Abstract:
A COOLANT-LUBRICANT FOR THE COLD ROOLING OF ALUMINUM AND OTHER LIGHT METALS COMPRISING AN OIL-IN-WATER EMULSION WHEREIN THE NONAQUEOUS FRACTION OF SAID EMULSION CONSISTS ESSENTIALLY OF FROM ABOUT 45 TO 90% OF A LIGHT PETROLEUM OIL, FROM ABOUT 5 TO 50% BY WEIGHT OF ESTERS OF FATTY ACIDS, FROM ABOUT 5 TO 50% BY WEIGHT OF FATTY ALCOHOLS, BETWEEN ABOUT 0.05 TO 1.0% BY WEIGHT OF AN OIL-SOLUBLE EMULSIFIER AND PREFERABLY BETWEEN ABOUT 0.05 AND 1.0% BY WEIGHT OF AN OIL-INSOLUBLE EMULSIFIER. THE NONAQUEOUS FRACTION OF SAID EMULSION AMOUNTS TO BETWEEN ABOUT 3 AND 20% OF THE TOTAL WEIGHT OF THE EMULSION. PREFERABLY, THE WATER PHASE OF THE EMULSION HAS AN ALKALI METAL SALT CONCENTRATION OF BETWEEN ABOUT 10 AND 400 PARTS PER MILLION AND A PH LEVEL BETWEEN ABOUT 5.0 AND 7.4.
Abstract:
A low water-sensitive hydraulic fluid composition which contains from about 20 to about 96 percent by weight of at least one borate ester as the base fluid. Such low-water sensitive hydraulic fluids are high boiling compositions particularly useful as brake fluids.
Abstract:
WATER INSOLUBLE ORGANIC COMPOUNDS WHICH LIBERATE GASEOUS NITROGEN AT HIGH TEMPERATURES AND HAVE AT LEAST ONE N-N SINGLE OR DOUBLE BOND IN EACH MOLECULE ARE ADDED TO LUBRICANTS TO IMPROVE LUBRICITY AND DECREASE CORROSION WHILE REMAINING READILY REMOVABLE FROM THE SURFACES TO WHICH THEY HAVE BEEN APPLIED.
Abstract:
An alkaline earth metal sulfonate of high alkalinity is prepared by reacting an alkaline earth metal base, e.g. calcium hydroxide, with carbon dioxide in the presence of the metal sulfonate and an alkaline earth metal phenate, there also being present a polar solvent such as benzyl alcohol or tetrahydrofurfuryl alcohol, as well as free phenol in an amount over and above the stoichiometric quantity necessary to form metal phenate by reaction with the metal base. At the end of the reaction the solvent and free phenol are removed from the product by distillation. Preformed metal phenate can be used at the beginning of the reaction or the metal phenate can be formed in situ, starting with free phenol. Also, in place of metal sulfonate, free sulfonic acid can be used initially, with sufficient metal base to convert it to metal sulfonate. The attainment of total base numbers of 400 or more is possible by use of a second dispersant along with the metal sulfonate. This second dispersant, which is used with the sulfonate in the proportion of 0.1 to 1 part per part of sulfonate, can be a thioacid of phosphorus, or metal salt thereof, obtained by reaction of a sulfide of phosphorus on a hydrocarbon; an alkyl phenol or alkyl phenol sulfide, or metal salt thereof; or a monocarboxylic or polycarboxylic acid or anhydride, or metal salt thereof, characterized by a long chain hydrocarbon group of from about 20 to 200 carbon atoms, as for example, a polyisobutenyl succinic acid.
Abstract:
1. The production of a gel which comprises incorporating into a normally liquid hydrocarbon a small proportion effective to form a gel of at least one liquid hydrocarbon dispersible copolymer selected from the group consisting of rubbery and solid copolymers compound represented by the formula WHEREIN R is selected from the group consisting of hydrogen, alkyl and alkoxy; and R'' is selected from the group consisting of WHEREIN X is selected from the group consisting of hydrogen, alkyl and a halogen, Y is selected from the group consisting of hydrogen, alkyl and aryl; wherein R'''' is selected from the group consisting of alkyl, cycloalkyl, aryl, alkaryl, and aralkyl; the total of the carbon atoms in R and R'' when R'' does not contain R'''' is two to eight; and wherein when R'''' is present the total of the carbon atoms in R and R'' is two to thirteen and a copolymerizable compound containing a basic tertiary amine group selected from the group consisting of vinylpyridines, vinylquinolines and their nuclear-alkyl-substituted derivatives containing not more than a total of 12 carbon atoms in the nuclear-substituted groups, said copolymerizable compound containing not more than a total of 12 carbon atoms in the hydrocarbon groups attached to the nitrogen atom, said copolymer having been prepared using 0.25-8 parts per 100 by weight of total monomeric material.
Abstract:
METHOD FOR APPLYING A COATING TO A METALLIC SURFACE, THE SURFACE BEING IMMERSED IN AN ACIDIC AQUEOUS COATING COMPOSITION COMPRISING AN ORGANIC COATING-FORMING MATERIAL, AN OXIDIZING AGENT, HYDROGEN ION AND AN ANION, WHEREIN THE WEIGHT OF THE COATING FORMED ON THE SURFACE CAN BE CONTROLLED BY THE TIME THE SURFACE IS IMMERSED IN THE COMPOSITION.