公开(公告)号：AU2003241293A8

公开(公告)日：2003-10-27

申请号：AU2003241293

申请日：2003-04-11

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LAPOINTE ANNE M ,  BRUMMER OLIVER ,  LONGMIRE JAMES ,  GOH CHRISTOPHER ,  LECLERC MARGARETE K ,  DIAMOND GARY M ,  SHOEMAKER JAMES A W

IPC: C07D249/06 ,  C07F7/00 ,  C08F4/06 ,  C08F4/642 ,  C08F4/659 ,  C08F210/02 ,  C07D249/20

Abstract: Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.

公开(公告)号：AU2003241293A1

公开(公告)日：2003-10-27

申请号：AU2003241293

申请日：2003-04-11

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BRUMMER OLIVER ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  LONGMIRE JAMES ,  SHOEMAKER JAMES A W

IPC: C07D249/06 ,  C07F7/00 ,  C08F4/06 ,  C08F4/642 ,  C08F4/659 ,  C08F210/02 ,  C08F210/00

Abstract: Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.

公开(公告)号：AU6701601A

公开(公告)日：2002-01-02

申请号：AU6701601

申请日：2001-06-18

Applicant: SYMYX TECHNOLOGIES INC

Inventor： DIAMOND GARY M ,  GOH CHRISTOPHER ,  LECLERC MARGARETE K ,  MURPHY VINCE ,  TURNER HOWARD W

IPC: C07B61/00 ,  C08F4/60 ,  C08F4/659 ,  C08F110/14 ,  C08F210/16

Abstract: A method is disclosed for screening potential catalysts for polymerization performance. The method includes the steps of reacting a potential catalyst with at least a first monomer under polymerization conditions, determining the polymerization performance of the catalyst with the at least first monomer, and using the determination as a predictor for the polymerization performance of the catalyst for at least a second monomer, wherein the first and second monomers are different from each other and the first monomer is an olefin other than ethylene. The method provides a useful, concrete and tangible result that has particular value for identifying appropriate catalysts for olefin polymerization and copolymerization.

公开(公告)号：CA2562090C

公开(公告)日：2014-12-02

申请号：CA2562090

申请日：2005-04-28

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  BRUEMMER OLIVER ,  DIAMOND GARY M ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  MICKLATCHER CYNTHIA ,  SUN PU ,  BEI XIAOHONG

IPC: C07F7/00 ,  C07F5/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands and method of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including higher comonomer incorporation into ethylene ethylene/olefin copolymers, where such olefins are for example, 1-ocetene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

公开(公告)号：CA2483192A1

公开(公告)日：2003-11-06

申请号：CA2483192

申请日：2003-04-23

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY ,  BRUEMMER OLIVER ,  GOH CHRISTOPHER ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  SHOEMAKER JAMES A

IPC: C07D213/32 ,  B01J31/00 ,  C07C43/23 ,  C07C217/80 ,  C07C323/12 ,  C07C323/18 ,  C07D209/86 ,  C07D213/70 ,  C07F5/00 ,  C07F7/00 ,  C07F9/00 ,  C07F9/50 ,  C08F4/44 ,  C08F4/60 ,  C08F4/602 ,  C08F4/64 ,  C08F4/642 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C07F11/00

Abstract: New ligands, compositions, metal-ligand complexes and arrays with bridged bi s- aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olef in copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylen e.

公开(公告)号：AU2003225156A1

公开(公告)日：2003-11-10

申请号：AU2003225156

申请日：2003-04-23

Applicant: SYMYX TECHNOLOGIES INC

Inventor： GOH CHRISTOPHER ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  SHOEMAKER JAMES A ,  BOUSSIE THOMAS R ,  BRUMMER OLIVER ,  DIAMOND GARY

IPC: C07D213/32 ,  B01J31/00 ,  C07C43/23 ,  C07C217/80 ,  C07C323/12 ,  C07C323/18 ,  C07D209/86 ,  C07D213/70 ,  C07F5/00 ,  C07F7/00 ,  C07F9/00 ,  C07F9/50 ,  C08F4/44 ,  C08F4/60 ,  C08F4/602 ,  C08F4/64 ,  C08F4/642 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C07F11/00

