公开(公告)号：WO0160945A2

公开(公告)日：2001-08-23

申请号：PCT/EP0101838

申请日：2001-02-16

Applicant: STICHTING TECH WETENSCHAPP ,  DORENBOS PIETER ,  EIJK CAREL WILHELM EDUARD VAN ,  GUEDEL HANS ULRICH ,  KRAEMER KARL WILHELM ,  LOEF EDGAR VALENTIJN DIEUWER V

Inventor： DORENBOS PIETER ,  VAN EIJK CAREL WILHELM EDUARD ,  GUEDEL HANS-ULRICH ,  KRAEMER KARL WILHELM ,  VAN LOEF EDGAR VALENTIJN DIEUW

IPC: G01T1/20 ,  C01F17/00 ,  C09K11/00 ,  C09K11/08 ,  C09K11/77 ,  C09K11/85 ,  C30B29/12 ,  G01T1/202

CPC classification number: G01T1/2023 ,  C01F17/0056 ,  C01F17/0068 ,  C09K11/7772

Abstract: The invention concerns an inorganic scintillator material of general composition M>1-x x 3

Abstract translation: 本发明涉及通用组合物M> 1-x x xBr 3的无机闪烁体材料，其中：M选自La，Gd，Y中的镧系元素或镧系元素混合物，特别是镧系元素或 由La，Gd组成的组的镧系元素混合物; x是M与铈的摩尔取代度，x不小于0.01mol％且严格小于100mol％。 本发明还涉及用于生长这种单晶闪烁体材料的方法，以及其用于工业和医疗目的的闪烁检测器的组分或在石油工业中的用途。

公开(公告)号：WO0160944A3

公开(公告)日：2002-02-14

申请号：PCT/EP0101837

申请日：2001-02-16

Applicant: STICHTING TECH WETENSCHAPP ,  DORENBOS PIETER ,  EIJK CAREL WILHELM EDUARD VAN ,  GUEDEL HANS ULRICH ,  KRAEMER KARL WILHELM ,  LOEF EDGAR VALENTIJN DIEUWER V

Inventor： DORENBOS PIETER ,  VAN EIJK CAREL WILHELM EDUARD ,  GUEDEL HANS-ULRICH ,  KRAEMER KARL WILHELM ,  VAN LOEF EDGAR VALENTIJN DIEUW

IPC: G01T1/20 ,  C01F17/00 ,  C09K11/00 ,  C09K11/08 ,  C09K11/77 ,  C09K11/85 ,  C30B29/12 ,  G01T1/202

CPC classification number: G01T1/2023 ,  C01F17/0056 ,  C01F17/0068 ,  C09K11/7772

Abstract: The invention concerns an inorganic scintillator material of general composition M1-xCexCl3, wherein: M is selected among lanthanides or lanthanide mixtures, preferably among the elements or mixtures of elements of the group consisting of Y, La, Gd, Lu, in particular among the elements or mixtures of elements of the group consisting of La, Gd and Lu; and x is the molar rate of substitution of M with cerium, x being not less than 1 mol %and strictly less than 100 mol %. The invention also concerns a method for growing said monocrystalline scintillator material, and the use of said scintillator material as component of a scintillating detector in particular for industrial and medical purposes and in the oil industry.

Abstract translation: 本发明涉及一般组合物M1-xCexCl3的无机闪烁体材料，其中：M选自镧系元素或镧系元素混合物，优选选自Y，La，Gd，Lu中的元素或元素混合物，特别是在 由La，Gd和Lu组成的组分元素或元素的混合物; x是M与铈的摩尔摩尔比，x不小于1摩尔％，严格小于100摩尔％。 本发明还涉及用于生长所述单晶闪烁体材料的方法，以及使用所述闪烁体材料作为闪烁检测器的组分，特别用于工业和医疗目的以及在石油工业中。

公开(公告)号：WO2005068585A8

公开(公告)日：2006-09-28

申请号：PCT/EP2005000098

申请日：2005-01-10

Applicant: STICHTING TECH WETENSCHAPP ,  UNIV BERNE ,  KRAMER KARL WILHELM ,  GUEDEL HANS-ULRICH ,  BESSIERE AURELIE ,  DORENBOS PIETER ,  VAN EIJK CAREL WILHELM EDUARD

Inventor： KRAMER KARL WILHELM ,  GUEDEL HANS-ULRICH ,  BESSIERE AURELIE ,  DORENBOS PIETER ,  VAN EIJK CAREL WILHELM EDUARD

IPC: C09K11/77 ,  G01T3/00

CPC classification number: C09K11/7772 ,  C30B11/00 ,  C30B29/12

Abstract: The invention pertains to a neutron detector comprising a scintillating material of the generic formula Cs ( 2-z ) Rb Z LiLn(1- X )X 6 : xCe 3+ , where X is either Br or I, Ln is Y or Gd or Lu or Sc or La, where z is greater or equal to 0 and less or equal to 2, and x is above 0.0005, generally under the form of monocristal. The scintillating material has a remarkably low decay time.

