公开(公告)号：BR0213905A

公开(公告)日：2004-08-31

申请号：BR0213905

申请日：2002-11-06

Applicant: BASF AG ,  SYMYX TECHNOLOGIES INC

Inventor： KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

IPC: A01N43/38 ,  A01N25/04 ,  A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  C08F220/60

Abstract: The invention relates to a solid crop protection formulation comprising a) cinidon-ethyl as a crop protection agent; b) at least one random radical copolymer comprising as polymerized units at least one hydrophilic and at least one hydrophobic monomer; and c) optionally further additives, wherein at least 50% of the dispersed cinidon-ethyl particles in said solid crop protection formulation are in an X-ray amorphous state and an aqueous dispersion formulation thereof. Additionally, the invention relates to processes for preparing said formulations and the use of said formulations in agriculture. Further, the invention relates to a random radical copolymer essentially consisting of as polymerized units a) 5 to 95% by weight of styrene as component A; b) 5 to 95% by weight of DMAPMAM (dimethylaminopropyl methacrylic amide) as component B; c) 0 to 98% by weight of methyl acrylate and/or vinyl acetate as component C.

公开(公告)号：CA2290394C

公开(公告)日：2006-02-28

申请号：CA2290394

申请日：1999-04-02

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LEE THOMAS S ,  NIELSEN RALPH B ,  FRECHET JEAN M J ,  SAFIR ADAM ,  BENNETT JAMES ,  CARLSON ERIC ,  DALES G CAMERON ,  KUEBLER SIGRID C ,  PETRO MIROSLAV

IPC: G01N30/02 ,  G01N37/00 ,  B01D15/08 ,  B01D15/26 ,  B01D15/32 ,  B01D15/34 ,  B01J19/00 ,  B01J19/26 ,  C40B40/14 ,  C40B40/18 ,  G01N1/00 ,  G01N1/14 ,  G01N15/02 ,  G01N21/53 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/54 ,  G01N30/60 ,  G01N30/74 ,  G01N30/88 ,  G01N30/90 ,  G01N33/44 ,  G01N35/08

Abstract: Rapid characterization and screening of polymer samples to determine average molecular weight, molecular weight distribution and other properties is disclosed. Rapid flow characterization systems and methods, including liquid chromatography and flow-injection analysis systems and methods are preferably employed. High throughput, automated sampling systems and methods, high-temperature characterization systems and methods, and rapid, indirect calibration compositions and methods are also disclosed. The described methods, systems, and devices have primary applications in combinatorial polymer research and in industrial process control.

公开(公告)号：CA2290394A1

公开(公告)日：1999-10-14

申请号：CA2290394

申请日：1999-04-02

Applicant: SYMYX TECHNOLOGIES INC

Inventor： PETRO MIROSLAV ,  CARLSON ERIC ,  SAFIR ADAM ,  KUEBLER SIGRID C ,  NIELSEN RALPH B ,  DALES G CAMERON ,  LEE THOMAS S ,  BENNETT JAMES ,  FRECHET JEAN M J

IPC: G01N37/00 ,  B01D15/08 ,  B01D15/26 ,  B01D15/32 ,  B01D15/34 ,  B01J19/00 ,  B01J19/26 ,  C40B40/14 ,  C40B40/18 ,  G01N1/00 ,  G01N15/02 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/54 ,  G01N30/60 ,  G01N30/88 ,  G01N30/90 ,  G01N33/44 ,  G01N35/08 ,  G01N1/14 ,  G01N21/53 ,  G01N30/74

Abstract: Rapid characterization and screening of polymer samples to determine average molecular weight, molecular weight distribution and other properties is disclosed. Rapid flow characterization systems and methods, including liquid chromatography and flow-injection analysis systems and methods are preferably employed. High throughput, automated sampling systems and methods, hightemperature characterization systems and methods, and rapid, indirect calibration compositions and methods are also disclosed. The described methods, systems, and devices have primary applications in combinatorial polymer research and in industrial process control.

