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公开(公告)号:CA2080207A1
公开(公告)日:1993-04-10
申请号:CA2080207
申请日:1992-10-08
Applicant: HOECHST AG
Inventor: PAPENFUHS THEODOR , PRESSLER WILFRIED , RAPP JOCHEN
IPC: B01J23/04 , C07B61/00 , C07C201/12 , C07C205/37
Abstract: HOE 91/F 317 Process for the preparation of 1,2-bis-(2-nitrophenoxy)-ethane The present invention relates to a process for the preparation of 1,2-bis-(2-nitrophenoxy)-ethane, by reacting 1 mole of ethylene glycol with about 190 to about 250 mol% of 2-chloronitrobenzene at temperatures of about 40 to about 100 metal hydroxide in dimethylacetamide.
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公开(公告)号:CA2076142A1
公开(公告)日:1993-02-17
申请号:CA2076142
申请日:1992-08-14
Applicant: HOECHST AG
Inventor: PAPENFUHS THEODOR , RAPP JOCHEN
IPC: B01J27/122 , C07B61/00 , C07C227/08 , C07C229/56
Abstract: HOE 91/F 252 of the disclosure: Process for the preparation of 2-amino-3-chlorobenzoic acid The present invention relates to a process for the preparation of 2-amino-3-chlorobenzoic acid by dissolving 1 mol of 2,3-dichlorobenzoic acid in about 400 to about 2000 parts of water with at least the equimolar amount of an alkali metal hydroxide or with an aqueous solution of the equimolar amount of an alkali metal hydroxide, and subsequently reacting it with about 500 to about 2500 mol % of ammonia at temperatures of about 150.degree. to about 220.degree.C in the presence of copper bronze, copper(I) salts and/or copper(II) salts.
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公开(公告)号:IE910515A1
公开(公告)日:1991-08-28
申请号:IE51591
申请日:1991-02-14
Applicant: HOECHST AG
Inventor: KEIL GUENTER , HESS REINER , RAPP JOCHEN
Abstract: Aromatic copolyamides are described, which are soluble in organic amide solvents. The polymers are composed to at least 95 mol % of repeat structural units A: -OC-AR-CO- B: -HN-Ar'-NH- C: -HN-Ar''-NH- in the combinations A+B+C+D, or A+C+D+E and up to 5 mol % of m-bond-containing structural units F and/or G derived from aromatic dicarboxylic acids (F') and/or from aromatic diamines (G'), the sum total of the mole fractions of structural units A+F and the sum total of the mole fractions of the structural units of B+C+D+E+G being essentially the same, -Ar- and -Ar'- are divalent aromatic radicals whose C-N valence bonds are in a para-position or in a similar coaxial or parallel position and which may be substituted by one or two inert radicals, such as lower alkykl or halogen, is a trivalent aromatic radical which after removal of the -SO2R group has the same meaning as -Ar- or -Ar'- or else is the structural unit wehre X is -O-, -NHCO-, -SO2- or -CO-, -R is lower alkyl and -R' is lower alkyl or alkoxy, and the proportions of the diamine components B, C, D and E are within the following limits: B: 25-47.5 mol % C: 7.5-30 mol D: 45-67.5 mol and E: 20-40 mol.
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公开(公告)号:AU648923B2
公开(公告)日:1994-05-05
申请号:AU2100892
申请日:1992-08-14
Applicant: HOECHST AG
Inventor: PAPENFUHS THEODOR , RAPP JOCHEN
IPC: B01J27/122 , C07B61/00 , C07C227/08 , C07C229/56 , C07C229/38
Abstract: The present invention relates to a process for the preparation of 2-amino-3-chlorobenzoic acid by dissolving 1 mol of 2,3-dichlorobenzoic acid in about 400 to about 2000 parts of water with at least the equimolar amount of an alkali metal hydroxide or with an aqueous solution of the equimolar amount of an alkali metal hydroxide, and subsequently reacting it with about 500 to about 2500 mol % of ammonia at temperatures of about 150 DEG to about 220 DEG C. in the presence of copper bronze, copper(I) salts and/or copper(II) salts.
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公开(公告)号:ZA9206129B
公开(公告)日:1993-06-14
申请号:ZA9206129
申请日:1992-08-14
Applicant: HOECHST AG
Inventor: PAPENFUHS THEODOR , RAPP JOCHEN
IPC: B01J27/122 , C07B61/00 , C07C227/08 , C07C229/56 , C07C
CPC classification number: C07C227/08
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公开(公告)号:PT96772A
公开(公告)日:1991-10-31
申请号:PT9677291
申请日:1991-02-14
Applicant: HOECHST AG
Inventor: KEIL GUNTER , HESS REINER , RAPP JOCHEN
Abstract: Aromatic copolyamides are described, which are soluble in organic amide solvents. The polymers are composed to at least 95 mol % of repeat structural units A: -OC-AR-CO- B: -HN-Ar'-NH- C: -HN-Ar''-NH- in the combinations A+B+C+D, or A+C+D+E and up to 5 mol % of m-bond-containing structural units F and/or G derived from aromatic dicarboxylic acids (F') and/or from aromatic diamines (G'), the sum total of the mole fractions of structural units A+F and the sum total of the mole fractions of the structural units of B+C+D+E+G being essentially the same, -Ar- and -Ar'- are divalent aromatic radicals whose C-N valence bonds are in a para-position or in a similar coaxial or parallel position and which may be substituted by one or two inert radicals, such as lower alkykl or halogen, is a trivalent aromatic radical which after removal of the -SO2R group has the same meaning as -Ar- or -Ar'- or else is the structural unit wehre X is -O-, -NHCO-, -SO2- or -CO-, -R is lower alkyl and -R' is lower alkyl or alkoxy, and the proportions of the diamine components B, C, D and E are within the following limits: B: 25-47.5 mol % C: 7.5-30 mol D: 45-67.5 mol and E: 20-40 mol.
