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1.发明专利
公开(公告)号：AU2566202A
公开(公告)日：2002-05-21
申请号：AU2566202
申请日：2001-11-06
Applicant: SYMYX TECHNOLOGIES INC
Inventor： BOUSSIE THOMAS R , DIAMOND GARY M , GOH CHRISTOPHER , HALL KEITH A , LAPOINTE ANNE M , LECLERC MARGAETE K , LUND CHERYL , MURPHY VINCE
IPC: C07B61/00 , C07D213/38 , C07D213/61 , C07D213/68 , C07D213/74 , C07F7/00 , C07F9/58 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/646 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C07D213/16
Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
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公开(公告)号：AU4151702A
公开(公告)日：2002-06-18
申请号：AU4151702
申请日：2001-11-06
Applicant: SYMYX TECHNOLOGIES INC
Inventor： BOUSSIE THOMAS R , DIAMOND GARY M , GOH CHRISTOPHER , HALL KEITH A , POINTE ANNE M LA , LECLERC MARGARETE K , LUND CHERYL , MURPHY VINCE
IPC: C07B61/00 , C07D213/38 , C07D213/61 , C07D213/68 , C07D213/74 , C07F7/00 , C07F9/58 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/646 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F10/02 , C08F210/10
Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
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公开(公告)号：AU4987101A
公开(公告)日：2001-10-15
申请号：AU4987101
申请日：2001-04-04
Applicant: SYMYX TECHNOLOGIES INC
Inventor： GOH CHRISTOPHER , DIAMOND GARY M , MURPHY VINCE , LECLERC MARGARETE K , HALL KEITH , LAPOINTE ANNE M , BOUSSIE THOMAS R , LUND CHERYL , UNO TETSUO
IPC: C07B61/00 , C07C217/92 , C07D213/38 , C07D263/10 , C07D307/14 , C07D307/52 , C07D317/28 , C07D333/20 , C07F7/00 , C07F7/08 , C07F7/28 , C08F4/00 , C08F4/06 , C08F4/60 , C08F4/645 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/16
Abstract: The inventions disclosed herein are new complexes and catalysts comprising metal-ligand complexes or compositions of metal precursors and ligands (and optionally activators) that catalyze polymerization and copolymerization reactions, particularly with monomers that are olefins, diolefins or acetylenically unsaturated. These compositions can also polymerize monomers that have polar functionalities in homopolymerizations or copolymerizations. Also, diolefins in combination with ethylene or alpha-olefins or 1,1-disubstituted olefins may be co-polymerized. The new catalyst compositions can be prepared by combining a metal precursor with a suitable ligand and, optionally, an activator or combination of activators. The main feature of this invention is the use of new metal ligand complexes to provide the active polymerization catalysts.
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4.发明专利
公开(公告)号：AU6040699A
公开(公告)日：2001-04-17
申请号：AU6040699
申请日：1999-09-10
Applicant: SYMYX TECHNOLOGIES INC
Inventor： GURAM ANIL S , LUND CHERYL , TURNER HOWARD W , UNO TETSUO
IPC: C07C211/55 , C07C223/06 , C07C251/24 , C40B60/14 , C07D317/28
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公开(公告)号：AU4186500A
公开(公告)日：2000-10-23
申请号：AU4186500
申请日：2000-03-31
Applicant: SYMYX TECHNOLOGIES INC
Inventor： LUND CHERYL , HALL KEITH , BOUSSIE THOMAS , MURPHY VINCE , HILLHOUSE GREG
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Patent Agency Ranking
公开(公告)号：AU2900499A
公开(公告)日：1999-09-27
申请号：AU2900499
申请日：1999-03-08
Applicant: SYMYX TECHNOLOGIES INC
Inventor： LAPOINTE ANNE MARIE , GURAM ANIL , POWERS TIMOTHY , JANDILEIT BERND , BOUSSIE THOMAS , LUND CHERYL
IPC: B01J31/24 , C07B61/00 , C07C209/10 , C07C253/30 , C07D295/023 , C07F7/00 , C07F9/50 , C07F9/58 , C07F9/59 , C07F9/60 , C07F9/6509 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C07F17/02 , C08F4/70
Abstract: Novel aminomethylphosphine ligands have particular substituents on the central carbon atom. Such ligands form coordination complexes that may be catalysts for the polymerization of monomers or other catalytic induced reactions.