公开(公告)号：AU3742599A

公开(公告)日：1999-10-25

申请号：AU3742599

申请日：1999-04-03

Applicant: SYMYX TECHNOLOGIES INC

Inventor： CARLSON ERIC ,  SAFIR ADAM ,  PETRO MIROSLAV ,  NIELSEN RALPH B ,  LEE THOMAS S ,  FRECHET JEAN M J ,  DALES G CAMERON ,  KUEBLER SIGRID C ,  BENNETT JAMES

IPC: G01N37/00 ,  B01D15/08 ,  B01D15/26 ,  B01D15/32 ,  B01D15/34 ,  B01J19/00 ,  B01J19/26 ,  C40B40/14 ,  C40B40/18 ,  G01N1/00 ,  G01N15/02 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/54 ,  G01N30/60 ,  G01N30/88 ,  G01N30/90 ,  G01N33/44 ,  G01N35/08

Abstract: A method and system for researching and developing and/or optimizing new catalysts and products in a combinatorial manner is disclosed. The method begins with starting components or a ligand library and provides methods of creating catalyst or product libraries, which are then tested in a reaction of interest. The system uses methods of robotic handling for moving libraries from station to station. The method and apparatus are especially useful for synthesizing, screening, and characterizing combinatorial catalyst libraries, but also offer significant advantages over conventional experimental methods as well.

公开(公告)号：CA2527935A1

公开(公告)日：1999-10-14

申请号：CA2527935

申请日：1999-04-02

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LEE THOMAS S ,  FRECHET JEAN M J ,  DALES G CAMERON ,  KUEBLER SIGRID C ,  SAFIR ADAM ,  CARLSON ERIC ,  PETRO MIROSLAV ,  BENNETT JAMES ,  NIELSEN RALPH B

IPC: G01N30/54 ,  G01N30/24 ,  G01N30/30 ,  G01N30/36 ,  G01N30/74 ,  G01N35/10

Abstract: A method for characterizing a polymer sample that includes the steps of withdrawing a polymer sample from a sample container into an injection probe of an auto- sampler where the probe is heated to maintain the withdrawn sample at a temperature of not less than about 75 degrees Celsius while resident in the probe. The heated injection probe resides in a first environment maintained at about ambient temperature while withdrawing the polymer sample. The method further includes loading at least a portion of the withdrawn sample into an injection port or a loading port of a liquid chromatography system where the injection port or loading port is adaptable for fluid communication with a chromatographic column. The chromatographic column resides in a heated second environment maintained at a temperature of not less than about 75 degrees Celsius. The loaded sample is injected into a mobile phase of the liquid chromatography system. The sample is maintained at a temperature but not les s than about 75 degrees Celsius during a period of time including from when the sample is withdrawn from the sample container to when the sample is within the heated second environment. The injected sample is chromatographically separated and a property of the sample or a composition thereof is detected.

公开(公告)号：CA2527935C

公开(公告)日：2008-02-12

申请号：CA2527935

申请日：1999-04-02

Applicant: SYMYX TECHNOLOGIES INC

Inventor： NIELSEN RALPH B ,  BENNETT JAMES ,  KUEBLER SIGRID C ,  PETRO MIROSLAV ,  SAFIR ADAM ,  CARLSON ERIC ,  FRECHET JEAN M J ,  DALES G CAMERON ,  LEE THOMAS S

IPC: G01N35/10

Abstract: A method for characterizing a polymer sample that includes the steps of withdrawing a polymer sample from a sample container into an injection probe of an auto- sampler where the probe is heated to maintain the withdrawn sample at a temperature of not less than about 75 degrees Celsius while resident in the probe. The heated injection probe resides in a first environment maintained at about ambient temperature while withdrawing the polymer sample. The method further includes loading at least a portion of the withdrawn sample into an injection port or a loading port of a liquid chromatography system where the injection port or loading port is adaptable for fluid communication with a chromatographic column. The chromatographic column resides in a heated second environment maintained at a temperature of not less than about 75 degrees Celsius. The loaded sample is injected into a mobile phase of the liquid chromatography system. The sample is maintained at a temperature but not les s than about 75 degrees Celsius during a period of time including from when the sample is withdrawn from the sample container to when the sample is within the heated second environment. The injected sample is chromatographically separated and a property of the sample or a composition thereof is detected.

