Abstract:
A thermoplastic elastomer composition obtained by heat-treating dynamically a mixture comprising both a thermoplastic resin (A) having a melting point of 165°C or above and an elastomer (B) comprising constituent units derived from a monomer having an ester group in the presence of a crosslinking agent (C) consisting of a polymer (C1) which is composed of constituent units derived from a (meth)acrylic ester and has a weight-average molecular weight (Mw) of 1000 to 30000 and a molecular weight distribution (Mw/Mn) of 1.0 to 4.0 and/or a polymer (C2) which comprises 5 to 35 % by mass of constituent units derived from a (meth)acrylic ester and 65 to 95 % by mass of constituent units derived from an aromatic vinyl monomer and has a weight-average molecular weight of 1000 to 30000 and a molecular weight distribution (Mw/Mn) of 1.0 to 4.0. The composition is excellent in flexibility, heat resistance, mechanical properties, rubber elasticity, and oil resistance and has an excellent sea-island structure as a whole.
Abstract translation:一种热塑性弹性体组合物,其是通过在含有具有165℃以上的熔点的热塑性树脂(A)和含有来自具有酯基的单体的结构单元的弹性体(B)的混合物中动态热处理而得到的热塑性弹性体组合物 (C),由来自(甲基)丙烯酸酯的结构单元构成的重均分子量(Mw)为1000〜30000的聚合物(C1)和分子量分布(Mw) / M n)为1.0〜4.0的聚合物构成单元和/或由来自(甲基)丙烯酸酯的构成单元5〜35质量%和来自芳香族乙烯基单体的构成单元65〜95质量%构成的聚合物(C2) 重均分子量为1000〜30000,分子量分布(Mw / Mn)为1.0〜4.0。 该组合物具有优异的柔韧性,耐热性,机械性能,橡胶弹性和耐油性,整体上具有优良的海岛结构。
Abstract:
A liquid crystal alignment agent containing at least two kinds of polymers selected from the group consisting of polyamic acids and imidized polymers and having a structure obtained by dehydration and ring closure of polyamic acid. In the at least two kinds of polymers contained in the liquid crystal alignment agent, the polymer of higher imidization degree has a smaller surface free energy. The liquid crystal alignment agent gives a liquid crystal display device having less stuck image and high pretilt angle.
Abstract:
Disclosed are a conjugated diolefin (co)polymer rubber formed from either a conjugated diolefin or a conjugated diolefin and an aromatic vinyl compound, wherein the (co) polymer rubber has a primary amino group and an alkoxysilyl group which are bonded to a (co)polymer chain; a process for producing the same; a rubber composition; a composite; and a tire. The (co) polymer rubber has satisfactory processability, and can give an automotive tire tread having a balance among wear resistance, failure characteristics, low hysteresis loss and wet-skid characteristics.
Abstract:
Photosensitive resin composition comprises particulate copolymer, photopolymerizable unsaturated monomer and at least one initiator. A photosensitive resin composition comprises: (1) a particulate copolymer; (2) a photopolymerizable unsaturated monomer; and (3) at least one photopolymerization initiator selected from compounds of formula (I) and (II). [Image] X and Y : H, halogen, carboxyl group, 1-20C monovalent hydrocarbon group or 1-20C alkoxyl group; Z : oxygen, sulfur or a bond. The particulate copolymer comprises (mole%): (A) an aliphatic conjugated diene monomer (10 - 99.8); (B) a monomer which has one polymerizable unsaturated group and an amino group (0.1 - 30); (C) a monomer which has at least two polymerizable unsaturated groups (0.1 - 20); and (D) a copolymerizable monomer having one polymerizable unsaturated group (0 - 40). An independent claim is also included for a photosensitive resin composition which comprises 1), 2), 3) and 4) a block copolymer comprising hard and soft segments as the main components. The hard segment is a thermoplastic non-elastomeric polymer having a glass transition (Tg) not lower than 20 [deg]C. The soft segment is an aliphatic conjugated diene-based elastomeric polymer or a hydrogenated aliphatic conjugated diene-based elastomeric polymer having a Tg not higher than 10 [deg]C.
Abstract:
Photosensitive resin composition comprises particulate copolymer, photopolymerizable unsaturated monomer and at least one initiator. A photosensitive resin composition comprises: (1) a particulate copolymer; (2) a photopolymerizable unsaturated monomer; and (3) at least one photopolymerization initiator selected from compounds of formula (I) and (II). [Image] X and Y : H, halogen, carboxyl group, 1-20C monovalent hydrocarbon group or 1-20C alkoxyl group; Z : oxygen, sulfur or a bond. The particulate copolymer comprises (mole%): (A) an aliphatic conjugated diene monomer (10 - 99.8); (B) a monomer which has one polymerizable unsaturated group and an amino group (0.1 - 30); (C) a monomer which has at least two polymerizable unsaturated groups (0.1 - 20); and (D) a copolymerizable monomer having one polymerizable unsaturated group (0 - 40). An independent claim is also included for a photosensitive resin composition which comprises 1), 2), 3) and 4) a block copolymer comprising hard and soft segments as the main components. The hard segment is a thermoplastic non-elastomeric polymer having a glass transition (Tg) not lower than 20 [deg]C. The soft segment is an aliphatic conjugated diene-based elastomeric polymer or a hydrogenated aliphatic conjugated diene-based elastomeric polymer having a Tg not higher than 10 [deg]C.
Abstract:
Una goma (co)polímero de diolefina conjugada formada a partir de bien una diolefina conjugada o de una diolefina conjugada y un compuesto aromático vinílico, en la que la goma (co)polímero tiene un grupo amino primario y un grupo alkoxisililo unidos a una cadena (co)polímero.
Abstract:
A conjugated diolefin (co)polymer rubber formed from either a conjugated diolefin or a conjugated diolefin and an aromatic vinyl compound and having a primary amino group and alkoxysilyl group bonded to the (co)polymer chain. I t has satisfactory processability and can give an automotive tire tread having a balance among wearing resistance, failure characteristics, low hysteresis loss, and wet skid characteristics.
Abstract:
There are provided a polyamic acid obtainable by reacting a diamine compound of the formula (1) wherein R is an alkyl group having 1 to 12 carbon atoms, a haloalkyl group having 1 to 12 carbon atoms or a halogen atom, each of X and Y is independently a divalent linking group, with a tetracarboxylic acid dianhydride; a polyimide obtainable by dehydrating and ring-closing the above polyamic acid; and a liquid crystal aligning agent containing the above polyamic acid and/or the above polyimide.
Abstract:
Disclosed is a thermoplastic elastomer composition obtained by dynamically heat-treating a mixture containing a thermoplastic resin (A) having a melting point of not less than 200˚C and an elastomer (B) having a constitutional unit derived from an ester group-containing monomer in the presence of a polymer (C-1) which is composed only of a (meth)acrylate unit (c-1) and has a weight average molecular weight Mw of 1,000-30,000 and a molecular weight distribution Mw/Mn of 1.0-4.0 and/or a polymer (C-2) which is composed of 5-35 mass% of a (meth)acrylate unit (c-1) and 65-95 mass% of an aromatic vinyl monomer unit (c-2) and has a weight average molecular weight Mw of 1,000-30,000 and a molecular weight distribution Mw/Mn of 1.0-4.0, as a crosslinking agent (C). Such a thermoplastic elastomer composition has a good sea-island structure as a whole and is excellent in cold resistance. Consequently, the thermoplastic elastomer composition is useful as an alternative to acrylic rubbers.