公开(公告)号：US3790358A

公开(公告)日：1974-02-05

申请号：US3790358D

申请日：1971-07-30

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： ROSSI A ,  JACOBSON N ,  MILLER H

IPC: C08F210/14 ,  C10L1/16

CPC classification number: C08F210/14 ,  C10L1/1633 ,  C10L1/1641 ,  C10L1/165 ,  C10L1/1666 ,  C08F210/08 ,  C08F210/06

Abstract: Hydrocarbon polymers comprising linear C18 alkyl side chains are added to residual fuels to improve their pour point and flow characteristics. These polymers are prepared by polymerizing C20C40 alpha-olefins in the presence of a Ziegler-type catalyst to a number average molecular weight within the range between about 500 and 125,000. Particularly effective polymers are prepared from C3-C18 alpha-olefins and C20-C40 alpha-olefins.

Abstract translation: 包含直链C 18 +烷基侧链的烃聚合物加入到残余燃料中以改善其倾点和流动特性。 这些聚合物通过在齐格勒型催化剂存在下将C20-C40α-烯烃聚合至数均分子量在约500至125,000之间的范围内来制备。 特别有效的聚合物由C3-C18α-烯烃和C20-C40α-烯烃制备。

公开(公告)号：US3767561A

公开(公告)日：1973-10-23

申请号：US3767561D

申请日：1971-07-21

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： JACOBSON N ,  SONG W ,  ROSSI A ,  TORNQVIST E

IPC: C10G73/04 ,  C10G43/06

CPC classification number: C10G73/04

Abstract: Ziegler-type polymers comprising C14-C24 alpha-monoolefins and having a number average molecular weight within the range between about 1,000 and about 200,000 are effective dewaxing aids for improving the efficiency of the separation of wax from hydrocarbon oils. Preferred dewaxing aids include mixtures of two or more homopolymers of C14-C24 alpha-monoolefins and copolymers of two or more alpha-monoolefins containing from 14 to 24 carbon atoms in the molecule. The Ziegler-type polymers when combined with Friedel-Crafts condensation products of chlorinated wax and naphthalene synergistically improve the separation of wax from petroleum oils.

Abstract translation: 包含C14-C24α-单烯烃并且数均分子量在约1,000至约200,000之间的齐格勒型聚合物是有效的脱蜡助剂，用于提高蜡与烃油的分离效率。 优选的脱蜡助剂包括C14-C24α-单烯烃的两种或更多种均聚物和两种或多种在分子中含有14-24个碳原子的α-单烯烃的共聚物的混合物。

公开(公告)号：US3854893A

公开(公告)日：1974-12-17

申请号：US26271972

申请日：1972-06-14

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： ROSSI A

IPC: C10M101/00 ,  C08L31/02 ,  C08L33/06 ,  C08L35/02 ,  C09K3/00 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/192 ,  C10L1/195 ,  C10L1/196 ,  C10L1/198 ,  C10L1/22 ,  C10L1/20

CPC classification number: C10L1/146 ,  C08L31/02 ,  C08L33/06 ,  C08L35/02 ,  C08L2205/02 ,  C10L1/1641 ,  C10L1/165 ,  C10L1/195 ,  C10L1/198 ,  C10L1/1983 ,  C10L1/236 ,  C10L1/238 ,  C08L2666/02 ,  C08L2666/04

Abstract: Combination of two or more oil-soluble, polymeric materials having long linear side chains can be used to improve the flow properties of hydrocarbon oils containing high boiling waxes, such as fuel oils containing residua and crude oils. Examples of these polymeric materials include: condensation polymers of dicarboxylic acid or anhydride, polyol and monocarboxylic acid; addition polymers of: unsaturated esters, or long chain alpha monoolefins, or copolymers of said olefins with said unsaturated ester; polystyrene acylated with long chain fatty acid; etc. The invention also includes a method for formulating said polymer combinations to achieve an optimum effect in oil subject to pour point reversion, by giving samples of the oil containing the individual polymers a series of thermal histories, measuring the pour point of each of said samples to determine Flow Point, i.e., the highest pour point that the oil exhibits, and then blending the polymers to achieve a minimum Flow Point.

