公开(公告)号：JP2006016307A

公开(公告)日：2006-01-19

申请号：JP2004192605

申请日：2004-06-30

Applicant: Kao Corp ,  花王株式会社

Inventor： SASA YOSHIMASA ,  MATSUNAGA AKIRA ,  TANAKA TOSHINORI ,  TAWARA HIDEO

IPC: C07F9/09 ,  C07C69/33 ,  C07F9/11

Abstract: PROBLEM TO BE SOLVED: To provide a method capable of efficiently removing orthophosphoric acid from a mixture containing a phosphoric acid ester and orthophosphoric acid produced when producing the phosphoric acid ester by using phosphoric acids such as phosphorus pentoxide (phosphoric anhydride), condensed phosphoric acid (polyphosphoric acid) and orthophosphoric acid and capable of producing, in a high purity, a phosphoric acid monoester in which separation and refining by recrystallization method, etc., was conventionally difficult.
SOLUTION: The method for producing the phosphoric acid monoester comprises adding a polyglycerol fatty acid ester represented by general formula (1) (wherein R
1 , R
2 and R
3 are each a 7-35C straight-chain or branched chain hydrocarbon group; m is ≥1) in an amount of 0.1-2 mass% based on the mixture containing the phosphoric acid monoester, the phosphoric acid diester and orthophosphoric acid to the mixture, when carrying out crystallization treatment of the mixture containing the phosphoric acid monoester, the phosphoric acid diester and orthophosphoric acid by using a solvent composed of a 4-8C straight-chain or branched chain aliphatic hydrocarbon or a 5-7C saturated alicyclic hydrocarbon.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种能够通过使用磷酸如五氧化磷（磷酸酐）生产磷酸酯时产生的磷酸酯和正磷酸的混合物有效地除去正磷酸的方法，缩合 磷酸（多磷酸）和正磷酸，能够高纯度地制造通过重结晶法等进行分离精制的磷酸单酯。 解决方案：制备磷酸单酯的方法包括加入由通式（1）表示的聚甘油脂肪酸酯（其中R 1 ，R 2 和R 相对于含有磷酸单酯的混合物，磷酸为0.1〜2质量％， 3 分别为7-35C直链或支链烃基; m为≥1） 二酯和正磷酸混合时，通过使用由4-8C直链或支链脂族烃组成的溶剂或5元/平方米的溶剂进行含有磷酸单酯，磷酸二酯和正磷酸的混合物的结晶处理 -7C饱和脂环烃。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2003238503A

公开(公告)日：2003-08-27

申请号：JP2002038636

申请日：2002-02-15

Applicant: KAO CORP

Inventor： TANAKA TOSHINORI ,  OMAE KAORU ,  FUKUSHIMA TETSURO

IPC: C07C213/04 ,  C07C215/08 ,  C07C217/08 ,  C07C217/28 ,  C08K5/17 ,  C08L101/00 ,  C09K3/16

Abstract: PROBLEM TO BE SOLVED: To obtain an aliphatic amine ethoxylate composition containing a 2 mol EO adduct to an aliphatic primary amine in a high content and having good quality and to provide a method for producing the composition and to obtain an antistatic agent and an antistatic resin composition. SOLUTION: The method for producing the composition containing the 2 mol EO adduct to the aliphatic primary amine comprises carrying out addition reaction of 1 mol aliphatic primary amine with 1.85-1.99 mol EO at 140-180°C. The aliphatic amine ethoxylate composition has 85-100 pts.wt. content of the 2 mol EO adduct to the aliphatic primary amine, ≤2 wt.% primary amine content, ≤6 wt.% content of 1 mol EO adduct and ≤4 wt.% ≥3 mol EO adduct, and has ≤10 mgKOH/g secondary amine value. The antistatic agent is composed of the composition. The antistatic resin composition is obtained by compounding the antistatic agent with a thermoplastic resin. COPYRIGHT: (C)2003,JPO

公开(公告)号：JP2003231686A

公开(公告)日：2003-08-19

申请号：JP2002029912

申请日：2002-02-06

Applicant: KAO CORP

Inventor： TAWARA HIDEO ,  TANAKA TOSHINORI ,  OMAE KAORU

IPC: C07D317/20 ,  C07D319/06

Abstract: PROBLEM TO BE SOLVED: To provide a method for purifying a glycerol acetal by which discoloration is not caused even by carrying out a reaction in the presence of a basic catalyst using the glycerol acetal after long-term storage as a raw material for various kinds of organic syntheses, and a method for producing an alcoholated substance of the glycerol acetal with suppressed discoloration. SOLUTION: The method for purifying the glycerol acetal selected from the glycerol acetals represented by formula (1) or (2) [wherein, R 1 , R 2 , R 3 and R 4 are the same or different and denote each H, a 1-22C alkyl group or a 12C alkenyl group or an aryl group having 6-30 total number of carbon atoms which may be substituted; and R 1 and R 2 or R 3 and R 4 may be bound to form a ring] by distillation comprises adding a base before carrying out the distillation and then heat-treating the glycerol acetal. The method for producing the alcoholated substance comprises alcoholating the glycerol acetal purified by the method in the presence of the basic catalyst. COPYRIGHT: (C)2003,JPO

