公开(公告)号：US3883573A

公开(公告)日：1975-05-13

申请号：US37028773

申请日：1973-06-15

Applicant: STANDARD OIL CO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R ,  WHITE JAMES F

IPC: B01J8/06 ,  B01J23/88 ,  B01J27/192 ,  B01J27/195 ,  C07C121/02

CPC classification number: C07C253/26 ,  B01J8/06 ,  B01J27/192 ,  B01J27/195 ,  B01J2208/00212 ,  B01J2208/00256 ,  B01J2208/00876 ,  Y02P20/52 ,  C07C255/08

Abstract: Very desirable temperature control in the ammoxidation of propylene or isobutylene in a fixed-bed, tubular reactor is obtained by using an oxidation catalyst having two physical forms. The first catalyst which initially contacts the reactants is an essentially inert support having a strongly adhering coat of a catalytic material, and the second catalyst that contacts the reactants after contact with the first catalyst consists essentially of the catalytic material.

Abstract translation: 通过使用具有两种物理形式的氧化催化剂，可以获得固定床，管式反应器中丙烯或异丁烯的氨氧化反应非常理想的温度控制。 最初与反应物接触的第一催化剂是具有催化材料的强粘附层的基本上惰性的载体，并且在与第一催化剂接触之后与反应物接触的第二催化剂基本上由催化材料组成。

公开(公告)号：US3875220A

公开(公告)日：1975-04-01

申请号：US40530973

申请日：1973-10-11

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J27/199 ,  C07C51/25 ,  C07C57/055 ,  C07C57/04 ,  C07C51/30

CPC classification number: B01J23/8878 ,  B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/8877 ,  B01J23/8885 ,  B01J27/199 ,  B01J2523/00 ,  C07C51/252 ,  C07C57/04 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/67 ,  B01J2523/14 ,  B01J2523/847 ,  B01J2523/24 ,  B01J2523/397 ,  B01J2523/845 ,  B01J2523/28 ,  B01J2523/54 ,  B01J2523/822 ,  B01J2523/3712 ,  B01J2523/53 ,  B01J2523/18 ,  B01J2523/17 ,  B01J2523/43

Abstract: Catalysts containing phosphorus, vanadium and molybdenum have been found to be especially effective for the oxidation of methacrolein with molecular oxygen to obtain methacrylic acid. The catalysts may be optionally promoted with Bi, As, B, Ce, Cr, Ag, Fe, W, Pb, Mn, Tl, Te, Ni, Nb, B, Sn and/or Cu.

Abstract translation: 已经发现含有磷，钒和钼的催化剂对于用分子氧氧化甲基丙烯醛特别有效，以获得甲基丙烯酸。 可以任选地用Bi，As，B，Ce，Cr，Ag，Fe，W，Pb，Mn，Tl，Te，Ni，Nb，B，Sn和/或Cu来促进催化剂。

公开(公告)号：RO69968A

公开(公告)日：1981-06-26

申请号：RO8721776

申请日：1976-08-05

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J23/24 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J23/16 ,  C07C57/04

公开(公告)号：CA1090770A

公开(公告)日：1980-12-02

申请号：CA281680

申请日：1977-06-29

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  APPLEQUIST MICHAEL D

IPC: B01J23/00 ,  B01J23/88 ,  B01J23/89 ,  B01J27/00 ,  B01J27/057 ,  B01J27/192 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J27/14 ,  C07C57/04

Abstract: PREPARATION OF METHACRYLIC ACID FROM METHACROLEIN Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, bismuth, copper, oxygen, a halogen selected from the group consisting of chlorine, bromine or iodine, and optionally, at least one element selected from the group consisting of Fe, Cr, Ni, Mn, Sb, Te, Rh, and Pd.

公开(公告)号：CS200529B2

公开(公告)日：1980-09-15

申请号：CS639778

申请日：1978-10-03

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST C

IPC: C07D307/60

公开(公告)号：CS200528B2

公开(公告)日：1980-09-15

申请号：CS671277

申请日：1977-10-14

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST

IPC: C07D307/60

公开(公告)号：CA1083165A

公开(公告)日：1980-08-05

申请号：CA286647

申请日：1977-09-13

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WHITE JAMES F ,  MILBERGER ERNEST C

IPC: C07D307/60 ,  B01J27/00 ,  B01J27/192 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: PREPARATION OF MALEIC ANHYDRIDE FROM FOUR-CARBON HYDROCARBONS Maleic anhydride is produced by the oxidation of n-butane, n-butenes, 1,3-butadiene with molecular oxygen in the vapor phase in the presence of catalysts containing molybdenum, phosphorus, oxygen and the following components delineated in Groups I to IV: (I) bismuth, copper and a halogen selected from the group consisting of chlorine, bromine or iodine; or (II) arsenic and at least one element selected from the group consisting of Sn, rare earth metal, Zr, Rh, Mn, Re, Ru, Cu, Pb, Zn, Ti, Cr, Nb, Al, Ga and alkaline earth metal; or (III) at least one element selected from the group consisting of As, Rb, Pd, Cd, Cs, Tl and In; or (IV) rubidium, and at least one element selected from the group consisting of Sn, rare earth element, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co and Cu.

公开(公告)号：CS196318B2

公开(公告)日：1980-03-31

申请号：CS532776

申请日：1976-08-16

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J27/18 ,  B01J21/16 ,  B01J23/16 ,  B01J23/88 ,  B01J27/00 ,  B01J27/186 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055 ,  C07C67/00 ,  C07C57/05

Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.

公开(公告)号：CA1059532A

公开(公告)日：1979-07-31

申请号：CA258069

申请日：1976-07-29

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  REGE JAMES R

IPC: B01J23/24 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

Abstract: PROCESS FOR THE PREPARATION OF UNSATURATED ACIDS FROM UNSATURATED ALDEHYDES Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, and promoted with chromium or at least one element selected from the group consisting of thallium, rubidium, cesium, potassium, titanium and arsenic, or a mixture thereof, wherein at least part of the molybdenum employed in the preparation of the catalyst is supplied in the form of molybdenum trioxide. The oxidation of methacrolein in the presence of a catalyst wherein all the molybdenum employed in the preparation of the catalyst has been supplied by molybdenum trioxide gives especially desirable high yields and selectivities to methacrylic acid.

公开(公告)号：DD133431A5

公开(公告)日：1979-01-03

申请号：DD20157477

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES F ,  SHAW WILFRID G ,  APPLEQUIST MICHAEL D

IPC: B01J23/28 ,  B01J23/54 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  B01J27/24 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  B01J21/00 ,  B01J23/00 ,  B01J27/16 ,  C07C51/26