Abstract:
This invention provides hydrocarbon oil compositions comprising a major amount of a hydrocarbon oil and, as active ingredients, minor amounts of a copolymer of at least one n-(C.sub.8 -C.sub.40 -alkyl) (meth)acrylate with maleic anhydride, and at least one additive selected from the group consisting of a homopolymer or copolymer derived from an unsaturated hydrocarbon monomer, an ester and a wax anti-settling additive; additive concentrates containing the active ingredients and use of the latter in improving the cold flow properties of hydrocarbon oils.
Abstract:
A fuel additive having the formula: ##STR1## where A.sub.1 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl, or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl and each R.sub.3 and R.sub.4 is independently selected in each --O--CHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10.
Abstract translation:一种具有下式的燃料添加剂:其中A1是硫醚,亚砜,砜,磺酸,磺酰胺,腈,羧酸或酯或羧酰胺; R 1和R 2独立地是氢,羟基,低级烷基或低级烷氧基; R 3和R 4独立地为氢或低级烷基,并且每个R 3和R 4独立地选自各-O-CHR 3 -CHR 4 - 单元; R5是氢,具有1至100个碳原子的烷基,苯基,具有7至100个碳原子的芳烷基或具有7至100个碳原子的烷芳基,或下式的酰基:其中R 6是具有1至30个碳原子的烷基 原子,苯基,具有7至36个碳原子的芳烷基或具有7至36个碳原子的烷芳基; n为5〜100的整数。 x为0〜10的整数。
Abstract:
Poly(oxyalkylene) hydroxyaromatic ethers having the formula: ##STR1## or a fuel-soluble salt thereof; where n is an integer from 5 to 100; x is an integer from 0 to 10; R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is an acyl group of the formula: ##STR2## wherein y is 1, 2 or 3; R.sub.6 is a divalent hydrocarbyl radical, when y is 1, a trivalent hydrocarbyl radical, when y is 2, or tetravalent hydrocarbyl radical, when y is 3, said hydrocarbyl radicals having 1 to about 20 carbon atoms; and each Z is independently selected from the group consisting of: ##STR3## where each R.sub.7 is independently alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms.The poly(oxyalkylene) hydroxyaromatic ethers of formula I are useful as fuel additives for the prevention and control of engine deposits.
Abstract translation:具有下式的聚(氧化烯)羟基芳族醚:(I)或其燃料可溶性盐; 其中n是5至100的整数; x是0至10的整数; R 1和R 2各自独立地为氢,羟基,具有1至6个碳原子的低级烷基或具有1至6个碳原子的低级烷氧基; R 3和R 4各自独立地为氢或具有1至6个碳原子的低级烷基; R5是下式的酰基:其中y是1,2或3; 当y为1时,当Y为2时,R 6为二价烃基,y为2时为三价烃基,当y为3时,所述烃基为1至约20个碳原子; 并且每个Z独立地选自:其中每个R 7独立地为具有1至30个碳原子的烷基,苯基,具有7至36个碳原子的芳烷基或具有7至36个碳原子的烷芳基组成的组。 式I的聚(氧化烯)羟基芳族醚可用作预防和控制发动机沉积物的燃料添加剂。
Abstract:
Additives which improve the low-temperature properties of distillate fuels are oligomeric/polymeric reaction products consisting of cross-linked anhydride and cross-linked epoxide (or their corresponding acid/diol equivalents), with optional termonomers.
Abstract:
A fuel additive having detergency, solubility and thermal stability is a mixture of polyalkenyl succinimides, polyalkylenes, i.e., polyisobutylene or polypropylene, an ester and a polyether; namely a polybutylene oxide, polypropylene oxide or polybutylene/polypropylene oxide copolymer, and an optional amount of a mineral oil or synthetic oil.
Abstract:
A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --AR--(OH).sub.b I wherein R* is a hydrocarbyl group selected from the group consisting of hydrocarbyl groups of from about 8 to about 30 carbon atoms and polymers of at least 30 carbon atoms, Ar is an aromatic moiety having 0 to 4 optional substituents selected from the group consisting of lower alkyl, lower alkoxyl, nitro, halo or combinations of two or more of said optional substituents, and a and b are each independently an integer of 1 up to 5 times the number of aromatic nuclei present in Ar with the proviso that the sum of a and b does not exceed the unsatisfied valences of Ar;(iii) mixtures of (i) and (ii); and(B) as a second component, the reaction product of (B)(I) a hydrocarbyl-substituted carboxylic acylating agent with (B)(II) one or more amines, one or more alcohols, or a mixture of one or more amines and/or one or more alcohols, the hydrocarbyl substituent of said agent (B)(I) being selected from the group consisting of(i') one or more mono-olefins of from about 8 to about 30 carbon atoms;(ii') mixtures of one or more mono-olefins of from about 8 to about 30 carbon atoms with one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of polymers of mono-1-olefins of from 2 to 8 carbon atoms, or the chlorinated or brominated analogs of such polymers; and(iii') one or more olefin polymers of at least 30 carbon atoms selected from the group consisting of(a) polymers of mono-olefins of from about 8 to about 30 carbon atoms;(b) interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with mono-olefins of from about 8 to about 30 carbon atoms;(c) one or more mixtures of homopolymers and/or interpolymers of mono-1-olefins of from 2 to 8 carbon atoms with homopolymers and/or interpolymers of mono-olefins of from about 8 to about 30 carbon atoms; and(d) chlorinated or brominated analogs of (a), (b), or (c).
Abstract:
Lubricating oils containing olefin polymerizable acid esters and dimers and/or trimers thereof have been found to increase fuel economy in internal combustion engines. This is done by deposition of the additive on the lubricated surface.
Abstract:
Novel dicarboxylic ester-acids resulting from the condensation of an alkenylsuccinic anhydride with an aliphatic hydroxy acid having from 2 to about 18 carbon atoms and amine salts of said ester-acid are useful as rust or corrosion inhibitors in organic compositions.
Abstract:
Compounds having the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are alkyl or cycloalkyl;R.sup.4 and R.sup.5 are alkyl or phenyl; andR is hydrogen, alkyl or a trialkylhydroxybenzyl,Are good antioxidants and thermal stabilizers. These compounds are prepared by reacting the corresponding alkylated 4-hydroxybenzyl-tert-amine with a malonate ester in the presence of an alkali metal alkoxide.
Abstract translation:具有式“IMAGE”的化合物,其中R 1,R 2和R 3是烷基或环烷基; R 4和R 5是烷基或苯基; 和R是氢,烷基或三烷基羟基苄基,是良好的抗氧化剂和热稳定剂。 这些化合物通过在碱金属醇盐的存在下使相应的烷基化的4-羟基苄基叔胺与丙二酸酯反应来制备。
Abstract:
Gasoline compositions containing manganese additives are improved by the addition of either a citrate compound having at least one alkyl group or a tetravalent tin compound having at least one alkyl group, both of which compounds must be soluble in gasoline and are added to the gasoline composition to improve the performance of the engine.