公开(公告)号：JP2002234886A

公开(公告)日：2002-08-23

申请号：JP2001282983

申请日：2001-09-18

Applicant: KAO CORP

Inventor： TAWARA HIDEO ,  TANAKA TOSHINORI ,  OMAE KAORU

IPC: C07D317/20

Abstract: PROBLEM TO BE SOLVED: To provide a method for easily and efficiently producing a high-quality acetal in a short time. SOLUTION: This method for producing an acetal comprises reaction between a polyhydric alcohol and a ketone or aldehyde in the equivalent ratio of the ketone or aldehyde to the to-be-acetalized hydroxy groups in the polyhydric alcohol of (0.5-4):2 in the presence of a solid acid catalyst without conducting a substantial dehydration, and distillation of the resultant reaction liquid.

公开(公告)号：JPH0971554A

公开(公告)日：1997-03-18

申请号：JP23129095

申请日：1995-09-08

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  IWAHASHI MASAAKI ,  TANAKA TOSHINORI ,  NAGUMO HIROSHI ,  SAKAI SHIGEFUMI

IPC: A61K8/00 ,  A61K8/37 ,  A61Q19/10 ,  B01J23/02 ,  B01J23/04 ,  C07B61/00 ,  C07C67/02 ,  C07C67/08 ,  C07C67/29 ,  A61K7/50

Abstract: PROBLEM TO BE SOLVED: To obtain an oil agent useful as a functional oil agent for body shampoo having excellent emulsifying property, foaming and feeling of the skin after the use. SOLUTION: This oil agent contains the compounds of formula I [X , X and X are each independently H or formula II (R is a 7-21C alkyl, etc.); A is independently a 2-4C alkylene; (m), (n) and (p) are each 0-100] wherein 0-4wt.% the compound of X =X =X =H, 0-10wt.% the compound of two among X , X and X are equally H and remainder one is of the formula II, 0-40wt.% the compound of one among X , X and X is H and remainder two are of the formula II and >=50wt.% the compound of X =X =X = the formula II. The compound of the formula I is obtained by adding a 2-4C alkylele oxide to trigluyceride of formula III in the presence of an alkoxylating catalyst containing an oxide of an alkali metal, etc.

公开(公告)号：JPH08323200A

公开(公告)日：1996-12-10

申请号：JP13162595

申请日：1995-05-30

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  NAGUMO HIROSHI ,  TANAKA TOSHINORI ,  KONO JUN

IPC: B01J23/08 ,  B01J23/14 ,  B01J23/18 ,  B01J23/24 ,  B01J23/40 ,  B01J23/70 ,  B01J23/755 ,  B01J27/18 ,  C07C67/28 ,  C07C69/24

Abstract: PURPOSE: To produce an ester alkoxylate almost free from unreacted starting materials and a by-product at a high rate in a high yield by using an alkoxylation catalyst contg. magnesium oxide and oxide of an atom belonging to the group IV, VI, etc., in a specified ratio. CONSTITUTION: This alkoxylation catalyst contains a magnesium compd. and oxide of a metallic atom such as antimony or zinc so that the atomic ratio between the metallic atom and magnesium is regulated to (0.002-0.4):1. When this catalyst is used, a 2-4C alkylene oxide is added to a compd. having COOR and the objective compd. having COO(AO)m R is rapidly produced with high selectivity in a high yield. In the formulae, R is a residue obtd. by removing one hydroxyl group from alcohol, etc., A is alkylene and (m) is the average mol number of added alkylene oxide.

