公开(公告)号：EP1219961B1

公开(公告)日：2006-04-19

申请号：EP01204815.3

申请日：2001-12-10

Applicant: Delphi Technologies, Inc.

Inventor： Tai, Lone-Wen F. ,  Kikuchi, Paul Casey ,  Symons, Walter Thomas

IPC: G01N27/407

CPC classification number: G01N27/4071

公开(公告)号：EP1215489A1

公开(公告)日：2002-06-19

申请号：EP01204817.9

申请日：2001-12-10

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kikuchi, Paul Casey ,  Symons, Walter Thomas ,  Polikarpus, Kaius Kiiren ,  Oberdier, Larry M.

IPC: G01N27/407 ,  G01N27/419

CPC classification number: G01N27/419

Abstract: A gas sensor is disclosed comprising an oxygen pump cell having at least one exterior pump electrode (40, 42) and at least one interior pump electrode (44, 46) disposed on opposite sides of a first solid electrolyte layer (30). An emf cell having a first and second emf electrodes (50, 52) and first and second reference gas electrodes (54, 56) are disposed on opposite sides of a second solid electrolyte layer (32). At least one insulating layer (22) is in contact with the first and second emf electrodes (50, 52). At least one via hole (60, 62) is disposed through the first solid electrolyte layer (30). At least one air channel (80, 82) is disposed through at least one insulating layer (22). An air vent (84) is disposed in at least one insulating layer (24) in contact with the first and second reference gas electrodes (54, 56). A heater (934) is disposed in thermal communication with the sensor. And at least five electrical leads are in electrical communication with said sensor. A method of using a gas sensor is also disclosed.

Abstract translation: 公开了一种气体传感器，其包括具有至少一个外部泵电极（40,42）和设置在第一固体电解质层（30）的相对侧上的至少一个内部泵电极（44,46）的氧气泵电池。 具有第一和第二电极电极（50,52）和第一和第二参考气体电极（54,56）的电池单元设置在第二固体电解质层（32）的相对侧上。 至少一个绝缘层（22）与第一和第二电极电极（50,52）接触。 至少一个通孔（60,62）穿过第一固体电解质层（30）设置。 至少一个空气通道（80,82）穿过至少一个绝缘层（22）设置。 在与第一和第二参考气体电极（54,56）接触的至少一个绝缘层（24）中设置有通风口（84）。 加热器（934）被布置成与传感器热连通。 并且至少五个电引线与所述传感器电连通。 还公开了一种使用气体传感器的方法。

公开(公告)号：EP1793224B1

公开(公告)日：2015-09-09

申请号：EP06077100.3

申请日：2006-11-24

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kirwan, John E. ,  Symons, Walter Thomas ,  Kupe, Joachim ,  Farhat, Robert Jerome

IPC: H01M8/04 ,  H01M8/06 ,  G01N27/419 ,  G01K7/16

CPC classification number: G01N27/419 ,  H01M8/04089 ,  H01M8/0618

公开(公告)号：EP1793224A3

公开(公告)日：2007-09-26

申请号：EP06077100.3

申请日：2006-11-24

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kirwan, John E. ,  Symons, Walter Thomas ,  Kupe, Joachim ,  Farhat, Robert Jerome

IPC: G01N27/419 ,  G01K7/16

CPC classification number: G01N27/419 ,  H01M8/04089 ,  H01M8/0618

Abstract: A system (144) comprising a sensor (22), a reformer (146), a reformer electronic control module (150) and a sensor control module (152), wherein the sensor (22) includes an oxygen pump cell (24); an oxygen pump chamber (26); an emf cell (32); a reference chamber (34) providing a fluid connection to the reference gas (30); gas channels in fluid communication with the pump (48,52) and emf electrodes (64,66), the reference gas (30) comprising reformate produced by fuel reformer (146) fuelled by an air-fuel gas mixture having an air-fuel ratio; a heater (72); a temperature sensor (70) disposed in communication with the heater (72) and the sensor control module (152) for maintaining the sensor (22) at a desired operating temperature; a closed loop controlled operation amplifier (40) in electrical communication with the sensor (22), whereby the oxygen pump cell (24) provides sufficient oxygen ions to oxidize an incoming diffusion-limiting fuel flux to the emf cell (32) and maintain a constant emf at the emf cell (32), and wherein a current value represents an equivalent to the air-fuel ratio of the air-fuel gas mixture.

