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公开(公告)号：JP2000143574A
公开(公告)日：2000-05-23
申请号：JP31832599
申请日：1999-11-09
Applicant: DEGUSSA
Inventor： WEBER ROBERT , KEIM WILHELM , JAEGER BERND , HAAS THOMAS , VANHEERTUM RUDOLF
Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound with high selectivity and at high yield without using much catalyst by reacting an oxirane with CO and H2 in the presence of a catalyst i.e., a transition metal modified with a specified ligand. SOLUTION: This compound is (E) a β-hydroxyaldehyde and is obtained by reacting (B) a 1,2-oxirane with (C) carbon monoxide and (D) hydrogen in the presence of (A) a transition metal modified with a phosphorus-oxygen-ligand or nitrogen-oxygen-ligand and working as a catalyst. A cobolt-carbonyl-catalyst combined with phosphine oxide is preferably used as the component A and the ratio of oxygen based on phosphorus in the phosphine oxide is preferably 0.5-2.0. High yield is expectable thereby without using any accelerant.
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2.发明申请
公开(公告)号：WO2006050781A2
公开(公告)日：2006-05-18
申请号：PCT/EP2005010997
申请日：2005-10-13
Applicant: DEGUSSA , ADRIAENSSENS JOZEF , BATHEN DIETER , BAEUML MANFRED , BEWERSDORF MARTIN , GAIL ERNST , LIESER THOMAS , MUELLER THOMAS , PELGRIMS IVAN , RINNER MICHAEL , WEBER ROBERT
Inventor： ADRIAENSSENS JOZEF , BATHEN DIETER , BAEUML MANFRED , BEWERSDORF MARTIN , GAIL ERNST , LIESER THOMAS , MUELLER THOMAS , PELGRIMS IVAN , RINNER MICHAEL , WEBER ROBERT
CPC classification number: B01J19/0053 , B01J12/007 , B01J19/2415 , C01C3/0229
Abstract: The invention relates to reaction tubes provided with catalyst coated inserts whose main faces are inclined at an angle equal to or less than 10° with respect to the longitudinal axis of a reaction tube, wherein said reaction tubes enable to attain an improved yield for a hydrogen cyanide production according to a BMA process without increased sooting in the reaction tubes.
Abstract translation: 反应管与其主面是倾斜的不超过10度至反应管的纵向轴线，导致产生由BMA工艺提高产量氰化氢而不增加反应管的碳污损催化剂涂覆的刀片。
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公开(公告)号：DE602004026443D1
公开(公告)日：2010-05-20
申请号：DE602004026443
申请日：2004-02-18
Applicant: EVONIK DEGUSSA GMBH
Inventor： VON HIPPEL LUKAS , WEBER ROBERT , BEWERSDORF MARTIN , GAIL ERNST , SCHWARZ HELMUT
Abstract: The invention relates to an improvement to the BMA process for the production of hydrogen cyanide from methane and ammonia in the presence of a platinum-containing catalyst. The problem of sooting, and thus the decrease in activity, of the catalysts can be reduced, or the activity increased, in that the catalyst is doped with an element from the series Cu, Ag, Au, Pd and W. The doping is preferably in the range of 0.01 to 20 mole % doping element, based on Pt.
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公开(公告)号：AU2004215667A1
公开(公告)日：2004-09-10
申请号：AU2004215667
申请日：2004-02-18
Applicant: DEGUSSA
Inventor： WEBER ROBERT , BEWERSDORF MARTIN , GAIL ERNST , SCHWARZ HELMUT , HIPPEL LUKAS VON
Abstract: The invention relates to an improvement to the BMA process for the production of hydrogen cyanide from methane and ammonia in the presence of a platinum-containing catalyst. The problem of sooting, and thus the decrease in activity, of the catalysts can be reduced, or the activity increased, in that the catalyst is doped with an element from the series Cu, Ag, Au, Pd and W. The doping is preferably in the range of 0.01 to 20 mole % doping element, based on Pt.
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公开(公告)号：ES2343959T3
公开(公告)日：2010-08-13
申请号：ES04712015
申请日：2004-02-18
Applicant: EVONIK DEGUSSA GMBH
Inventor： VON HIPPEL LUKAS , WEBER ROBERT , BEWERSDORF MARTIN , GAIL ERNST , SCHWARZ HELMUT
Abstract: Proceso para la producción de cianuro de hidrógeno por el denominado proceso BMA, en el cual un hidrocarburo alifático que tiene 1 a 4 átomos C se hace reaccionar con amoníaco en presencia de un catalizador que contiene platino a 1000 hasta 1350ºC y se separa cianuro de hidrógeno del gas de reacción formado, caracterizado porque el platino del catalizador está impurificado con oro.
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Patent Agency Ranking
公开(公告)号：DE19852104A1
公开(公告)日：2000-05-18
申请号：DE19852104
申请日：1998-11-12
Applicant: DEGUSSA
Inventor： WEBER ROBERT , KEIM WILHELM , JAEGER BERND , HAAS THOMAS , VANHEERTUM RUDOLF
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公开(公告)号：AU2004229151A1
公开(公告)日：2004-10-28
申请号：AU2004229151
申请日：2004-04-02
Applicant: DEGUSSA
Inventor： BATHEN DIETER , WEBER ROBERT , RINNER MICHAEL , MENNERICH HEIKO , GAIL ERNST , BEWERSDORF MARTIN
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公开(公告)号：DE10309209A1
公开(公告)日：2004-09-09
申请号：DE10309209
申请日：2003-02-28
Applicant: DEGUSSA
Inventor： HIPPEL LUKAS VON , WEBER ROBERT , BEWERSDORF MARTIN , GAIL ERNST , SCHWARZ HELMUT
Abstract: The invention relates to an improvement to the BMA process for the production of hydrogen cyanide from methane and ammonia in the presence of a platinum-containing catalyst. The problem of sooting, and thus the decrease in activity, of the catalysts can be reduced, or the activity increased, in that the catalyst is doped with an element from the series Cu, Ag, Au, Pd and W. The doping is preferably in the range of 0.01 to 20 mole % doping element, based on Pt.
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公开(公告)号：DE102004054727A1
公开(公告)日：2006-05-24
申请号：DE102004054727
申请日：2004-11-12
Applicant: DEGUSSA
Inventor： ADRIAENSSENS JOZEF , BATHEN DIETER , BAEUML MANFRED , BEWERSDORF MARTIN , GAIL ERNST , LIESER THOMAS , MUELLER THOMAS , PELGRIMS IVAN , RINNER MICHAEL , WEBER ROBERT
IPC: C01C1/02
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公开(公告)号：AT463466T
公开(公告)日：2010-04-15
申请号：AT04712015
申请日：2004-02-18
Applicant: EVONIK DEGUSSA GMBH
Inventor： VON HIPPEL LUKAS , WEBER ROBERT , BEWERSDORF MARTIN , GAIL ERNST , SCHWARZ HELMUT
Abstract: The invention relates to an improvement to the BMA process for the production of hydrogen cyanide from methane and ammonia in the presence of a platinum-containing catalyst. The problem of sooting, and thus the decrease in activity, of the catalysts can be reduced, or the activity increased, in that the catalyst is doped with an element from the series Cu, Ag, Au, Pd and W. The doping is preferably in the range of 0.01 to 20 mole % doping element, based on Pt.
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