Abstract: New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

公开(公告)号：AU4151702A

公开(公告)日：2002-06-18

申请号：AU4151702

申请日：2001-11-06

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  HALL KEITH A ,  POINTE ANNE M LA ,  LECLERC MARGARETE K ,  LUND CHERYL ,  MURPHY VINCE

IPC: C07B61/00 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F7/00 ,  C07F9/58 ,  C08F4/64 ,  C08F4/642 ,  C08F4/643 ,  C08F4/646 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C08F10/02 ,  C08F210/10

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

公开(公告)号：CA2379490A1

公开(公告)日：2001-12-27

申请号：CA2379490

申请日：2001-06-18

Applicant: SYMYX TECHNOLOGIES INC

Inventor： DIAMOND GARY M ,  MURPHY VINCE ,  LECLERC MARGARETE K ,  GOH CHRISTOPHER ,  TURNER HOWARD W

IPC: C07B61/00 ,  C08F4/60 ,  C08F4/659 ,  C08F110/14 ,  C08F210/16 ,  G01N37/00 ,  C08F4/00 ,  C08F10/00 ,  G01N30/02 ,  G01N33/26

Abstract: A method is disclosed for screening potential catalysts for polymerization performance. The method includes the steps of reacting a potential catalyst with at least a first monomer under polymerization conditions, determining t he polymerization performance of the catalyst with the at least first monomer, and using the determination as a predictor for the polymerization performanc e of the catalyst for at least a second monomer, wherein the first and second monomers are different from each other and the first monomer is an olefin other than ethylene. The method provides a useful, concrete and tangible result that has particular value for identifying appropriate catalysts for olefin polymerization and copolymerization.

公开(公告)号：AU4987101A

公开(公告)日：2001-10-15

申请号：AU4987101

申请日：2001-04-04

Applicant: SYMYX TECHNOLOGIES INC

Inventor： GOH CHRISTOPHER ,  DIAMOND GARY M ,  MURPHY VINCE ,  LECLERC MARGARETE K ,  HALL KEITH ,  LAPOINTE ANNE M ,  BOUSSIE THOMAS R ,  LUND CHERYL ,  UNO TETSUO

IPC: C07B61/00 ,  C07C217/92 ,  C07D213/38 ,  C07D263/10 ,  C07D307/14 ,  C07D307/52 ,  C07D317/28 ,  C07D333/20 ,  C07F7/00 ,  C07F7/08 ,  C07F7/28 ,  C08F4/00 ,  C08F4/06 ,  C08F4/60 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: The inventions disclosed herein are new complexes and catalysts comprising metal-ligand complexes or compositions of metal precursors and ligands (and optionally activators) that catalyze polymerization and copolymerization reactions, particularly with monomers that are olefins, diolefins or acetylenically unsaturated. These compositions can also polymerize monomers that have polar functionalities in homopolymerizations or copolymerizations. Also, diolefins in combination with ethylene or alpha-olefins or 1,1-disubstituted olefins may be co-polymerized. The new catalyst compositions can be prepared by combining a metal precursor with a suitable ligand and, optionally, an activator or combination of activators. The main feature of this invention is the use of new metal ligand complexes to provide the active polymerization catalysts.

公开(公告)号：CA2562090A1

公开(公告)日：2005-11-17

申请号：CA2562090

申请日：2005-04-28

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LAPOINTE ANNE M ,  MICKLATCHER CYNTHIA ,  LECLERC MARGARETE K ,  BRUEMMER OLIVER ,  BOUSSIE THOMAS R ,  SUN PU ,  DIAMOND GARY M ,  BEI XIAOHONG

IPC: C07F7/00 ,  C07F5/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands and method of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalyts have high performance characteristics, including higher comonomer incorporation into ethylene/olef in copolymers, where such olefins are for exmaple, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylen e.