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公开(公告)号:JPH11269484A
公开(公告)日:1999-10-05
申请号:JP1250399
申请日:1999-01-20
Applicant: LUBRIZOL CORP
Inventor: JAYNES SCOT E , SWEET WILLIAM R
IPC: C07C51/41 , C07C53/126 , C09D7/12 , C10M159/20 , C10M177/00 , C10N30/04 , C10N70/00 , C11C3/00
Abstract: PROBLEM TO BE SOLVED: To provide a process for preparing an excellent overbased gel and to provide coatings and other materials contg. the gel. SOLUTION: An overbased calcium carboxylate gel is prepd. by a process comprising (I) the step of treating an about 8-30C carboxylic acid or its reactive equivalent with calcium oxide or hydroxide in an equivalent ratio of about (2/1)-(10/1) in the presence of an org. solvent; (II) the step of converting the mixture from step I into a carbonate at about 50-100 deg.C in the presence of an accelerator system contg. water and a 1-8C alcohol under the condition that the alcohol/water molar ratio is substantially const. and is such that the viscosity of the mixture is kept at about 1,000 cP or lower during the whole step II and the amt. of the alcohol is adjusted, esp. when in the presence of calcium hydroxide, so that this viscosity is kept during the whole step II; (III) the step of further adding water and the alcohol and causing the mixture from step II to gel at about 25-100 deg.C provided stripping is not conducted at between step II and step 11; and optionally (IV) the step of removing water and the alcohol.
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公开(公告)号:CA2133393C
公开(公告)日:2005-09-20
申请号:CA2133393
申请日:1994-09-30
Applicant: LUBRIZOL CORP
Inventor: VINCI JAMES N , SWEET WILLIAM R
IPC: C10M159/20 , C10N30/04
Abstract: Gelled overbased materials are prepared by mixing an overbased composition of a metal salt of an organic acid material containing at least 8 carbon atoms, a metal salt of an organic acid material containing fewer than 6 carbon atoms, and a metal carbonate in an oleophilic medium, with an alcohol or an alcohol-water mixture, and heating the mixture.
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公开(公告)号:CA2506631A1
公开(公告)日:2004-06-10
申请号:CA2506631
申请日:2003-11-21
Applicant: LUBRIZOL CORP
Inventor: MALCHOW GEORGE A JR , BAUMANN ALBERT F , YI OKSON , PERZ JOHN S , QUINN ROBERT E , SWEET WILLIAM R , MATHUR NARESH C , LARSEN JOHN H , POLLACK ROBERT A
Abstract: The present invention is directed a rheology control additive for solvent based coating and ink formulations comprising an overbased carboxylate or sulfonate in combination with a hydrocarbyl succinic anhydride based dispersant. The combination of dispersant with carboxylate or sulfonate offe rs proportionately less viscosity decrease at elevated temperatures and control of viscosity under various shear rates.
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公开(公告)号:AU7428394A
公开(公告)日:1995-04-13
申请号:AU7428394
申请日:1994-09-29
Applicant: LUBRIZOL CORP
Inventor: VINCI JAMES N , SWEET WILLIAM R
IPC: C10M159/20 , C10N30/04 , C10M129/48
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公开(公告)号:AT307665T
公开(公告)日:2005-11-15
申请号:AT99310113
申请日:1999-12-15
Applicant: LUBRIZOL CORP
Inventor: LAWATE SAURABH S , SWEET WILLIAM R
Abstract: A stable emulsion composition is disclosed which comprises: (A) a metal overbased gelled composition, prepared by forming a mixture of (i) a carbonated overbased material in an oleophilic medium, which material contains a metal salt of at least one organic acid material containing at least 8 carbon atoms, and (ii) an alcohol or an alcohol-water mixture; (B) a surfactant; and (C) an aqueous liquid. The stable emulsion composition may further comprise at least one of a solute, a suspended solid or an oxidation inhibitor.
