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公开(公告)号:DE2819638A1
公开(公告)日:1979-11-08
申请号:DE2819638
申请日:1978-05-05
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DIPL CHEM , TAN EWE HONG
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公开(公告)号:DE2346653A1
公开(公告)日:1975-04-03
申请号:DE2346653
申请日:1973-09-17
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DIPL CHEM , CLAS WILLI , BUECHEL WOLFGANG
Abstract: Mixts. of elastomers and silicates as coarse powders contg. 20-90 wt. % silicic acid/silicate with particle size 0.5-1.5mm are obtd. by co-precipitation of aq. elastomer lattices and silicate suspensions with organic acids, pref. formic or acetic, drying and grinding the coagulum. The mixts. are used for mineral-filled rubber applications. Such product mixes process well in the internal mixers, rolls, calenders and injection presses used by the rubber industry. Lengthy washing out of residual salts after pptn is avoided by use of volatile organic acids.
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公开(公告)号:CS224587A2
公开(公告)日:1990-09-12
申请号:CS224587
申请日:1987-03-31
Applicant: DEGUSSA
Inventor: SCHWARZE WERNER DR , WOLFF SIEGFRIED DIPL CHEM , LAMBERTZ HORST
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公开(公告)号:DE3305373A1
公开(公告)日:1984-08-23
申请号:DE3305373
申请日:1983-02-17
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DIPL CHEM , GOLOMBECK PAUL
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公开(公告)号:DE2848559A1
公开(公告)日:1980-05-14
申请号:DE2848559
申请日:1978-11-09
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DIPL CHEM , TAN EWE-HONG
IPC: C08J3/24 , B29C33/02 , B29C35/00 , C08K3/00 , C08K3/04 , C08K3/06 , C08K3/34 , C08K5/548 , C08K13/02 , C08L1/00 , C08L7/00 , C08L9/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K5/44
Abstract: Mouldable and vulcanisable rubber mixtures are made containing a rubber (A) which still contains double bonds and which is cross-linkable by means of sulphur and a vulcanization accelerator or a mixture of rubber (A) with a different rubber (B), 0.2 to 10 parts of sulphur, 0.2 to 10 parts of a vulcanization accelerator and 1.0 to 10 parts of a bis-(alkoxysilylalkyl)polysulfide. There can also be present a silicate filler and/or a carbon black filler of rubber. The rubber mixtures have the silane, vulcanization accelerator and sulphur, calculated as S8 present in a molar ratio which causes the rubber mixture to have a reversion R=O (+/-5%) resulting from the cross-linking isotherm at the vulcanization temperature where the reversion R is calculated according to Formula II in which Dmax is the maximum vulcameter moment of rotation Dmin is the minimum vulcameter moment of rotation D(max+60 min) is the vulcameter moment of rotation measured 60 minutes after the appearance of the maximum moment of rotation. There is also disclosed the process of vulcanizing the above-mentioned rubber mixtures or moulding compositions and forming vehicle tires using the rubber mixtures.
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公开(公告)号:DE2401056A1
公开(公告)日:1975-07-31
申请号:DE2401056
申请日:1974-01-10
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DIPL CHEM , POCHERT JOHANNES , THURN FRIEDRICH DR , BURMESTER KURT
IPC: C08L7/00 , B29C35/00 , B29C55/00 , B29C65/00 , B29C65/70 , C08J5/10 , C08K3/00 , C08K5/00 , C08K5/548 , C08K7/00 , C08L21/00 , C08L61/10 , C08L67/00 , C08L77/00 , C08J5/04
Abstract: Silica containing mixtures for the improvement of the adhesion of vulcanizable mixtures of natural and/or synthetic rubber to reinforcing fillers or supports of textile and/or metallic fabrics after the vulcanization are prepared that substantially consist of (A) active synthetically produced silica or silicates having a specific surface area according to the BET procedure of about 50 to 500 m2/g and an average primary particle size of from about 5 to 100 and at least one of (B) phenolic resin or aminoplast forming components, namely on the one hand phenols and/or amines and on the other hand aldehydes or aldehyde donors, and/or at least (C) one organosilane which can be a bisalkoxysilylalkyl-oligosulfide of the formula I. Z-Alk-Sn-Alk-Z, in which Z stands for the group R1 R1 R2 ¦ ¦ ¦ (a)-Si-R1, (b)-Si-R2 or (c)-Si-R2 ¦ ¦ ¦ R
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公开(公告)号:DE3376216D1
公开(公告)日:1988-05-11
申请号:DE3376216
申请日:1983-12-23
Applicant: DEGUSSA
Inventor: WOLFF SIEGFRIED DIPL CHEM , GOLOMBECK PAUL
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公开(公告)号:DE2935454A1
公开(公告)日:1981-03-19
申请号:DE2935454
申请日:1979-09-01
Applicant: DEGUSSA
IPC: C07F7/18
Abstract: There are prepared nitrogen containing alkoxysilanes of the formula (RO)3-n(CH3)nSi(CH2)mNHCON3 in which R is an alkyl group having 1 to 3 carbon atoms, n is 0, 1 or 2 and m is 1, 2 or 3 by a process comprising dissolving in an inert solvent an isocyanate group containing silane of the formula (RO)3-n(CH3)nSi(CH2)mN=C=O in which R, n and m are as defined above and reacting the silane with a water free hydrogen nitride or with hydrogen halide and an alkali metal-alkaline earth metal-, or ammonium azide at a temperature between 0 DEG C. and the boiling point of the inert solvent. The compounds are useful in making phosphinimines.
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公开(公告)号:DE2933346A1
公开(公告)日:1981-02-26
申请号:DE2933346
申请日:1979-08-17
Applicant: DEGUSSA
IPC: C08K3/00 , C04B20/10 , C08K5/00 , C08K5/5419 , C08K9/06 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K3/04 , C08K3/26 , C08K3/34 , C08K5/54 , C08L9/00
Abstract: The invention relates to a silane/filler preparation, consisting essentially of from 5 to 70% by weight of at least one silane corresponding to the following formula Xp-CmH2m+1-pSiRn1(OR)3-n, I in which X=a halogen atom, preferably chlorine or bromine, p=1 or 2, m=1 to 5, R1=a C1-C5 alkyl group, C5-C8-cycloalkyl group or a phenyl group, R=a C1-C5-alkyl group, a C5-C8-cycloalkyl group, a phenyl group, a benzyl group or a C1-C5-alkoxy-C1-C5-alkyl group, and n=0, 1 or 2, and-respectively balanced to 100%-from 95 to 30% by weight of at lesat one inorganic filler, preferably carbon black and silicate fillers as, e.g., silica. There is also disclosed a process for the production of the silane/filler preparation and its use in optionally cross-linkable polymeric moulding compositions or vulcanizable or cross-linkable rubber moulding compositions such as sulphur-vulcanizable moulding compositions based on natural rubber and/or synthetic rubber.
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