Polyesters of poly(oxyalkylene) hydroxyaromatic ethers
    93.
    发明授权
    Polyesters of poly(oxyalkylene) hydroxyaromatic ethers 失效
    聚(氧化烯)羟基芳族醚的聚酯

    公开(公告)号:US5296003A

    公开(公告)日:1994-03-22

    申请号:US28024

    申请日:1993-03-08

    Abstract: Poly(oxyalkylene) hydroxyaromatic ethers having the formula: ##STR1## or a fuel-soluble salt thereof; where n is an integer from 5 to 100; x is an integer from 0 to 10; R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is an acyl group of the formula: ##STR2## wherein y is 1, 2 or 3; R.sub.6 is a divalent hydrocarbyl radical, when y is 1, a trivalent hydrocarbyl radical, when y is 2, or tetravalent hydrocarbyl radical, when y is 3, said hydrocarbyl radicals having 1 to about 20 carbon atoms; and each Z is independently selected from the group consisting of: ##STR3## where each R.sub.7 is independently alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms.The poly(oxyalkylene) hydroxyaromatic ethers of formula I are useful as fuel additives for the prevention and control of engine deposits.

    Abstract translation: 具有下式的聚(氧化烯)羟基芳族醚:(I)或其燃料可溶性盐; 其中n是5至100的整数; x是0至10的整数; R 1和R 2各自独立地为氢,羟基,具有1至6个碳原子的低级烷基或具有1至6个碳原子的低级烷氧基; R 3和R 4各自独立地为氢或具有1至6个碳原子的低级烷基; R5是下式的酰基:其中y是1,2或3; 当y为1时,当Y为2时,R 6为二价烃基,y为2时为三价烃基,当y为3时,所述烃基为1至约20个碳原子; 并且每个Z独立地选自:其中每个R 7独立地为具有1至30个碳原子的烷基,苯基,具有7至36个碳原子的芳烷基或具有7至36个碳原子的烷芳基组成的组。 式I的聚(氧化烯)羟基芳族醚可用作预防和控制发动机沉积物的燃料添加剂。

    Trialkylsubstituted hydroxybenzyl malonates and stabilized compositions
    99.
    发明授权
    Trialkylsubstituted hydroxybenzyl malonates and stabilized compositions 失效
    三烷基取代羟基苄基丙二酸酯和稳定组合物

    公开(公告)号:US4081475A

    公开(公告)日:1978-03-28

    申请号:US596865

    申请日:1975-07-17

    Inventor: John D. Spivack

    CPC classification number: C10L1/1905 C07C37/62 C07C69/732 C08K5/11

    Abstract: Compounds having the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are alkyl or cycloalkyl;R.sup.4 and R.sup.5 are alkyl or phenyl; andR is hydrogen, alkyl or a trialkylhydroxybenzyl,Are good antioxidants and thermal stabilizers. These compounds are prepared by reacting the corresponding alkylated 4-hydroxybenzyl-tert-amine with a malonate ester in the presence of an alkali metal alkoxide.

    Abstract translation: 具有式“IMAGE”的化合物,其中R 1,R 2和R 3是烷基或环烷基; R 4和R 5是烷基或苯基; 和R是氢,烷基或三烷基羟基苄基,是良好的抗氧化剂和热稳定剂。 这些化合物通过在碱金属醇盐的存在下使相应的烷基化的4-羟基苄基叔胺与丙二酸酯反应来制备。

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