公开(公告)号：DE4207787A1

公开(公告)日：1992-10-15

申请号：DE4207787

申请日：1992-03-11

Applicant: KAO CORP

Inventor： TAMURA HIROYUKI ,  HATTORI YASUYUKI ,  HASHIBA KUNIZO ,  TABATA OSAMU ,  TSUKADA KIYOSHI ,  FUKUOKA NORIAKI

IPC: C07C29/149 ,  C11B3/02

Abstract: A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm2 in the absolute pressure at a temperature of from 100 DEG to 350 DEG C. in the presence of a catalyst of the following formula (I): CuxXxxYyxOz(I) wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

公开(公告)号：DE4143091A1

公开(公告)日：1992-07-30

申请号：DE4143091

申请日：1991-12-27

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  MORI ATSUHITO ,  KAWAKAMI TAKAHIRO ,  HASHIBA KUNIZO ,  TSUKADA KIYOSHI

IPC: C07C29/149 ,  C07C29/17

Abstract: A process for producing an alcohol from a fatty acid ester, a fatty acid triglyceride or a fatty acid by continuously catalytically reducing the starting material in the presence of a hydrogenation catalyst is disclosed. In the process of the present invention, two reactors (i.e., the main reactor located upstream and the after reactor located downstream) being located in series are employed. In the process of the present invention, two reactors are employed and the temperatures thereof are individually controlled, whereby the conversion ratio is elevated while suppressing the formation of hydrocarbon and aldehyde by-products. Thus, an alcohol of extremely high quality and high purity can be produced. Further, the process of the present invention makes it possible to omit any post-treatment for eliminating the by-products. Furthermore, the active life of the hydrogenation catalyst can be remarkably prolonged by using three reactors (i.e., the guard reactor, the main reactor and the after reactor).

公开(公告)号：DE3533615A1

公开(公告)日：1986-04-03

申请号：DE3533615

申请日：1985-09-20

Applicant: KAO CORP

Inventor： TANIGAKI MASANOBU ,  HASHIBA KUNIZO ,  WADA HIDETOSHI ,  SAKATA MASARU

IPC: C12Q1/00 ,  C12M1/00 ,  C12M1/12 ,  C12M1/40 ,  C12P1/00 ,  C12P7/20 ,  C12P7/64 ,  C12N11/00 ,  C12P7/40

公开(公告)号：PH28856A

公开(公告)日：1995-04-28

申请号：PH43705

申请日：1991-12-26

Applicant: KAO CORP

Inventor： TABATA OSAMU ,  HASHIBA KUNIZO ,  KAWAKAMI TAKAHIRO

IPC: B01J23/86 ,  C07B61/00 ,  C07C29/149 ,  C07C29/17 ,  C07C31/02 ,  C07C31/125

Abstract: A process for producing an alcohol by continuously passing a fatty acid ester, a fatty acid triglyceride or a fatty acid through a hydrogenation catalyst to thereby produce the aimed alcohol through catalytic reduction is disclosed, wherein the employed reactor is a fixed bed reactor in which the liquid phase and the gas phase are continuously passed together in descending parallel flows through the hydrogenation catalyst fixed in the reactor; and at least one cooling mean for cooling the reaction system is provided at a position in the vertical direction of the reactor. According to the process of the present invention with the use of a fixed bed reactor, an alcohol, which has extremely high qualities and a high purity and is contaminated with little hydrocarbon and aldehyde by-products, can be produced. The process of the present invention further makes it possible to omit the post-treatment for eliminating the by-products.

公开(公告)号：FR2673950B1

公开(公告)日：1993-12-03

申请号：FR9202913

申请日：1992-03-11

Applicant: KAO CORP

Inventor： TAMURA HIROYUKI ,  HATTORI YASUYUKI ,  HASHIBA KUNIZO ,  TABATA OSAMU ,  TSUKADA KIYOSHI ,  FUKUOKA NORIAKI

IPC: C11B3/02 ,  C07C29/149 ,  C07C31/02 ,  C07C67/60

Abstract: L'invention a notamment pour objet un procédé pour produire des alcools par réduction catalytique de graisses et d'huiles ou d'esters d'acides gras par l'hydrogène en présence d'un catalyseur pour la réduction des esters. Selon l'invention, lesdites graisses et huiles ou lesdits esters d'acides gras sont préalablement traités dans une atmosphère d'hydrogène ou d'un mélange d'hydrogène et d'un gaz inerte à une température de 100 à 350degré C pour donner une teneur en soufre des graisses et huiles ou des esters d'acides gras de 0,6 ppm ou moins, en présence d'un catalyseur représenté par la formule (I) suivante: (CF DESSIN DANS BOPI) dans laquelle X représente un élément choisi parmi Fe, Zn et Cr; Y représente un élément choisi parmi Al, Si et Ti; x et y représentent chacun une proportion atomique rapportée à la proportion de Cu prise égale à 1, pourvu que x ait une valeur de 0,02 à 2,4 et y une valeur de 0 à 2,0; et z est la proportion d'oxygène satisfaisant les conditions de valences des éléments représentés par X et Y. Applications: fabrication d'alcools de haute pureté avec un bon rendement par réduction.

公开(公告)号：FR2570715A1

公开(公告)日：1986-03-28

申请号：FR8514012

申请日：1985-09-20

Applicant: KAO CORP

Inventor： TANIGAKI MASANOBU ,  HASHIBA KUNIZO ,  WADA HIDETOSHI ,  SAKATA MASARU

IPC: C12Q1/00 ,  C12M1/00 ,  C12M1/12 ,  C12M1/40 ,  C12P1/00 ,  C12P7/20 ,  C12P7/64

公开(公告)号：DE4131209C2

公开(公告)日：2002-06-20

申请号：DE4131209

申请日：1991-09-19

Applicant: KAO CORP

Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  YAMAMURO AKIRA ,  HASHIBA KUNIZO ,  TABATA OSAMU

IPC: C07C29/149

Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50 DEG to 200 DEG C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

公开(公告)号：FR2667062B1

公开(公告)日：1993-12-03

申请号：FR9111659

申请日：1991-09-20

Applicant: KAO CORP

Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  YAMAMURO AKIRA ,  HASHIBA KUNIZO ,  TABATA OSAMU

IPC: C07C29/149 ,  C07C67/60 ,  C11B3/02

Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50 DEG to 200 DEG C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

公开(公告)号：DE4131209A1

公开(公告)日：1992-03-26

申请号：DE4131209

申请日：1991-09-19

Applicant: KAO CORP

Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  YAMAMURO AKIRA ,  HASHIBA KUNIZO ,  TABATA OSAMU

IPC: C07C29/149

Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50 DEG to 200 DEG C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

公开(公告)号：PH25454A

公开(公告)日：1991-07-01

申请号：PH38734

申请日：1989-06-02

Applicant: KAO CORP

Inventor： HATTORI YASUYUKI ,  FUKUOKA NORIAKI ,  TAMURA SHIGERU ,  HASHIBA KUNIZO ,  TSUKADA KIYOSHI ,  MISONO MAKOTO

IPC: B01J23/80 ,  C07B61/00 ,  C07C27/00 ,  C07C29/136 ,  B01J23/72 ,  C07C29/149 ,  C07C67/00 ,  C07C27/08 ,  B01J21/06

Abstract: An alcohol is effective produced by catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing a catalyst precursor comprising (A) copper oxide and (B) titanium oxide and/or titanium hydroxide at a weight ratio of (A) to (B) in the range between 15/85 and 65/35. The component (A) may be alternatively a composite metal oxide comprises copper oxide and up to 20 wt. % of zinc oxide.