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公开(公告)号:ES2201070T3
公开(公告)日:2004-03-16
申请号:ES94307234
申请日:1994-10-03
Applicant: LUBRIZOL CORP
Inventor: VINCI JAMES N , SWEET WILLIAM R
IPC: C10M159/20 , C10N30/04
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公开(公告)号:BR9900239A
公开(公告)日:2000-05-09
申请号:BR9900239
申请日:1999-01-19
Applicant: LUBRIZOL CORP
Inventor: JAYNES SCOT E , SWEET WILLIAM R
IPC: C07C51/41 , C07C53/126 , C09D7/12 , C10M159/20 , C10M177/00 , C10N30/04 , C10N70/00 , C11C3/00 , C10M105/36
Abstract: The present invention is directed to a process for preparing a gelled overbased calcium carboxylate which involves carbonating a carboxylic acid of 8 to 30 carbon atoms in the presence of a promoter system consisting of water and an alcohol of 1 to 8 carbon atoms, such that the mole ratio of alcohol to water is substantially constant and is such that the viscosity of the reaction mixture during carbonation step does not exceed 1 pascal second (1000 centipoise). This process prevents excessive thickening of the reaction mixture in a manufacturing unit during carbonation and affords ample time to complete the process of carbonation without premature crystallization of the calcium carbonate formed during overbasing.
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公开(公告)号:CA2470953A1
公开(公告)日:2003-06-26
申请号:CA2470953
申请日:2002-12-16
Applicant: LUBRIZOL CORP
Inventor: SIVIK MATTHEW R , SWEET WILLIAM R
IPC: C08L23/00 , C08K5/098 , C08K5/138 , C10M169/04 , C21D1/58
Abstract: Quenching oil composition comprising (1) an oil having kinematic viscosity (ASTM Test Method D-445) at 40 ~C ranging from about 4 to about 45 mm2sec-1 (about 40 to about 210 Saybolt Universal Seconds (SUS)) and having a saturat ed content from about 80 % to about 100 %; (2) an aliphatic polyolefin having M n ranging from about 300 to about 10,000; and (3) at least one member selected from members of the groups consisting of (a) a metal salt of hydrocarbyl substituted phenols, salicylic acids, carboxylic acids, and sulfonic acids a nd alkaline earth metal salts of hydrocarbyl substituted saligenin derivatives; and optionally, at least one member selected from members of the groups consisting of (b) hydrocarbyl substituted succinic esters, amides, ester- amides, imides, amine salts, acid-esters, acid-amides ester-amine salts, ami de- amine-salts and acid-amine salts.
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公开(公告)号:CA2292251A1
公开(公告)日:2000-06-17
申请号:CA2292251
申请日:1999-12-10
Applicant: LUBRIZOL CORP
Inventor: SWEET WILLIAM R , LAWATE SAURABH S
Abstract: A stable emulsion composition is disclosed which comprises: (A) a metal overbased gelled composition, prepared by forming a mixture of (i) a carbonated overbased material in an oleophilic medium, which material contains a metal salt of at least one organic acid material containing at least 8 carbon atoms, and (ii) an alcohol or an alcohol-water mixture; (B) a surfactant; and (C) an aqueous liquid. The stable emulsion composition may further comprise at least one of a solute; a suspended solid or an oxidation inhibitor.
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公开(公告)号:AU1128799A
公开(公告)日:1999-08-12
申请号:AU1128799
申请日:1999-01-12
Applicant: LUBRIZOL CORP
Inventor: JAYNES SCOT E , SWEET WILLIAM R
IPC: C07C51/41 , C07C53/126 , C09D7/12 , C10M159/20 , C10M177/00 , C10N30/04 , C10N70/00 , C11C3/00 , C10M129/42
Abstract: The present invention is directed to a process for preparing a gelled overbased calcium carboxylate which involves carbonating a carboxylic acid of 8 to 30 carbon atoms in the presence of a promoter system consisting of water and an alcohol of 1 to 8 carbon atoms, such that the mole ratio of alcohol to water is substantially constant and is such that the viscosity of the reaction mixture during carbonation step does not exceed 1 pascal second (1000 centipoise). This process prevents excessive thickening of the reaction mixture in a manufacturing unit during carbonation and affords ample time to complete the process of carbonation without premature crystallization of the calcium carbonate formed during overbasing.
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