Abstract translation: 本发明涉及一种中子检测器，其包括通式为Cs（2-z）R b R z LiLn（1-Sub）的闪烁材料 其中X为Br或I，Ln为Y或Gd或Lu或Sc或La，其中z为X或X， 大于或等于0且小于或等于2，并且x大于0.0005，通常为单晶形式。 闪烁材料具有非常低的衰减时间。

公开(公告)号：EP2912143A4

公开(公告)日：2016-10-19

申请号：EP13849213

申请日：2013-10-28

Applicant: STICHTING TECH WETENSCHAPP ,  SAINT GOBAIN CERAMICS ,  UNIV BERNE

Inventor： DORENBOS PIETER ,  MENGE PETER R ,  OUSPENSKI VLADIMIR ,  KRÄMER KARL W

IPC: C09K11/77 ,  G01T1/20 ,  G21K4/00

CPC classification number: G01T1/2023 ,  C09K11/7772 ,  C09K11/7773 ,  G01T1/2006 ,  G21K4/00 ,  G21K2004/06

Abstract: A scintillation crystal can include Ln(1-y)REyX3, wherein Ln represents a rare earth element, RE represents a different rare earth element, y has a value in a range of 0 to 1, and X represents a halogen. In an embodiment, the scintillation crystal is doped with a Group 1 element, a Group 2 element, or a mixture thereof, and the scintillation crystal is formed from a melt having a concentration of such elements or mixture thereof of at least approximately 0.02 wt. %. In another embodiment, the scintillation crystal can have unexpectedly improved proportionality and unexpectedly improved energy resolution properties. In a further embodiment, a radiation detection apparatus can include the scintillation crystal, a photosensor, and an electronics device. Such a radiation detection apparatus can be useful in a variety of applications.

公开(公告)号：CA2622381C

公开(公告)日：2014-05-20

申请号：CA2622381

申请日：2006-09-15

Applicant: STICHTING TECH WETENSCHAPP ,  UNIV BERNE

Inventor： VAN EIJK CAREL WILHELM EDUARD ,  GUDEL HANS-ULRICH ,  BIROWOSUTO MUHAMMAD DANANG ,  DORENBOS PIETER ,  KRAMER KARL WILHELM

IPC: C01F17/00 ,  C09K11/85 ,  C30B29/12 ,  G01T1/164 ,  G01T1/202

Abstract: The invention concerns a material comprising a compound of formula Pr(1-x-y)LnyCexX3 wherein - Ln is chosen from the elements or mixtures of at least two elements, of the group: La, Nd, Pm, Sm, Eu, Gd, Y, - X is chosen from the halides or mixtures of at least two halides, of the group: Cl, Br, I, - x is above 0.0005 and is lower than 1 , - y is from 0 to less than 1 and - x+y) is less than 1 , and its use as scintillation detector, for example in PET scanner with time of flight apabilities.

公开(公告)号：DE602004004396T2

公开(公告)日：2007-11-08

申请号：DE602004004396

申请日：2004-06-01

Applicant: STICHTING TECH WETENSCHAPP ,  UNIV BERNE

Inventor： DORENBOS PIETER ,  VAN EIJK WILHELM ,  GUDEL HANS-ULRICH ,  VAN LOEF VALENTIJN ,  KRAMER WILHELM

IPC: G01T1/202 ,  C09K11/77 ,  C09K11/85

Abstract: The invention relates to an inorganic rare-earth iodide scintillation material of formula A X Ln (y-y',) Ln' y' I (x+3y) in which: A represents at least one element selected among Li, Na, K, Rb, Cs; Ln represents at least one first rare-earth element selected among La, Gd, Y, Lu, said first rare-earth element having a valency of 3+ in the aforementioned formula: Ln' represents at least one second rare-earth element selected among Ce, Tb, Pr, said second rare-earth element having a valency of 3+ in the aforementioned formula, x is an integer and represents 0, 1, 2 or 3; y is an integer or non-integer greater than 0 and less than 3, and; y' is an integer or non-integer greater than 0 and less than y. This material presents a high stopping power, a rapid decay time, in particular, less than 100 ns, a good energy resolution (in particular, less than 6% at 662 keV) and a high luminous level. This material can be used in nuclear medicine equipment, in particular, in Anger-type gamma cameras and in positron emission tomography scanners.