公开(公告)号：AU1978102A

公开(公告)日：2002-04-22

申请号：AU1978102

申请日：2001-10-10

Applicant: SYMYX TECHNOLOGIES INC

Inventor： KUEBLER SIGRID C ,  BENNETT JAMES

IPC: B01D15/08 ,  B01D15/26 ,  B01D15/32 ,  B01D15/34 ,  B01J19/00 ,  B01J19/26 ,  C40B40/14 ,  C40B60/14 ,  G01N1/00 ,  G01N15/02 ,  G01N21/25 ,  G01N21/51 ,  G01N21/53 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/54 ,  G01N30/60 ,  G01N30/62 ,  G01N30/88 ,  G01N33/44 ,  G01N35/08 ,  G01N21/49

公开(公告)号：WO03039254A8

公开(公告)日：2004-05-21

申请号：PCT/EP0212401

申请日：2002-11-06

Applicant: BASF AG ,  SYMYX TECHNOLOGIES INC ,  KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

Inventor： KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

IPC: A01N43/38 ,  A01N25/04 ,  A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  C08F220/60

CPC classification number: A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  A01N25/12 ,  A01N25/04 ,  A01N2300/00 ,  A01N25/14

Abstract: The invention relates to a solid crop protection formulation comprising a) cinidon-ethyl as a crop protection agent; b) at least one random radical copolymer comprising as polymerized units at least one hydrophilic and at least one hydrophobic monomer; and c) optionally further additives, wherein at least 50 % of the dispersed cinidon-ethyl particles in said solid crop protection formulation are in an X-ray amorphous state and an aqueous dispersion formulation thereof. Additionally, the invention relates to processes for preparing said formulations and the use of said formulations in agriculture. Further, the invention relates to a random radical copolymer essentially consisting of as polymerized units a) 5 to 95 % by weight of styrene as component A; b) 5 to 95 % by weight of DMAPMAM (dimethylaminopropyl methacrylic amide) as component B; c) 0 to 98 % by weight of methyl acrylate and/or vinyl acetate as component C.

Abstract translation: 本发明涉及一种固体作物保护制剂，其包含a）作为作物保护剂的cinidon-ethyl; b）至少一种含有至少一种亲水和至少一种疏水单体作为聚合单元的无规自由基共聚物; 和c）任选的其它添加剂，其中所述固体作物保护制剂中至少50％的分散的cinidon-ethyl颗粒是X射线非晶态，以及其水分散体制剂。 此外，本发明涉及制备所述制剂的方法和所述制剂在农业中的用途。 此外，本发明涉及一种基本上由作为聚合单元a）5至95重量％的作为组分A的苯乙烯组成的无规自由基共聚物; b）5至95重量％的作为组分B的DMAPMAM（二甲基氨基丙基甲基丙烯酰胺）; c）0至98重量％的丙烯酸甲酯和/或作为组分C的乙酸乙烯酯。

公开(公告)号：WO0231477A9

公开(公告)日：2003-02-20

申请号：PCT/US0131710

申请日：2001-10-10

Applicant: SYMYX TECHNOLOGIES INC ,  KUEBLER SIGRID C ,  BENNETT JAMES

Inventor： KUEBLER SIGRID C ,  BENNETT JAMES

IPC: B01D15/08 ,  B01D15/26 ,  B01D15/32 ,  B01D15/34 ,  B01J19/00 ,  B01J19/26 ,  C40B40/14 ,  C40B60/14 ,  G01N1/00 ,  G01N15/02 ,  G01N21/25 ,  G01N21/51 ,  G01N21/53 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/54 ,  G01N30/60 ,  G01N30/62 ,  G01N30/88 ,  G01N33/44 ,  G01N35/08 ,  G01N21/49

CPC classification number: B01D15/08 ,  B01D15/26 ,  B01D15/265 ,  B01D15/325 ,  B01D15/34 ,  B01J19/0046 ,  B01J19/26 ,  B01J2219/00274 ,  B01J2219/00315 ,  B01J2219/00585 ,  B01J2219/00587 ,  B01J2219/00707 ,  B01J2219/00722 ,  C40B40/14 ,  C40B60/14 ,  G01N15/0205 ,  G01N21/253 ,  G01N21/51 ,  G01N21/532 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/461 ,  G01N30/466 ,  G01N30/54 ,  G01N30/60 ,  G01N30/6052 ,  G01N30/88 ,  G01N33/44 ,  G01N33/442 ,  G01N35/085 ,  G01N35/1097 ,  G01N2015/0288 ,  G01N2015/0294 ,  G01N2030/324 ,  G01N2030/625

Abstract: Methods, systems and devices are described for rapid characterization and screening of liquid samples to determine properties (e.g., particle size, particle size distribution, molar mass and/or molar mass distribution) thereof with static light scattering and/or dynamic light scattering. The liquid samples can be solutions, emulsions, suspensions or dispersions. One method, includes providing a vessel containing a liquid sample having an exposed surface that defines a gas-liquid sample interface, and analyzing the sample by light scattering methods that include transmitting light through the gas-liquid sample interface into the sample, and detecting light scattered from the sample or from a component thereof. Additional methods are directed to characterizing a plurality of liquid samples or components thereof. The methods, systems, and devices have applications in high-throughput screening, and particularly, in combinatorial materials research and in industrial process control.

