doping said catalyst with rhenium.
Abstract:
A fixed bed catalyst of the Raney-type is produced from metal alloying fibers and/or flakes formed according to a crucible metal extraction process, and then tabletting, and pressing into mats and/or filling into cartridges.
Abstract:
Metal catalysts consist of hollow molds. An Independent claim is also included for the production of metal catalysts comprising spraying metal powders together with a binder onto molds made of combustible material, i.e. polystyrene, and calcining the material forming the hollow mold. Preferred Features: The catalysts comprise hollow spheres having a diameter of 0.5-20 mm and a wall thickness of 0.1-5 mm. The catalysts have an impermeable casing having an open porosity of maximum 80% and made up of different layers.
Abstract:
Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.
Abstract:
A fixed bed catalyst of the Raney-type is produced from metal alloying fibers and/or flakes formed according to a crucible metal extraction process, and then tabletting, and pressing into mats and/or filling into cartridges.
Abstract:
In the overall methods of hydrogenating esters and maleic anhydride, which methods comprise a hydration reaction, comprising conducting the hydration reaction in the presence of the shaped Raney metal fixed-bed catalysts of the invention.
Abstract:
Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.