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公开(公告)号:IE67443B1
公开(公告)日:1996-04-03
申请号:IE51591
申请日:1991-02-14
Applicant: HOECHST AG
Inventor: KEIL GUENTER , HESS REINER , RAPP JOCHEN
Abstract: Aromatic copolyamides are described, which are soluble in organic amide solvents. The polymers are composed to at least 95 mol % of repeat structural units A: -OC-AR-CO- B: -HN-Ar'-NH- C: -HN-Ar''-NH- in the combinations A+B+C+D, or A+C+D+E and up to 5 mol % of m-bond-containing structural units F and/or G derived from aromatic dicarboxylic acids (F') and/or from aromatic diamines (G'), the sum total of the mole fractions of structural units A+F and the sum total of the mole fractions of the structural units of B+C+D+E+G being essentially the same, -Ar- and -Ar'- are divalent aromatic radicals whose C-N valence bonds are in a para-position or in a similar coaxial or parallel position and which may be substituted by one or two inert radicals, such as lower alkykl or halogen, is a trivalent aromatic radical which after removal of the -SO2R group has the same meaning as -Ar- or -Ar'- or else is the structural unit wehre X is -O-, -NHCO-, -SO2- or -CO-, -R is lower alkyl and -R' is lower alkyl or alkoxy, and the proportions of the diamine components B, C, D and E are within the following limits: B: 25-47.5 mol % C: 7.5-30 mol D: 45-67.5 mol and E: 20-40 mol.
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8.
公开(公告)号:CA2117736A1
公开(公告)日:1995-04-09
申请号:CA2117736
申请日:1994-10-07
Applicant: HOECHST AG
Inventor: RAPP JOCHEN , PLANKER SIEGFRIED , PAPENFUHS THEODOR , BARTELS GUENTER
IPC: B01J27/045 , C07B61/00 , C07C227/04 , C07C227/06 , C07C227/08 , C07C229/56
Abstract: The present invention relates to a process for the preparation of 5-fluoroanthranilic alkyl esters and/or 5-fluoroanthranilic acid, which comprises dissolving a 3-fluorobenzoic alkyl ester in sulfuric acid and reacting the solution with nitrating acid at from -10 to 30.degree.C, then adding water, separating off the nitrated reaction product and reacting it with hydrogen at from 50 to 120.degree.C under elevated pressure in the presence of a catalyst comprising a metal of the platinum group and sulfur, and, if desired, removing 5-fluoroanthranilic alkyl esters by distillation and hydrolyzing them to give 5-fluoro-anthranilic acid.
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公开(公告)号:CA2117734A1
公开(公告)日:1995-04-09
申请号:CA2117734
申请日:1994-10-07
Applicant: HOECHST AG
Inventor: ROEHRSCHEID FREIMUND , RAPP JOCHEN , PAPENFUHS THEODOR
IPC: B01J27/128 , C07B61/00 , C07C51/265 , C07C63/70 , C07C227/08 , C07C229/56
Abstract: The present invention relates to a process for the preparation of 5-fluoroanthranilic acid, which comprises reacting 5-fluoro-2-bromotoluene in the presence of a catalyst and of an acidic solvent, with oxygen or an oxygen-containing gas at from 80 to 220.degree.C, separating off the 5-fluoro-2-bromobenzoic acid formed and reacting it with ammonia at from 70 to 180.degree.C.
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公开(公告)号:ZA926129B
公开(公告)日:1993-06-14
申请号:ZA926129
申请日:1992-08-14
Applicant: HOECHST AG
Inventor: RAPP JOCHEN , PAPENFUHS THEODOR
IPC: C07B61/00 , B01J27/122 , C07C227/08 , C07C229/56 , C07C
Abstract: The present invention relates to a process for the preparation of 2-amino-3-chlorobenzoic acid by dissolving 1 mol of 2,3-dichlorobenzoic acid in about 400 to about 2000 parts of water with at least the equimolar amount of an alkali metal hydroxide or with an aqueous solution of the equimolar amount of an alkali metal hydroxide, and subsequently reacting it with about 500 to about 2500 mol % of ammonia at temperatures of about 150 DEG to about 220 DEG C. in the presence of copper bronze, copper(I) salts and/or copper(II) salts.
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