公开(公告)号：EP1215492A3

公开(公告)日：2004-03-03

申请号：EP01204821.1

申请日：2001-12-10

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kikuchi, Paul Casey ,  Symons, Walter Thomas ,  Polikarpus, Kaius Kiiren ,  Oberdier, Larry M.

IPC: G01N27/407 ,  G01N27/419

CPC classification number: G01N27/419

Abstract: A gas sensor, comprising an oxygen pump cell with a first pump electrode (40) and a second pump electrode (42) disposed on opposite sides of a first solid electrolyte layer (30) and a second pump electrode (42). The sensor also comprises an emf cell with an emf electrode (44) and a reference gas electrode (46) disposed on opposite sides of a second solid electrolyte layer (32). The emf electrode (44) is disposed in fluid communication to the second pump electrode (42). A via hole (50) is disposed through the first solid electrolyte layer (30), such that the first pump electrode (40) is in fluid communication with the second pump electrode (42). A protective insulating layer (20), having a passage for gas to be sensed, is disposed in contact with the first pump electrode (40). A first insulating layer (22), having a conduit (54), is disposed in contact with the emf electrode (44). A second insulating layer (24), having an air channel (56), is disposed in contact with the reference gas electrode (46). A heater (60) is disposed in thermal communication with the emf cell. At least four electrical leads are in electrical communication with the sensor. A method of producing a gas sensor is disclosed.

Abstract translation: 一种气体传感器，包括具有第一泵电极（40）和第二泵电极（42）的氧泵单元，所述第一泵电极和第二泵电极设置在第一固体电解质层（30）和第二泵电极（42）的相对侧上。 该传感器还包括具有设置在第二固体电解质层（32）的相对侧上的emf电极（44）和参考气体电极（46）的emf电池。 emf电极（44）设置成与第二泵电极（42）流体连通。 通孔（50）设置穿过第一固体电解质层（30），使得第一泵电极（40）与第二泵电极（42）流体连通。 具有用于感测气体的通道的保护性绝缘层（20）被布置成与第一泵电极（40）接触。 具有导管（54）的第一绝缘层（22）设置成与emf电极（44）接触。 具有空气通道（56）的第二绝缘层（24）设置成与参考气体电极（46）接触。 加热器（60）设置成与emf电池热连通。 至少四根电导线与传感器电连通。 公开了一种制造气体传感器的方法。

公开(公告)号：EP1217363A3

公开(公告)日：2004-04-21

申请号：EP01204811.2

申请日：2001-12-10

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kikuchi, Paul Casey ,  Symons, Walter Thomas ,  Polikarpus, Kaius Kiiren ,  Gross, Kerry J.

IPC: G01N27/407 ,  C04B35/48

CPC classification number: G01N27/4073

Abstract: The electrolyte (30) comprises up to about 80 wt% zirconia, up to about 30 wt% stabilizer, and up to about 40 wt% dopant-zirconia. Alternatively, the electrolyte (30) can comprise zirconia having a phase chemistry, wherein the phase chemistry, at about 25°C, is about 15 wt% to about 35 wt% monoclinic, less than about 10 wt% tetragonal, balance cubic, based upon the weight of the zirconia in the electrolyte (30).

公开(公告)号：EP1225158A1

公开(公告)日：2002-07-24

申请号：EP01204972.2

申请日：2001-12-18

Applicant: Delphi Technologies, Inc.

Inventor： Polikarpus, Kaius Kiiren ,  Symons, Walter Thomas

IPC: C04B35/486

CPC classification number: C04B35/4885

Abstract: A conductive co-fired body for an electrochemical cell for an exhaust sensor comprises zirconia, yttrium oxide, and alumina. The body comprises about 15 to about 30 weight% monoclinic phase zirconia. This produces an electrochemical cell having low impedance wherein the zirconia body and alumina body are co-fired. One method for manufacturing the electrochemical cell comprises combining zirconia, yttria, and alumina with solvent and dispersant to form a mixture. After, binder is added to the mixture which is then de-aired and cast onto a tape surface. The tape is dried, metallized, and laminated to an unfired alumina surface. The structure is then co-fired to form a body for said electrochemical cell.