Abstract translation: 具有长线性侧链的两种或更多种油溶性聚合材料的组合可用于改善含有高沸点蜡的烃油的流动性能，例如含有残余物和原油的燃料油。 这些聚合材料的实例包括：二羧酸或酸酐的缩聚物，多元醇和一元羧酸; 加成聚合物：不饱和酯或长链α-单烯烃，或所述烯烃与所述不饱和酯的共聚物; 用长链脂肪酸酰化聚苯乙烯; 本发明还包括一种用于配制所述聚合物组合以通过倾点反转获得最佳效果的方法，通过给含有各种聚合物的油的样品提供一系列热历史，测量每个所述聚合物的倾点 样品以确定流动点，即油表现出的最高倾点，然后混合聚合物以达到最小流动点。

公开(公告)号：US3816314A

公开(公告)日：1974-06-11

申请号：US25838472

申请日：1972-05-31

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： PAPPAS J ,  ROSSI A

IPC: C08F297/02 ,  C10M149/02 ,  C10M1/32

CPC classification number: C10M149/02 ,  C08F297/026 ,  C10M2209/084 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2209/106 ,  C10M2215/04 ,  C10M2215/26 ,  C10M2217/022 ,  C10M2217/023 ,  C10M2217/024 ,  C10M2217/026 ,  C10M2217/028 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2223/045 ,  C10N2210/02 ,  C10N2270/02

Abstract: Block copolymers comprising an oil-soluble segment and a polar segment exhibit improved dispersancy characteristics in multifunctional viscosity index improver applications.

公开(公告)号：US3762888A

公开(公告)日：1973-10-02

申请号：US3762888D

申请日：1970-11-16

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KOBER A ,  ROSSI A

IPC: C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/20

CPC classification number: C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1633 ,  C10L1/1857 ,  C10L1/188 ,  C10L1/19 ,  C10L1/192 ,  C10L1/195 ,  C10L1/1985 ,  C10L1/201 ,  C10L1/202 ,  C10L1/206

Abstract: Cold flow properties of fuel oils are improved by addition thereto of certain oil-soluble, pour point depressant polymers together with non-nitrogen containing, oil-soluble, auxiliary, flow improving compounds.

公开(公告)号：BE800870A

公开(公告)日：1973-12-13

申请号：BE132233

申请日：1973-06-13

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： ROSSI A

IPC: C10M101/00 ,  C08L31/02 ,  C08L33/06 ,  C08L35/02 ,  C09K3/00 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/192 ,  C10L1/195 ,  C10L1/196 ,  C10L1/198 ,  C10L1/22 ,  C10L

Abstract: Combination of two or more oil-soluble, polymeric materials having long linear side chains can be used to improve the flow properties of hydrocarbon oils containing high boiling waxes, such as fuel oils containing residua and crude oils. Examples of these polymeric materials include: condensation polymers of dicarboxylic acid or anhydride, polyol and monocarboxylic acid; addition polymers of: unsaturated esters, or long chain alpha monoolefins, or copolymers of said olefins with said unsaturated ester; polystyrene acylated with long chain fatty acid; etc. The invention also includes a method for formulating said polymer combinations to achieve an optimum effect in oil subject to pour point reversion, by giving samples of the oil containing the individual polymers a series of thermal histories, measuring the pour point of each of said samples to determine Flow Point, i.e., the highest pour point that the oil exhibits, and then blending the polymers to achieve a minimum Flow Point.

公开(公告)号：CA932152A

公开(公告)日：1973-08-21

申请号：CA59341

申请日：1969-08-12

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： ROSSI A ,  MILLER H ,  JACOBSON N

IPC: C07C2/30 ,  C08F210/04 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C09K3/00 ,  C10L1/16

公开(公告)号：NO134661C

公开(公告)日：1976-11-24

申请号：NO172072

申请日：1972-05-15

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KOBER A E ,  ROSSI A

IPC: C10L1/18

公开(公告)号：BR7506793A

公开(公告)日：1976-08-17

申请号：BR7506793

申请日：1975-10-16

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： ROSSI A

IPC: C10M159/12 ,  C08F8/32 ,  C10M149/14 ,  C10M149/18 ,  C10M169/00 ,  C10N20/04 ,  C10N30/02 ,  C10N30/04 ,  C10N40/04 ,  C10N40/25 ,  C10M1/28

公开(公告)号：SE372283B

公开(公告)日：1974-12-16

申请号：SE633772

申请日：1972-05-15

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： KOBER A ,  ROSSI A

IPC: C10L1/14