Fungicide and bactericide 3-aryl-3-oxo-propyl-1,2,4-triazole derivs. - prepd. e.g. by reaction of Mannich base with 1,2,4-triazole

    公开(公告)号:DE3020500A1

    公开(公告)日:1982-01-21

    申请号:DE3020500

    申请日:1980-05-30

    Applicant: HOECHST AG

    Abstract: 1-(3-Oxopropyl)-1,2,4-triazole derivs. (Ia) and their metal complexes with group Ib, IIb, IVb or VIII metals, as well as their salts and quaternisation prods (Ib) are new. In the formulae R is H, phenyl opt. substd. by halogen and/or 1-4C alkyl, or 1-18C alkyl opt. substd. by halogen, CN or a gp. OR1 in which R1 is 1-4C alkyl, phenyl or phenyl substd. by halogen or 1-4C alkyl; Z is 1- or 2-naphthyl or one of the groups (A), (B) or (C) in which R2 is H, halogen, NO2, CN, OH, 1-6C alkyl, 5-6C cycloalkyl, 1-6C alkoxy, 2-6C alkenyloxy, -(CH2)3-, -(CH2)4- or opt halo-substd. phenyl or phenoxy, R3 is H, 1-4C alkyl or halogen, n is 1, 2, 3 or 4 and m is 1, 2 or 3; R4 is H, 1-18C alkyl, oxoalkyl or alkenyl, or opt. halo-substd. phenacyl; and Y is the anion of an organic or inorganic acid. (I) are fungicides and bactericides esp. useful against rusts and mildews of plants, some cpds. (I) have systemic activity. (I) are also suitable for use in the technical sector, e.g. in timber preservatives, in paints, and as antifungal and antibacterial preservatives.

    5,6,7,8-Tetra:hydro-quinoline derivs. - broad spectrum fungicides and bactericides esp. useful for treating leaf diseases

    公开(公告)号:DE2918590A1

    公开(公告)日:1980-11-13

    申请号:DE2918590

    申请日:1979-05-09

    Applicant: HOECHST AG

    Abstract: derivs. of formula (I) are new. R1 is H, 1-12C alkyl, benzyl, phenyl (opt. substd. by 1 or 2 Cl or by CF3 or 1-4C alkyl), -16C alkoxy-carbonyl, aryl-aminocarbonyl (in which aryl is opt. substd. by halogen, CF3, NO2 or 1-5C alkyl) N-alkyl-aryl aminocarbonyl (where alkyl has 1-3C and aryl is opt. substd. by halogen, CF3, or 1-4C alkyl), aminocarbonyl, 1-10C alkylaminocarbonyl, or di-(1-10C) alkylaminocarbonyl; R2 is H, opt. branched 1-12C alkyl, benzyl, phenyl (opt. substd. by 2 Cl or CF3, NO2 or 1-4C alkyl), 1-6C alkoxycarbonyl, phenylthio morpholino, piperidino, arylamino (in which aryl is substd. by halogen or 1-4C alkyl), di (1-6C) alkylaminomethyl morpholinomethyl or piperidinomethy; or R1 and R2 are together -CH2CH2CH2CH2-;R3 is H or 1-4C alkyl;R4 is H or opt. branched 1-12C alkyl;R5 is H or 1-4C alkyl;R6 is H or 1-6C alkyl;A is SH, Cl or -OR7;R7 is -SO2NR8R9 or -COOR10;R8 is opt. branched 1-10C alkyl, Ph or H and R9 is H or opt. branched 1-10C alkyl, or R8 and R9 together are -(CH2)-n, -CH2CH2OCH2CH2- or -CH2CH2N-(Me)CH2CH2- where n = 4 or 5; and R10 is 1-10C alkyl or Ph opt. substd. by halogen or NO2. (I) are biocides with a relatively broad spectrum of activity against fungi and bacteria, and are esp. useful for treating diseases of leaves. (I) are effective e.g. against phytopathogenic fungi and bacteria such as Botrytic cinerea and Xanthomonas oryltae, as well as against non-phytopathogenic fungi and bacteria such as Penicillium funiculosum and E. coli.

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