Abstract translation: 用于排气传感器的电化学电池的导电共烧体包括氧化锆，氧化钇和氧化铝。 身体包含约15至约30重量％的单斜相氧化锆。 这产生具有低阻抗的电化学电池，其中氧化锆体和氧化铝体共烧。 制造电化学电池的一种方法包括将氧化锆，氧化钇和氧化铝与溶剂和分散剂组合以形成混合物。 之后，将粘合剂加入到混合物中，然后将其脱模并浇注到带表面上。 将胶带干燥，金属化并层压到未烧结的氧化铝表面。 然后将该结构共烧以形成用于所述电化学电池的主体。

公开(公告)号：EP1217363A2

公开(公告)日：2002-06-26

申请号：EP01204811.2

申请日：2001-12-10

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kikuchi, Paul Casey ,  Symons, Walter Thomas ,  Polikarpus, Kaius Kiiren ,  Gross, Kerry J.

IPC: G01N27/407

CPC classification number: G01N27/4073

Abstract: The electrolyte (30) comprises up to about 80 wt% zirconia, up to about 30 wt% stabilizer, and up to about 40 wt% dopant-zirconia. Alternatively, the electrolyte (30) can comprise zirconia having a phase chemistry, wherein the phase chemistry, at about 25°C, is about 15 wt% to about 35 wt% monoclinic, less than about 10 wt% tetragonal, balance cubic, based upon the weight of the zirconia in the electrolyte (30).

Abstract translation: 电解质（30）包含至多约80重量％的氧化锆，至多约30重量％的稳定剂和至多约40重量％的掺杂剂 - 氧化锆。 或者，电解质（30）可以包括具有相化学性质的氧化锆，其中约25℃时的相化学为约15重量％至约35重量％的单斜晶系，小于约10重量％的四方晶系， 取决于电解质（30）中氧化锆的重量。

公开(公告)号：EP1215492A2

公开(公告)日：2002-06-19

申请号：EP01204821.1

申请日：2001-12-10

Applicant: Delphi Technologies, Inc.

Inventor： Wang, Da Yu ,  Kikuchi, Paul Casey ,  Symons, Walter Thomas ,  Polikarpus, Kaius Kiiren ,  Oberdier, Larry M.

IPC: G01N27/407

CPC classification number: G01N27/419

Abstract: A gas sensor, comprising an oxygen pump cell with a first pump electrode (40) and a second pump electrode (42) disposed on opposite sides of a first solid electrolyte layer (30) and a second pump electrode (42). The sensor also comprises an emf cell with an emf electrode (44) and a reference gas electrode (46) disposed on opposite sides of a second solid electrolyte layer (32). The emf electrode (44) is disposed in fluid communication to the second pump electrode (42). A via hole (50) is disposed through the first solid electrolyte layer (30), such that the first pump electrode (40) is in fluid communication with the second pump electrode (42). A protective insulating layer (20), having a passage for gas to be sensed, is disposed in contact with the first pump electrode (40). A first insulating layer (22), having a conduit (54), is disposed in contact with the emf electrode (44). A second insulating layer (24), having an air channel (56), is disposed in contact with the reference gas electrode (46). A heater (60) is disposed in thermal communication with the emf cell. At least four electrical leads are in electrical communication with the sensor. A method of producing a gas sensor is disclosed.

Abstract translation: 一种气体传感器，包括具有设置在第一固体电解质层（30）和第二泵电极（42）的相对侧上的第一泵电极（40）和第二泵电极（42）的氧泵电池。 传感器还包括具有emf电极（44）和设置在第二固体电解质层（32）的相对侧上的参考气体电极（46）的emf单元。 电动电极（44）设置成与第二泵电极（42）流体连通。 通孔（50）通过第一固体电解质层（30）设置，使得第一泵电极（40）与第二泵电极（42）流体连通。 具有用于检测气体通道的保护绝缘层（20）设置成与第一泵电极（40）接触。 具有导体（54）的第一绝缘层（22）设置成与电极电极（44）接触。 具有空气通道（56）的第二绝缘层（24）设置成与参考气体电极（46）接触。 加热器（60）设置成与电磁电池热连通。 至少四个电引线与传感器电连通。 公开了一种生产气体传感器的方法。

公开(公告)号：EP1225158B1

公开(公告)日：2012-09-12

申请号：EP01204972.2

申请日：2001-12-18

Applicant: Delphi Technologies, Inc.

Inventor： Polikarpus, Kaius Kiiren ,  Symons, Walter Thomas

IPC: C04B35/486 ,  G01N27/407

CPC classification number: C04B35/4885