公开(公告)号：CA2562090C

公开(公告)日：2014-12-02

申请号：CA2562090

申请日：2005-04-28

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  BRUEMMER OLIVER ,  DIAMOND GARY M ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  MICKLATCHER CYNTHIA ,  SUN PU ,  BEI XIAOHONG

IPC: C07F7/00 ,  C07F5/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands and method of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including higher comonomer incorporation into ethylene ethylene/olefin copolymers, where such olefins are for example, 1-ocetene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

公开(公告)号：CA2483192A1

公开(公告)日：2003-11-06

申请号：CA2483192

申请日：2003-04-23

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY ,  BRUEMMER OLIVER ,  GOH CHRISTOPHER ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  SHOEMAKER JAMES A

IPC: C07D213/32 ,  B01J31/00 ,  C07C43/23 ,  C07C217/80 ,  C07C323/12 ,  C07C323/18 ,  C07D209/86 ,  C07D213/70 ,  C07F5/00 ,  C07F7/00 ,  C07F9/00 ,  C07F9/50 ,  C08F4/44 ,  C08F4/60 ,  C08F4/602 ,  C08F4/64 ,  C08F4/642 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C07F11/00

Abstract: New ligands, compositions, metal-ligand complexes and arrays with bridged bi s- aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olef in copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylen e.

公开(公告)号：AU2003225156A1

公开(公告)日：2003-11-10

申请号：AU2003225156

申请日：2003-04-23

Applicant: SYMYX TECHNOLOGIES INC

Inventor： GOH CHRISTOPHER ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  SHOEMAKER JAMES A ,  BOUSSIE THOMAS R ,  BRUMMER OLIVER ,  DIAMOND GARY

IPC: C07D213/32 ,  B01J31/00 ,  C07C43/23 ,  C07C217/80 ,  C07C323/12 ,  C07C323/18 ,  C07D209/86 ,  C07D213/70 ,  C07F5/00 ,  C07F7/00 ,  C07F9/00 ,  C07F9/50 ,  C08F4/44 ,  C08F4/60 ,  C08F4/602 ,  C08F4/64 ,  C08F4/642 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C07F11/00

Abstract: New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.

公开(公告)号：AU4987101A

公开(公告)日：2001-10-15

申请号：AU4987101

申请日：2001-04-04

Applicant: SYMYX TECHNOLOGIES INC

Inventor： GOH CHRISTOPHER ,  DIAMOND GARY M ,  MURPHY VINCE ,  LECLERC MARGARETE K ,  HALL KEITH ,  LAPOINTE ANNE M ,  BOUSSIE THOMAS R ,  LUND CHERYL ,  UNO TETSUO

IPC: C07B61/00 ,  C07C217/92 ,  C07D213/38 ,  C07D263/10 ,  C07D307/14 ,  C07D307/52 ,  C07D317/28 ,  C07D333/20 ,  C07F7/00 ,  C07F7/08 ,  C07F7/28 ,  C08F4/00 ,  C08F4/06 ,  C08F4/60 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: The inventions disclosed herein are new complexes and catalysts comprising metal-ligand complexes or compositions of metal precursors and ligands (and optionally activators) that catalyze polymerization and copolymerization reactions, particularly with monomers that are olefins, diolefins or acetylenically unsaturated. These compositions can also polymerize monomers that have polar functionalities in homopolymerizations or copolymerizations. Also, diolefins in combination with ethylene or alpha-olefins or 1,1-disubstituted olefins may be co-polymerized. The new catalyst compositions can be prepared by combining a metal precursor with a suitable ligand and, optionally, an activator or combination of activators. The main feature of this invention is the use of new metal ligand complexes to provide the active polymerization catalysts.

公开(公告)号：AU2003241293A8

公开(公告)日：2003-10-27

申请号：AU2003241293

申请日：2003-04-11

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LAPOINTE ANNE M ,  BRUMMER OLIVER ,  LONGMIRE JAMES ,  GOH CHRISTOPHER ,  LECLERC MARGARETE K ,  DIAMOND GARY M ,  SHOEMAKER JAMES A W

IPC: C07D249/06 ,  C07F7/00 ,  C08F4/06 ,  C08F4/642 ,  C08F4/659 ,  C08F210/02 ,  C07D249/20

Abstract: Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.

公开(公告)号：AU2566202A

公开(公告)日：2002-05-21

申请号：AU2566202

申请日：2001-11-06

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  HALL KEITH A ,  LAPOINTE ANNE M ,  LECLERC MARGAETE K ,  LUND CHERYL ,  MURPHY VINCE

IPC: C07B61/00 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F7/00 ,  C07F9/58 ,  C08F4/64 ,  C08F4/642 ,  C08F4/643 ,  C08F4/646 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C07D213/16

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

公开(公告)号：AU2003241293A1

公开(公告)日：2003-10-27

申请号：AU2003241293

申请日：2003-04-11

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BRUMMER OLIVER ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  LAPOINTE ANNE M ,  LECLERC MARGARETE K ,  LONGMIRE JAMES ,  SHOEMAKER JAMES A W

IPC: C07D249/06 ,  C07F7/00 ,  C08F4/06 ,  C08F4/642 ,  C08F4/659 ,  C08F210/02 ,  C08F210/00

Abstract: Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.

公开(公告)号：CA2562090A1

公开(公告)日：2005-11-17

申请号：CA2562090

申请日：2005-04-28

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LAPOINTE ANNE M ,  MICKLATCHER CYNTHIA ,  LECLERC MARGARETE K ,  BRUEMMER OLIVER ,  BOUSSIE THOMAS R ,  SUN PU ,  DIAMOND GARY M ,  BEI XIAOHONG

IPC: C07F7/00 ,  C07F5/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands and method of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalyts have high performance characteristics, including higher comonomer incorporation into ethylene/olef in copolymers, where such olefins are for exmaple, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylen e.

公开(公告)号：AU7801698A

公开(公告)日：1998-12-30

申请号：AU7801698

申请日：1998-05-28

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS ,  HALL KEITH A ,  LAPOINTE ANNE M ,  MURPHY VINCE ,  POWERS TIMOTHY ,  BEEK JOHANNES A M VAN

IPC: B01J19/00 ,  C07B61/00 ,  C07F19/00

公开(公告)号：WO0238628A3

公开(公告)日：2003-05-22

申请号：PCT/US0143420

申请日：2001-11-06

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  HALL KEITH A ,  LAPOINTE ANNE M ,  LECLERC MARGAETE K ,  LUND CHERYL ,  MURPHY VINCE

IPC: C07B61/00 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F7/00 ,  C07F9/58 ,  C08F4/64 ,  C08F4/642 ,  C08F4/643 ,  C08F4/646 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C07D213/16

CPC classification number: C07D213/74 ,  B01J2219/00722 ,  C07B2200/11 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07F7/00 ,  C07F7/006 ,  C07F9/582 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C08F4/659 ,  C08F4/65904 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/10 ,  C08F212/08 ,  C08F210/14 ,  C08F4/64144 ,  C08F4/64113 ,  C08F4/64044

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract translation: 公开了新的配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。