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    SULFUR MODIFIED SILANES FOR THE ELABORATION OF HIGH REFRACTIVE INDEX MATERIALS
    2.
    发明申请
    SULFUR MODIFIED SILANES FOR THE ELABORATION OF HIGH REFRACTIVE INDEX MATERIALS 审中-公开
    用于制备高折射率材料的硫改性硅烷

    公开(公告)号：WO2009138853A8

    公开(公告)日：2010-01-21

    申请号：PCT/IB2009005574

    申请日：2009-05-12

    Applicant: ESSILOR INT ,  BITEAU JOHN ,  MOSSE HERBERT

    Inventor： BITEAU JOHN ,  MOSSE HERBERT

    IPC: C08G75/04 ,  C08L81/02

    CPC classification number: C08G75/045 ,  C07F7/1836 ,  C08L81/02

    Abstract: A composition having a polysulfide polysilane formed by the reaction of a polythiol and an alkenyl silane. The reactants are combined in a thiol-ene addition process driven by UV radiation or heat, preferably by UV radiation. The polysulfide polysilane is then hydrolyzed and may be combined with other hydrolyzed compounds. For coatings, the polysulfide polysilane is hydrolyzed and may optionally be combined with nanoparticles. For bulk materials, the polysulfide polysilane is hydrolyzed, concentrated and heated to form a high refractive index material which can be used to form lenses.

    Abstract translation: 通过多硫醇与烯基硅烷的反应形成的具有多硫化物聚硅烷的组合物。 反应物在由UV辐射或热驱动的硫醇 - 烯加成过程中组合，优选通过UV辐射组合。 然后将多硫化物聚硅烷水解，并可与其它水解化合物组合。 对于涂层，多硫化物聚硅烷被水解并且可任选地与纳米颗粒组合。 对于散装材料，多硫化物聚硅烷被水解，浓缩并加热以形成可用于形成透镜的高折射率材料。

    OPTICAL ARTICLE COMPRISING A MULTILAYER ANTI-REFLECTIVE COATING AND METHOD FOR PRODUCTION THEREOF
    3.
    发明申请
    OPTICAL ARTICLE COMPRISING A MULTILAYER ANTI-REFLECTIVE COATING AND METHOD FOR PRODUCTION THEREOF 审中-公开
    包含多层抗反射涂层的光学制品及其制造方法

    公开(公告)号：WO2005012955A3

    公开(公告)日：2005-04-07

    申请号：PCT/FR2004050364

    申请日：2004-07-28

    Applicant: ESSILOR INT ,  BITEAU JOHN ,  FANAYAR MYRIAM ,  MASSART NATHALIE ,  RYCHEL DOMINIQUE

    Inventor： BITEAU JOHN ,  FANAYAR MYRIAM ,  MASSART NATHALIE ,  RYCHEL DOMINIQUE

    IPC: C09D183/08 ,  G02B1/11 ,  C08J7/04

    CPC classification number: G02B1/11 ,  C09D183/08 ,  Y10T428/31663

    Abstract: The invention relates to an optical article, for example, an ophthalmic lens, comprising at least one multilayer anti-reflective coating on a transparent substrate made from organic or mineral glass. Said coating comprises successively and starting at the substrate, a layer of material with high refractive index (HI), made from a hybrid organic/inorganic matrix within which are dispersed particles of mineral oxide or chalcogenide with a diameter of 2 to 50 nm and a layer of material with low refractive index (BI), obtained by hardening of a composition comprising at least one silane precursor (I) with 4 hydrolysable groups and at least one fluorosilane precursor (II), said second composition comprising at least 10 % in mass of fluorine in a theoretical dry extract and with a molar ratio I/I+II greater than 80 %.

    Abstract translation: 本发明涉及光学制品，例如眼科镜片，其包括在由有机或无机玻璃制成的透明基底上的至少一个多层抗反射涂层。 所述涂层连续地并且在基底处开始具有高折射率（HI）的材料层，其由混合的有机/无机基质制成，其中分散有直径为2-50nm的矿物氧化物或硫族化物颗粒和 通过使包含至少一种具有4个可水解基团的硅烷前体（I）和至少一种氟代硅烷前体（II）的组合物硬化而获得的具有低折射率（BI）的材料层，所述第二组合物包含至少10质量％ 的氟在理论干提取物中并且具有大于80％的I / I + II的摩尔比。

    Composición polimérica y métodos que utilizan dicha composición polimérica para elaborar lentes oftálmicas
    4.
    发明专利
    Composición polimérica y métodos que utilizan dicha composición polimérica para elaborar lentes oftálmicas 未知

    公开(公告)号：ES2673569T3

    公开(公告)日：2018-06-22

    申请号：ES13854196

    申请日：2013-12-20

    Applicant: ESSILOR INT

    Inventor： VALERI ROBERT ,  BITEAU JOHN

    IPC: G02B1/04 ,  B29D11/00

    Abstract: Composición polimérica para elaborar una lente oftálmica transparente caracterizada por que se obtiene por polimerización de una composición polimerizable que comprende al menos: - un monómero u oligómero (A) que comprende al menos un grupo reactivo seleccionado entre epoxi, tioepoxi, epoxisilano, (met)acrilato, tio(met)acrilato, vinilo, uretano, tiouretano, isocianato, mercapto y alcohol, donde dicho monómero (A) se contrae durante la polimerización; - un monómero (B) que comprende al menos un grupo cíclico no aromático donde durante la polimerización dicho grupo cíclico se abre y reacciona con otra molécula de monómero (B) y/o con un grupo reactivo del monómero u oligómero (A), - donde dicho monómero (B) se expande durante la polimerización y donde dicho monómero (B) se selecciona entre tetraspiroortocarbonato y sulfatos cíclicos.