公开(公告)号：JPH07233111A

公开(公告)日：1995-09-05

申请号：JP2425594

申请日：1994-02-22

Applicant: KAO CORP

Inventor： TANAKA TOSHINORI ,  IMANAKA TAKEHIRO ,  KONO JUN ,  NAGUMO HIROSHI ,  YOKOTA YUKINAGA

IPC: B01J31/02 ,  C07B61/00 ,  C07C41/03 ,  C07C43/11 ,  C08G65/28

Abstract: PURPOSE:To obtain a polyether compound having narrow addition molar number distribution and high quality by carrying out an alkylene oxide addition reaction of an alcohol having low reactivity using a specific high-performance catalyst exhibiting sufficiently high activity even at a low temperature. CONSTITUTION:This polyether compound (having an average alkylene oxide addition molar number of 1-10) is produced by using a quaternary ammonium salt expressed by formula I (R and R each is a 1-20C alkyl, an aralkyl or an aryl; X is COOH or a 1-20C fatty acid residue) as a catalyst and reacting an aliphatic mono or polyhydric alcohol with an alkylene oxide under a pressure of about 0.5-10kg/cm at about 40-90 deg.C. The quaternary ammonium salt to be used as the catalyst is especially preferably a compound of formula II (R to R each is a 1-20C alkyl, an aralkyl or an aryl), e.g. tetramethylammonium hydroxide, tetraethylammonium hydroxide and tetrabutylammonium hydroxide.

公开(公告)号：JP2003034668A

公开(公告)日：2003-02-07

申请号：JP2001217598

申请日：2001-07-18

Applicant: Kao Corp ,  花王株式会社

Inventor： IMANAKA TAKEHIRO ,  TANAKA TOSHINORI ,  TAWARA HIDEO

IPC: A61K8/00 ,  A61K8/37 ,  A61Q1/02 ,  A61Q1/14 ,  A61Q5/02 ,  C07C67/02 ,  C07C67/54 ,  C07C69/708 ,  C11D1/72 ,  A61K7/02

Abstract: PROBLEM TO BE SOLVED: To provide a new monoglyceride.
SOLUTION: The new monoglyceride is an ether carboxylate monoglyceride represented by the general formula (1) [in the formula, A is a group represented by formula RO(GO)
m (CH
2 )
n CO-, wherein, R is a 1-50C straight or branched chain alkyl or alkenyl group, GO is a 2-4C oxyalkylene group and m is a number of 1-50 which represents an average mole number of alkyleneoxide adduct and GO among m may be the same or different from each other, and n is an integer of 1-6].
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：提供新的单甘油酯。 解决方案：新的单酸甘油酯是由通式（1）表示的醚羧酸盐单酸甘油酯[在式中，A是由式RO（GO）m（CH 2）n CO-表示的基团，其中R是1-50℃ 直链或支链烷基或烯基，GO是2-4C氧化烯基，m是1-50，其代表环氧烷烃加合物的平均摩尔数，m中的GO可以相同或不同， n为1-6的整数]。

公开(公告)号：JP2003012603A

公开(公告)日：2003-01-15

申请号：JP2001203068

申请日：2001-07-04

Applicant: Kao Corp ,  花王株式会社

Inventor： TAWARA HIDEO ,  TANAKA TOSHINORI ,  OMAE KAORU

IPC: C07D317/20 ,  B01D11/04 ,  B01F17/38 ,  C07C67/297 ,  C07C69/30 ,  C11C3/10

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a monoglyceride in, a high purity, simply and in a good efficiency.
SOLUTION: This method for producing the monoglyceride is provided by performing an ester interchange reaction of a carboxylic acid ester, glycerol and an acetal with glycerol in the presence of a catalyst while removing an alcohol to obtain a mixture containing an acetal with a monoglyceride, and removing the acetal portion by hydrolysis.
COPYRIGHT: (C)2003,JPO

Abstract translation: 要解决的问题：提供一种高纯度，简单且高效率地制备单酸甘油酯的方法。 解决方案：制备单酸甘油酯的方法是通过在催化剂存在下，通过羧酸酯，甘油和缩醛与甘油的酯交换反应，同时除去醇，得到含有单酸甘油酯的缩醛的混合物，以及 通过水解除去缩醛部分。

公开(公告)号：JP2002363134A

公开(公告)日：2002-12-18

申请号：JP2001167025

申请日：2001-06-01

Applicant: KAO CORP

Inventor： IMANAKA TAKEHIRO ,  TANAKA TOSHINORI ,  TAWARA HIDEO ,  OMAE KAORU

IPC: C07C67/28 ,  C07B61/00 ,  C07C69/003 ,  C07C69/708 ,  C07C69/732 ,  C07C69/78 ,  C11B11/00 ,  C11C3/00 ,  C11C3/10

Abstract: PROBLEM TO BE SOLVED: To provide a method for easily and efficiently producing a monoglyceride in high purity. SOLUTION: This method for producing a monoglyceride comprises the steps of carrying out a transesterification between a glycerol acetalized product and a raw material glyceride having as a constituent acyl groups each bearing at least one group selected from OH, ether group, aromatic ring, halogen atom, amido group, nitrile group, nitro group, thiol group and sulfido group to obtain a monoglyceride acetal-containing mixture, removing the unreacted glycerol acetalized product and glycerol from the mixture and then carrying out a deacetalization reaction through hydrolysis.