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公开(公告)号:DE2641662A1
公开(公告)日:1978-03-23
申请号:DE2641662
申请日:1976-09-16
Applicant: HOECHST AG
Inventor: WAGNER REINHARD DIPL CHEM DR , WERNER GERHARD DIPL CHEM DR , HENCKEN GUENTER DIPL CHEM DR , JUST CHRISTOPH DIPL CHEM DR
IPC: C08F299/04 , C08G63/47 , C08G63/676 , C08G63/52
Abstract: Unsatd. polyester based binders are made by (1) in a first stage, reacting (a) >=1 single olefinically unsatd. dicarboxylic acid which is free from polymerisable aliphatic multiple bonds; (I); (b) >=1 polyhydric alcohol (II) and (c) >=1 polycyclic norbornane ring cpd. (III) with >=1 functional COOH, OH or amino gp., and (2) in a second stage, reacting the prod. with (d) >=1 condensable acrylic cpd. (IV). The modified acrylated polyesters are esp. useful as binders for UV-curable printing inks. The norbornane ring modification gives prods. with improved processability and improved storage stability in pigmented form. The binders have good pigment wetting characteristics, fast cure times and low viscosity and thus give fast drying high gloss prints with freedom from 'picking' (sticking of paper to the printing rollers).