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7.发明申请ETHER-AMINE BASED POLYMERIZATION CATALYSTS, COMPOSITIONS AND PROCESSES USING SAME 审中-公开基于醚的聚合催化剂，组合物和使用方法
公开(公告)号：WO0174910A3
公开(公告)日：2002-02-14
申请号：PCT/US0111015
申请日：2001-04-04
Applicant: SYMYX TECHNOLOGIES INC
Inventor： GOH CHRISTOPHER , DIAMOND GARY M , MURPHY VINCE , LECLERC MARGARETE K , HALL KEITH , LAPOINTE ANNE M , BOUSSIE THOMAS R , LUND CHERYL , UNO TETSUO
IPC: C07B61/00 , C07C217/92 , C07D213/38 , C07D263/10 , C07D307/14 , C07D307/52 , C07D317/28 , C07D333/20 , C07F7/00 , C07F7/08 , C07F7/28 , C08F4/00 , C08F4/06 , C08F4/60 , C08F4/645 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/16
CPC classification number: C07D263/10 , C07C217/92 , C07C2603/24 , C07D213/38 , C07D307/14 , C07D307/52 , C07D317/28 , C07D333/20 , C07F7/00 , C07F7/006 , C07F7/082 , C07F7/28 , C08F4/65908 , C08F10/00 , C08F110/06 , C08F210/16 , C40B40/00 , C08F4/64055 , C08F4/65912 , C08F4/659 , C08F2500/03 , C08F210/14 , C08F4/52
Abstract: The inventions disclosed herein are new complexes and catalysts comprising metal-ligand complexes or compositions of metal precursors and ligands (and optionally activators) that catalyze polymerization and copolymerization reactions, particularly with monomers that are olefins, diolefins or acetylenically unsaturated monomers. These compositions can also polymerize monomers that have polar functionalities in homopolymerizations or copolymerizations. Also, diolefins in combination with ethylene or alpha -olefins or 1,1-disubstituted olefins may be co-polymerized. The new catalyst compositions can be prepared by combining a metal precursor with a suitable ligand and, optionally, an activator or combination of activators. The main feature of this invention is the use of new metal ligand complexes to provide the active polymerization catalysts.
Abstract translation: 本文公开的本发明是包含催化聚合和共聚反应的金属 - 配体络合物或金属前体和配体（和任选的活化剂）的新配合物和催化剂，特别是与烯烃，二烯烃或炔属不饱和单体的单体。 这些组合物还可以聚合在均聚或共聚中具有极性官能团的单体。 而且，二烯烃与乙烯或α-烯烃或1,1-二取代烯烃的组合可以共聚。 可以通过将金属前体与合适的配体和任选的活化剂或活化剂的组合组合来制备新的催化剂组合物。 本发明的主要特征是使用新的金属配体络合物来提供活性聚合催化剂。
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8.发明申请SUBSTITUTED PYRIDYL AMINE LIGANDS, COMPLEXES AND CATALYSTS THEREFROM; PROCESSES FOR PRODUCING POLYOLEFINS THEREWITH 审中-公开取代的吡啶胺配体，其复合物和催化剂; 生产聚烯烃的方法
公开(公告)号：WO0238628A3
公开(公告)日：2003-05-22
申请号：PCT/US0143420
申请日：2001-11-06
Applicant: SYMYX TECHNOLOGIES INC
Inventor： BOUSSIE THOMAS R , DIAMOND GARY M , GOH CHRISTOPHER , HALL KEITH A , LAPOINTE ANNE M , LECLERC MARGAETE K , LUND CHERYL , MURPHY VINCE
IPC: C07B61/00 , C07D213/38 , C07D213/61 , C07D213/68 , C07D213/74 , C07F7/00 , C07F9/58 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/646 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C07D213/16
CPC classification number: C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/006 , C07F9/582 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
Abstract translation: 公开了新的配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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9.发明申请METHODS OF COPOLYMERIZING ETHYLENE AND ISOBUTYLENE AND POLYMERS MADE THEREBY 审中-公开乙烯与异丁烯共聚合的方法及其制备方法
公开(公告)号：WO0246249A9
公开(公告)日：2003-05-01
申请号：PCT/US0144147
申请日：2001-11-06
Applicant: SYMYX TECHNOLOGIES INC
Inventor： BOUSSIE THOMAS R , DIAMOND GARY M , GOH CHRISTOPHER , HALL KEITH A , POINTE ANNE M LA , LECLERC MARGARETE K , LUND CHERYL , MURPHY VINCE
IPC: C07B61/00 , C07D213/38 , C07D213/61 , C07D213/68 , C07D213/74 , C07F7/00 , C07F9/58 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/646 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C07D213/16
CPC classification number: C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/006 , C07F9/582 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, l-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
Abstract translation: 公开了新的配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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10.发明申请METHODS OF COPOLYMERIZING ETHYLENE AND ISOBUTYLENE AND POLYMERS MADE THEREBY 审中-公开乙烯与异丁烯共聚合的方法及其制备方法
公开(公告)号：WO0246249A2
公开(公告)日：2002-06-13
申请号：PCT/US0144147
申请日：2001-11-06
Applicant: SYMYX TECHNOLOGIES INC
Inventor： BOUSSIE THOMAS R , DIAMOND GARY M , GOH CHRISTOPHER , HALL KEITH A , POINTE ANNE M LA , LECLERC MARGARETE K , LUND CHERYL , MURPHY VINCE
IPC: C07B61/00 , C07D213/38 , C07D213/61 , C07D213/68 , C07D213/74 , C07F7/00 , C07F9/58 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/646 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F10/02
CPC classification number: C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/006 , C07F9/582 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, l-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
Abstract translation: 公开了新的配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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