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公开(公告)号：DE69729352T2
公开(公告)日：2005-06-02
申请号：DE69729352
申请日：1997-01-31
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , ODAGIRI NOBUYUKI
Abstract: The present invention provides a prepreg excellent in self adhesiveness to a honeycomb core, low in porosity when used as skin panels, excellent in surface smoothness (low in surface porosity) when used as skin panels, and good in tackiness and drapability, and also provides a honeycomb sandwich panel high in skin panel peel strength and excellent in impact resistance and hot water resistance, and a resin composition for a fiber reinforced composite material to allow the above. The present invention has the following constitution. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential wherein the modulus of storage rigidity G' measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 5 to 200 Pa in an entire range of 70 DEG C to 100 DEG C. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ , ÄBÜ and ÄCÜ are essential, wherein the minimum modulus of storage rigidity G'min and the maximum modulus of storage rigidity G'max at 70 DEG C to 100 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min, satisfy the following relation: A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein the thixotropy index is in a range of 2.5 to 40, the resin viscosity at 80 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 100 to 1000 poises, and the minimum value of resin viscosity during heating is 30 to 400 poises. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein solid rubber and fine silica particles are contained as component ÄCÜ by 1 to 10 wt%, respectively, based on the total weight of the resin composition. The fiber reinforced composite material using the prepreg of the present invention can be used widely for airplanes, automobiles and other industrial applications, particularly as structural materials of airplanes, because of its excellent mechanical properties.
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公开(公告)号：AU1610795A
公开(公告)日：1995-10-19
申请号：AU1610795
申请日：1995-03-23
Applicant: TORAY INDUSTRIES
Inventor： MURAKI TOSHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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公开(公告)号：DE69834800D1
公开(公告)日：2006-07-20
申请号：DE69834800
申请日：1998-07-10
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME , HAYASHI MASAHIKO , HIGASHI TOSHIAKI
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公开(公告)号：DE69526997D1
公开(公告)日：2002-07-18
申请号：DE69526997
申请日：1995-03-21
Applicant: TORAY INDUSTRIES
Inventor： MURAKI TISHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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公开(公告)号：DE69834800T2
公开(公告)日：2007-05-16
申请号：DE69834800
申请日：1998-07-10
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME , HAYASHI MASAHIKO , HIGASHI TOSHIAKI
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Patent Agency Ranking
公开(公告)号：DE69526997T2
公开(公告)日：2003-01-23
申请号：DE69526997
申请日：1995-03-21
Applicant: TORAY INDUSTRIES
Inventor： MURAKI TISHIO , TOKUNOU MASAZUMI , SAWAOKA RYUJI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , TAZAKI TOKUO
Abstract: A prepreg precursor comprising a carbon fiber woven fabric having applied to the fabric from 0.5 to 10 wt% of a stabilizer material for rendering stable the structural form of the fabric. Prepregs can then be produced using the woven fabric. The undesired settlement, into the prepreg of matrix resin with which the fabric is impregnated in order to produce the prepreg and which is originally present on the surface of the woven fabric, is thus prevented. Hence, compared with a prepreg prepared using conventional woven fabric, a prepreg prepared by using the woven fabric of the invention can hold its tackiness for a long time and can be used to produce a fiber reinforced composite material excellent in smoothness without being devoid of the resin on the surface.
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公开(公告)号：DE69729352D1
公开(公告)日：2004-07-08
申请号：DE69729352
申请日：1997-01-31
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , ODAGIRI NOBUYUKI
Abstract: The present invention provides a prepreg excellent in self adhesiveness to a honeycomb core, low in porosity when used as skin panels, excellent in surface smoothness (low in surface porosity) when used as skin panels, and good in tackiness and drapability, and also provides a honeycomb sandwich panel high in skin panel peel strength and excellent in impact resistance and hot water resistance, and a resin composition for a fiber reinforced composite material to allow the above. The present invention has the following constitution. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential wherein the modulus of storage rigidity G' measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 5 to 200 Pa in an entire range of 70 DEG C to 100 DEG C. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ , ÄBÜ and ÄCÜ are essential, wherein the minimum modulus of storage rigidity G'min and the maximum modulus of storage rigidity G'max at 70 DEG C to 100 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min, satisfy the following relation: A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein the thixotropy index is in a range of 2.5 to 40, the resin viscosity at 80 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 100 to 1000 poises, and the minimum value of resin viscosity during heating is 30 to 400 poises. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein solid rubber and fine silica particles are contained as component ÄCÜ by 1 to 10 wt%, respectively, based on the total weight of the resin composition. The fiber reinforced composite material using the prepreg of the present invention can be used widely for airplanes, automobiles and other industrial applications, particularly as structural materials of airplanes, because of its excellent mechanical properties.
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公开(公告)号：AT268349T
公开(公告)日：2004-06-15
申请号：AT97901813
申请日：1997-01-31
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME RESIDENCE OGURI , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , ODAGIRI NOBUYUKI
Abstract: The present invention provides a prepreg excellent in self adhesiveness to a honeycomb core, low in porosity when used as skin panels, excellent in surface smoothness (low in surface porosity) when used as skin panels, and good in tackiness and drapability, and also provides a honeycomb sandwich panel high in skin panel peel strength and excellent in impact resistance and hot water resistance, and a resin composition for a fiber reinforced composite material to allow the above. The present invention has the following constitution. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential wherein the modulus of storage rigidity G' measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 5 to 200 Pa in an entire range of 70 DEG C to 100 DEG C. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ , ÄBÜ and ÄCÜ are essential, wherein the minimum modulus of storage rigidity G'min and the maximum modulus of storage rigidity G'max at 70 DEG C to 100 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min, satisfy the following relation: A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein the thixotropy index is in a range of 2.5 to 40, the resin viscosity at 80 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 100 to 1000 poises, and the minimum value of resin viscosity during heating is 30 to 400 poises. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein solid rubber and fine silica particles are contained as component ÄCÜ by 1 to 10 wt%, respectively, based on the total weight of the resin composition. The fiber reinforced composite material using the prepreg of the present invention can be used widely for airplanes, automobiles and other industrial applications, particularly as structural materials of airplanes, because of its excellent mechanical properties.
