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    PRODUCTION OF BIS(SILYLORGANYL)-POLYSULFANE
    1.
    发明专利
    PRODUCTION OF BIS(SILYLORGANYL)-POLYSULFANE 失效

    公开(公告)号：JPH10175981A

    公开(公告)日：1998-06-30

    申请号：JP34005697

    申请日：1997-12-10

    Applicant: DEGUSSA

    Inventor： MUENZENBERG JOERG DR ,  PANSTER PETER DR ,  PRINZ MATTHIAS

    IPC: C07F7/08 ,  C01B17/38 ,  C01B17/42 ,  C01D13/00 ,  C01G9/00 ,  C07F7/18

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in a shorter time than the cases with prior arts. SOLUTION: This compound, a bis(silylorganyl)-polysulfane of formula I: (R R R SiR )2 SX, is obtained by reaction between a haloalkyl alkoxysilane or haloalkoxysilane of formula II: R R R SiR and a polysulfide of formula III: M2 SX. In this case, in the 1st process, a dehydrated polysulfide is produced from the polysulfide of formula III at 60-300 deg.C under a vacuum by reaction of a crystal water-contg. sulfide hydrate with sulfur. In the above, R , R and R are each a 1-8C branched or non-branched alkyl and/or alkoxy (in this case, there exists at least one alkoxy group) or an aryl group (esp. phenyl, toluyl or benzyl); R is a 1-8C (pref. 1-4C) divalent alkylidene group or (CH2 )n -C6 H4 -(CH2 )n ((n) is 1-4); (x) is a number larger than 1 (pref. 2-8); X is a halogen atom such as Cl, Br or I; M is an alkali metal cation, semialkaline earth metal cation or zinc cation.

    PRODUCTION OF PROPYLSILANE
    2.
    发明专利
    PRODUCTION OF PROPYLSILANE 失效

    公开(公告)号：JP2000198791A

    公开(公告)日：2000-07-18

    申请号：JP35206299

    申请日：1999-12-10

    Applicant: DEGUSSA

    Inventor： KRAEUTER THOMAS ,  SEEBALD STEFFEN DR ,  BATZ-SOH CHRISTOPH DR ,  KARCH RALF DR ,  PRINZ MATTHIAS ,  LANSINK ROTGERINK HERMANUS G J

    IPC: B01J23/42 ,  B01J23/62 ,  C07B61/00 ,  C07F7/12 ,  C07F7/14

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in high selectivity and in high yield under suppression of undesired side-reactions by adding a specific allyl compound to a specific silane in the presence of a specific catalyst under specific conditions. SOLUTION: The addition reaction of an allyl compound of the formula: H2C=CH-CH2X (X is Cl, Br, I or the like), for example, allyl chloride to a silane of the formula: R2R3R4SiH (R2-R4 are each H, a halogen, a 1-6C alkyl or the like) (preferably trichlorosilane) is carried out at 0-200 deg.C and at 200 millibar - 10 bar, preferably in the presence of a multielement catalyst supported on a carrier, for example, activated carbon, in which one of these elements is platinum, to give the objective three-functional compound (3- chloropropyltrichlorosilane). The other elements in the multielement catalyst are preferably Ti or the like and the molar ratios of the platinum to other elements on the carrier are preferably 0.05/1-20/1.

    PRODUCTION OF PROPYLSILANE FUNCTIONALIZED AT THIRD POSITION
    3.
    发明专利
    PRODUCTION OF PROPYLSILANE FUNCTIONALIZED AT THIRD POSITION 失效

    公开(公告)号：JP2000026478A

    公开(公告)日：2000-01-25

    申请号：JP15981099

    申请日：1999-06-07

    Applicant: DEGUSSA

    Inventor： BATZ-SOH CHRISTOPH DR ,  KARCH RALF DR ,  SEEBALD STEFFEN DR ,  PRINZ MATTHIAS

    IPC: B01J31/22 ,  C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/14 ,  C07F7/18

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a propylsilane functionalized at the third position by reacting hydrogensilane with an allyl compound under the catalytic action of platinum. SOLUTION: A propylsilane functionalized at the third position is produced by the addition reaction of an allyl compound of the formula: H2C=CH-CH2X (X is Cl, Br, I, F, CN, SCN, SH, SR, OH, NRR1 or OR; R and R are each a 1-6C alkyl or a 3-7C aryl) with a silane of the formula: R2R3R4SiH [R2 to R4 are each H, a halogen, a 1-6C alkyl, a 1-6C haloalkyl, a 3-6C allyl, a 1-4C alkoxy, phenyl, an aryl or an aralkyl] at the reaction temperature of 0-200 deg.C and 800 mbar to 5 bar in the presence of a platinum catalyst having at least one kind of ligands containing sulfur.