Abstract translation: 描述了用于快速表征和筛选液体样品以确定静态光散射和/或动态光散射的性质（例如，粒度，粒度分布，摩尔质量和/或摩尔质量分布）的方法，系统和装置。 液体样品可以是溶液，乳液，悬浮液或分散体。 一种方法包括提供容器，该容器含有具有限定气 - 液样品界面的暴露表面的液体样品，并且通过光散射方法分析样品，所述光散射方法包括将透过气 - 液样品界面的光透射到样品中，以及检测光 从样品或其组分散射。 额外的方法涉及表征多个液体样品或其组分。 方法，系统和设备具有高通量筛选的应用，特别是在组合材料研究和工业过程控制中的应用。

公开(公告)号：WO9951980A3

公开(公告)日：2001-03-22

申请号：PCT/US9907304

申请日：1999-04-02

Applicant: SYMYX TECHNOLOGIES INC

Inventor： CARLSON ERIC ,  SAFIR ADAM ,  PETRO MIROSLAV ,  NIELSEN RALPH B ,  LEE THOMAS S ,  FRECHET JEAN M J ,  DALES G CAMERON ,  KUEBLER SIGRID C ,  BENNETT JAMES

IPC: G01N37/00 ,  B01D15/08 ,  B01D15/26 ,  B01D15/32 ,  B01D15/34 ,  B01J19/00 ,  B01J19/26 ,  C40B40/14 ,  C40B40/18 ,  G01N1/00 ,  G01N15/02 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/32 ,  G01N30/46 ,  G01N30/54 ,  G01N30/60 ,  G01N30/88 ,  G01N30/90 ,  G01N33/44 ,  G01N35/08

CPC classification number: G01N35/1097 ,  B01D15/08 ,  B01D15/12 ,  B01D15/14 ,  B01D15/1871 ,  B01D15/26 ,  B01D15/265 ,  B01D15/325 ,  B01D15/34 ,  B01J19/0046 ,  B01J19/26 ,  B01J2219/00274 ,  B01J2219/00283 ,  B01J2219/00308 ,  B01J2219/0031 ,  B01J2219/00313 ,  B01J2219/00335 ,  B01J2219/00337 ,  B01J2219/00344 ,  B01J2219/00351 ,  B01J2219/00452 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/00587 ,  B01J2219/0059 ,  B01J2219/00596 ,  B01J2219/00689 ,  B01J2219/00691 ,  B01J2219/00704 ,  B01J2219/00707 ,  B01J2219/00722 ,  B01J2219/00738 ,  B01J2219/00745 ,  C40B40/14 ,  C40B40/18 ,  G01N15/0205 ,  G01N30/02 ,  G01N30/16 ,  G01N30/24 ,  G01N30/30 ,  G01N30/461 ,  G01N30/466 ,  G01N30/54 ,  G01N30/60 ,  G01N30/6052 ,  G01N30/88 ,  G01N30/90 ,  G01N33/44 ,  G01N35/085 ,  G01N2015/0288 ,  G01N2015/0294 ,  G01N2030/324 ,  G01N2030/885 ,  G01N2030/8886 ,  G01N2035/1058 ,  Y10T436/11 ,  Y10T436/25

Abstract: Rapid characterization and screening of polymer samples to determine average molecular weight, molecular weight distribution and other properties is disclosed. Rapid flow characterization systems and methods, including liquid chromatography and flow-injection analysis systems and methods are preferably employed. High throughput, automated sampling systems and methods, high-temperature characterization systems and methods, and rapid, indirect calibration compositions and methods are also disclosed. The described methods, systems, and devices have primary applications in combinatorial polymer research and in industrial process control.

Abstract translation: 公开了聚合物样品的快速表征和筛选以确定平均分子量，分子量分布和其它性质。 优选采用快速流动表征系统和方法，包括液相色谱和流动注射分析系统和方法。 还公开了高通量，自动采样系统和方法，高温表征系统和方法，以及快速，间接校准组合物和方法。 所描述的方法，系统和装置在组合聚合物研究和工业过程控制中具有主要应用。