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公开(公告)号：EP0927737A4
公开(公告)日：2002-05-15
申请号：EP98931039
申请日：1998-07-10
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME , HAYASHI MASAHIKO , HIGASHI TOSHIAKI
IPC: B29C70/02 , B29C70/08 , B32B3/12 , B32B5/02 , B32B27/04 , C08J5/24 , E04C2/36 , B05D3/02 , B32B5/16 , B32B5/28 , B32B5/30
CPC classification number: B32B3/12 , B29C70/025 , B29C70/086 , B32B5/02 , B32B5/022 , B32B9/007 , B32B9/047 , B32B15/14 , B32B27/04 , B32B27/12 , B32B29/02 , B32B2260/021 , B32B2260/046 , B32B2262/106 , C08J5/24 , E04C2/365 , Y10T428/24149 , Y10T442/3179 , Y10T442/3374 , Y10T442/3854
Abstract: A prepreg fabric at least comprising [A] a reinforcing fabric, [B] a thermosetting resin or a thermosetting resin composition and [C] fine resin particles, which is characterized by having a cover factor of 95 % or above; and a sandwich panel characterized by comprising skin panels made from the prepreg fabric and [D] a honeycomb core. The prepreg fabric is little changed in the tack as prepreg after the lapse of time, has suitable drape properties (flexibility) and exhibits excellent self-bondability to ahoneycomb core when used as the skin panel of a honeycomb sandwich panel, and the honeycomb sandwich panel is advantageous in that the skin panels made of a product of curing of the prepreg fabric have a lowered inner porosity and that the skin panels have few holes and depressions on their surfaces and are thus excellent in surface smoothness.
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10.发明公开
公开(公告)号：EP0819723A4
公开(公告)日：2000-05-24
申请号：EP97901813
申请日：1997-01-31
Applicant: TORAY INDUSTRIES
Inventor： KISHI HAJIME , HAYASHI MASAHIKO , HIGASHI TOSHIAKI , ODAGIRI NOBUYUKI
CPC classification number: C08J5/24 , C08G59/18 , C08J2363/00 , C08L63/00 , Y10T428/249924
Abstract: The present invention provides a prepreg excellent in self adhesiveness to a honeycomb core, low in porosity when used as skin panels, excellent in surface smoothness (low in surface porosity) when used as skin panels, and good in tackiness and drapability, and also provides a honeycomb sandwich panel high in skin panel peel strength and excellent in impact resistance and hot water resistance, and a resin composition for a fiber reinforced composite material to allow the above. The present invention has the following constitution. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential wherein the modulus of storage rigidity G' measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 5 to 200 Pa in an entire range of 70 DEG C to 100 DEG C. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ , ÄBÜ and ÄCÜ are essential, wherein the minimum modulus of storage rigidity G'min and the maximum modulus of storage rigidity G'max at 70 DEG C to 100 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min, satisfy the following relation: A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein the thixotropy index is in a range of 2.5 to 40, the resin viscosity at 80 DEG C measured by parallel plates having vibration frequency of 0.5 Hz during elevation of temperature from 50 DEG C at 1.5 DEG C/min is in a range of 100 to 1000 poises, and the minimum value of resin viscosity during heating is 30 to 400 poises. A resin composition for a fiber reinforced composite material comprising the components ÄAÜ, ÄBÜ and ÄCÜ are essential, wherein solid rubber and fine silica particles are contained as component ÄCÜ by 1 to 10 wt%, respectively, based on the total weight of the resin composition. The fiber reinforced composite material using the prepreg of the present invention can be used widely for airplanes, automobiles and other industrial applications, particularly as structural materials of airplanes, because of its excellent mechanical properties.
Abstract translation: 本发明提供的蜂窝芯具有优异的自粘合性的预浸料坯，低孔隙率当作为蒙皮壁板，具有优异的表面平滑度（在表面孔隙度低）当作为皮肤板中使用的，和良好的胶粘性和悬垂使用的，并因此提供 一个蜂窝夹芯板高皮肤面板剥离强度和优异的耐冲击性和耐热水性，以及用于纤维的树脂组合物，增强复合材料，以允许上述情况。 本发明具有以下构成。 增强包含组分AAU复合材料的纤维的树脂组合物，阿布和ACU是worin的存储刚度G“在1.5°由50℃温度的上升期间具有0.5赫兹的振动频率的平行板测量C中的弹性模量基本/ min是在至70℃全部范围内具有范围为5〜200 Pa至100℃增强包含组分AAU复合材料的纤维的树脂组合物，阿布和ACU是必不可少的，worin存储刚性的最小模 G“分钟并储存刚度G的最大模量”最大在70℃下通过从50℃温度的上升期间具有0.5赫兹的振动频率的平行板测量以1.5℃/分钟至100℃，满足以下关系 ：
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