    4.
    发明专利
    未知

    公开(公告)号：DE59710608D1

    公开(公告)日：2003-09-25

    申请号：DE59710608

    申请日：1997-11-14

    Applicant: DEGUSSA

    Inventor： MUENZENBERG DR ,  PANSTER DR ,  PRINZ MATTHIAS

    IPC: C07F7/08 ,  C01B17/38 ,  C01B17/42 ,  C01D13/00 ,  C01G9/00 ,  C07F7/18

    Abstract: A method for the preparation of bis(silyl-organyl)-poly-sulphane of formula (I) comprises reacting halo(alkyl)alkoxysilane of formula (II) with a polysulphide of formula (III): (R R R SiR )2Sx (I) R R R SiR X (II) M2Sx (III) R -R = 1-8C alkyl, 1-8C alkoxy or aryl (preferably phenyl, toluyl or benzyl); R = 1-8 (1-4)C alkylidene or (CH2)n-C6H4-(CH2)n-; n = 1-4; x = greater than 1 (2-8) for (I), or 2-8 for polysulphide; X = halogen, eg. Cl, Br or I; and M = alkali metal cation or an alkaline earth metal or zinc cation equivalent, with the provision that at R -R

    6.
    发明专利
    未知

    公开(公告)号：ES2202534T3

    公开(公告)日：2004-04-01

    申请号：ES97119985

    申请日：1997-11-14

    Applicant: DEGUSSA

    Inventor： MUNZENBERG JORG DR ,  PANSTER PETER DR ,  PRINZ MATTHIAS

    IPC: C01B17/38 ,  C01B17/42 ,  C01D13/00 ,  C07F7/08 ,  C01G9/00 ,  C07F7/18

    Abstract: A method for the preparation of bis(silyl-organyl)-poly-sulphane of formula (I) comprises reacting halo(alkyl)alkoxysilane of formula (II) with a polysulphide of formula (III): (R R R SiR )2Sx (I) R R R SiR X (II) M2Sx (III) R -R = 1-8C alkyl, 1-8C alkoxy or aryl (preferably phenyl, toluyl or benzyl); R = 1-8 (1-4)C alkylidene or (CH2)n-C6H4-(CH2)n-; n = 1-4; x = greater than 1 (2-8) for (I), or 2-8 for polysulphide; X = halogen, eg. Cl, Br or I; and M = alkali metal cation or an alkaline earth metal or zinc cation equivalent, with the provision that at R -R

    8.
    发明专利
    未知

    公开(公告)号：DE19825793C1

    公开(公告)日：2000-01-05

    申请号：DE19825793

    申请日：1998-06-10

    Applicant: DEGUSSA

    Inventor： BATZ-SOHN CHRISTOPH ,  KARCH RALF ,  SEEBALD STEFFEN ,  PRINZ MATTHIAS

    IPC: B01J31/22 ,  C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/14 ,  C07F7/18

    Abstract: Preparation of 3-functionalized propylsilanes (I) comprises addition of allyl compounds (II) to silanes (III) at 0-200 degrees C and 800 mbar to 6 bar in the presence of a platinum catalyst that has ligand(s) containing sulfur. Preparation of 3-functionalized propylsilanes (I) comprises addition of allyl compounds of formula (II) to silanes of formula (III) at 0-200 degrees C and 800 mbar to 6 bar in the presence of a platinum (Pt) catalyst (IV) that has ligand(s) containing sulfur: X = chlorine (Cl), bromine (Br), iodine (I), fluorine (F), cyano (CN), thiocyanato (SCN), mercapto (SH), organylthio (SR), hydroxyl (OH), amino (NRR ) or organyloxy (OR); R, R = 1-6 carbon (C) alkyl or 3-7 C aryl; R , R , R = hydrogen (H), halogen, 1- C (halo)alkyl, 3-6 C allyl, 1-4 C alkoxy, phenyl, aryl or aralkyl. An Independent claim is also included for the use of (IV) in this addition reaction.

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