公开(公告)号：AT352046T

公开(公告)日：2007-02-15

申请号：AT04739492

申请日：2004-06-01

Applicant: STICHTING TECH WETENSCHAPP ,  UNIV BERN

Inventor： DORENBOS PIETER ,  VAN EIJK CAREL WILHELM EDUARD ,  GUDEL HANS-ULRICH ,  VAN LOEF EDGAR VALENTIJN DIEUW ,  KRAMER KARL WILHELM

IPC: C09K11/77 ,  G01T1/202 ,  C09K11/85

Abstract: The invention relates to an inorganic rare-earth iodide scintillation material of formula A X Ln (y-y',) Ln' y' I (x+3y) in which: A represents at least one element selected among Li, Na, K, Rb, Cs; Ln represents at least one first rare-earth element selected among La, Gd, Y, Lu, said first rare-earth element having a valency of 3+ in the aforementioned formula: Ln' represents at least one second rare-earth element selected among Ce, Tb, Pr, said second rare-earth element having a valency of 3+ in the aforementioned formula, x is an integer and represents 0, 1, 2 or 3; y is an integer or non-integer greater than 0 and less than 3, and; y' is an integer or non-integer greater than 0 and less than y. This material presents a high stopping power, a rapid decay time, in particular, less than 100 ns, a good energy resolution (in particular, less than 6% at 662 keV) and a high luminous level. This material can be used in nuclear medicine equipment, in particular, in Anger-type gamma cameras and in positron emission tomography scanners.

公开(公告)号：DE60107659T2

公开(公告)日：2005-12-08

申请号：DE60107659

申请日：2001-02-16

Applicant: STICHTING TECH WETENSCHAPP

Inventor： DORENBOS PIETER ,  VAN EIJK WILHELM ,  GUEDEL HANS-ULRICH ,  KRAEMER WILHELM ,  VAN LOEF VALENTIJN

IPC: G01T1/20 ,  C01F17/00 ,  C09K11/00 ,  C09K11/08 ,  C09K11/77 ,  C09K11/85 ,  C30B29/12 ,  G01T1/202

Abstract: The invention concerns an inorganic scintillator material of general composition M1-xCexCl3, wherein: M is selected among lanthanides or lanthanide mixtures, preferably among the elements or mixtures of elements of the group consisting of Y, La, Gd, Lu, in particular among the elements or mixtures of elements of the group consisting of La, Gd and Lu; and x is the molar rate of substitution of M with cerium, x being not less than 1 mol % and strictly less than 100 mol %. The invention also concerns a method for growing said monocrystalline scintillator material, and the use of said scintillator material as component of a scintillating detector in particular for industrial and medical purposes and in the oil industry.

公开(公告)号：AT284436T

公开(公告)日：2004-12-15

申请号：AT01905799

申请日：2001-02-16

Applicant: STICHTING TECH WETENSCHAPP

Inventor： DORENBOS PIETER ,  VAN EIJK CAREL WILHELM EDUARD ,  GUEDEL HANS-ULRICH ,  KRAEMER KARL WILHELM ,  VAN LOEF EDGAR VALENTIJN DIEUW

IPC: G01T1/20 ,  C01F17/00 ,  C09K11/00 ,  C09K11/08 ,  C09K11/77 ,  C09K11/85 ,  C30B29/12 ,  G01T1/202

Abstract: The invention concerns an inorganic scintillator material of general composition M1-xCexCl3, wherein: M is selected among lanthanides or lanthanide mixtures, preferably among the elements or mixtures of elements of the group consisting of Y, La, Gd, Lu, in particular among the elements or mixtures of elements of the group consisting of La, Gd and Lu; and x is the molar rate of substitution of M with cerium, x being not less than 1 mol % and strictly less than 100 mol %. The invention also concerns a method for growing said monocrystalline scintillator material, and the use of said scintillator material as component of a scintillating detector in particular for industrial and medical purposes and in the oil industry.

公开(公告)号：AT477509T

公开(公告)日：2010-08-15

申请号：AT06778442

申请日：2006-09-15

Applicant: STICHTING TECH WETENSCHAPP ,  UNIV BERNE

Inventor： VAN EIJK CAREL WILHELM EDUARD ,  GUEDEL HANS-ULRICH ,  BIROWOSUTO MUHAMMAD DANANG ,  DORENBOS PIETER ,  KRAEMER KARL WILHELM

IPC: G01T1/203 ,  C01F17/00 ,  C09K11/85

Abstract: The invention concerns a material comprising a compound of formula Pr(1-x-y)LnyCexX3 wherein—Ln is chosen from the elements or mixtures of at least two elements, of the group: La, Nd, Pm, Sm, Eu, Gd, Y, —X is chosen from the halides or mixtures of at least two halides, of the group: Cl, Br, I, —x is above 0.0005 and is lower than 1, —y is from 0 to less than 1 and—x+y) is less than 1, and its use as scintillation detector, for example in PET scanner with time of flight capabilities.