    artigo de óptica que compreende um empilhamento anti-reflexivo de múltiplas camadas e processo de fabricapção do artigo de óptica
    5.
    发明专利
    artigo de óptica que compreende um empilhamento anti-reflexivo de múltiplas camadas e processo de fabricapção do artigo de óptica 未知

    公开(公告)号：BRPI0413065B1

    公开(公告)日：2016-06-21

    申请号：BRPI0413065

    申请日：2004-07-28

    Applicant: ESSILOR INT

    Inventor： RYCHEL DOMINIQUE ,  BITEAU JOHN ,  FANAYAR MYRIAM ,  MASSART NATHALIE

    IPC: C08J7/04 ,  C09D183/08 ,  G02B1/11

    Abstract: "artigo e processo de fabricação de um artigo". a presente invenção refere-se a um artigo de óptica, por exemplo uma lente oftálmica, compreendendo pelo menos um empilhamento anti-reflexos de múltiplas camadas sobre um substrato transparente de vidro orgânico ou mineral, o referido empilhamento compreendendo, sucessivamente e na ordem a partir do substrato, pelo menos uma camada de material de índice de refração elevado (hi) compreendendo uma matriz híbrida orgânica - inorgânica na qual são dispersas as partículas de óxido metálico e/ou calcogeneto de um diâmetro de 2 a 50 nm, e uma camada de material de índice de refração baixo (bi) obtida por endurecimento de uma composição compreendendo pelo menos um silano precursor (i) tendo 4 partes hidrolisáveis e pelo menos um fluorossilano precursor (ii), esta segunda composição compreendendo pelo menos 10% em massa de flúor em seu extrato seco teórico e uma relação molar i/i + ii superior a 80%.

    Method of producing a substrate which is coated with a mesoporous layer and use thereof in ophthalmic optics
    6.
    发明专利
    Method of producing a substrate which is coated with a mesoporous layer and use thereof in ophthalmic optics 未知

    公开(公告)号：AU2005276313B2

    公开(公告)日：2011-01-06

    申请号：AU2005276313

    申请日：2005-05-03

    Applicant: ESSILOR INT

    Inventor： GACOIN THIERRY ,  MATHERON MURIEL ,  CANO JEAN-PAUL ,  BITEAU JOHN ,  BOILOT JEAN-PIERRE

    IPC: C09D183/04 ,  C09D183/02 ,  G02B1/04 ,  G02B1/10

    Abstract: The invention relates to a method of producing a substrate which is coated with a mesoporous layer and to the use thereof in ophthalmic optics. The inventive method comprises the following steps comprising: preparing a precursor sol containing (i) a precursor agent that is selected from compounds having formula M(X)4 (I), in which X is a hydrolysable group and M represents silicon or a tetravalent metal and mixtures thereof, (ii) at least one organic solvent, (iii) at least one pore-forming agent and (iv) water; depositing a film of the precursor sol on a main surface of the substrate; optionally consolidating the mesoporous structure of the deposited film; eliminating the pore-forming agent; and recovering the substrate coated with the mesoporous layer. The method is characterized in that: (i) the pore-forming agent is eliminated at a temperature of less than or equal to 150° C.; and (ii) the method comprises a step involving the introduction of at least one reactive agent bearing at least one hydrophobic group, before the deposition step and/or after said step.

    8.
    发明专利
    未知

    公开(公告)号：FR2896887B1

    公开(公告)日：2008-05-30

    申请号：FR0650381

    申请日：2006-02-02

    Applicant: ESSILOR INT

    Inventor： BITEAU JOHN ,  BOILOT JEAN PIERRE ,  CADO HERVE

    IPC: G02B6/13

    Abstract: The present invention relates to an article comprising a substrate having a main surface coated with a coating, part of which at least is mesoporous and has a refractive index profile with optical function, whose variation is imposed by the mesopore content and/or the filling ratio of the mesopores. The profile may be such that the refractive index varies depending on the distance to a given axis, or such that the refractive index variation is monotone, decreasing along any axis which is perpendicular to the surface of the substrate underlying the mesoporous part of said coating and oriented away from the substrate. The present invention also relates to methods for making said article, which differ depending on the technique from which the refractive index profile is created. The invention is applicable to ophthalmic optics.

    10.
    发明专利
    未知

    公开(公告)号：FR2876190B1

    公开(公告)日：2006-12-08

    申请号：FR0452248

    申请日：2004-10-04

    Applicant: ESSILOR INT

    Inventor： BITEAU JOHN ,  FANAYAR MYRIAM

    IPC: G02B1/08 ,  G02B3/00 ,  G02B5/30

    Abstract: The light-polarizing solid coating composition which comprises (i) particles of at least one magnetic material suspended in a solvent, is characterized in that it comprises (ii) at least one dichroic dye compound. Application to ophthalmic optics.

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