公开(公告)号：US09556088B2

公开(公告)日：2017-01-31

申请号：US13691181

申请日：2012-11-30

Applicant: Iowa State University Research Foundation, Inc.

Inventor： Igor Ivan Slowing ,  Kapil Kandel

IPC: C07C7/12 ,  C07C1/22 ,  B01J31/12 ,  C07C1/207 ,  C10G25/00 ,  C10G25/06 ,  C10G45/06 ,  C10G3/00 ,  B01J31/08 ,  B01J31/10 ,  B01J31/16 ,  B01J27/185 ,  B01J29/03 ,  B82Y30/00 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02

CPC classification number: C07C7/12 ,  B01J27/1853 ,  B01J29/0308 ,  B01J29/0325 ,  B01J29/0333 ,  B01J29/0341 ,  B01J31/08 ,  B01J31/10 ,  B01J31/1616 ,  B01J35/0013 ,  B01J35/0033 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0209 ,  B01J2231/641 ,  B82Y30/00 ,  C07C1/2078 ,  C07C1/22 ,  C07C2521/08 ,  C07C2523/755 ,  C10G3/44 ,  C10G3/45 ,  C10G3/48 ,  C10G3/50 ,  C10G25/003 ,  C10G25/06 ,  C10G45/06 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02P20/52 ,  C07C9/22

Abstract: The present invention provides an adsorbent catalytic nanoparticle including a mesoporous silica nanoparticle having at least one adsorbent functional group bound thereto. The adsorbent catalytic nanoparticle also includes at least one catalytic material. In various embodiments, the present invention provides methods of using and making the adsorbent catalytic nanoparticles. In some examples, the adsorbent catalytic nanoparticles can be used to selectively remove fatty acids from feedstocks for biodiesel, and to hydrotreat the separated fatty acids.

Abstract translation: 本发明提供一种吸附剂催化纳米颗粒，其包括具有至少一个与其结合的吸附官能团的介孔二氧化硅纳米颗粒。 吸附剂催化纳米颗粒还包括至少一种催化材料。 在各种实施方案中，本发明提供了使用和制备吸附剂催化纳米颗粒的方法。 在一些实例中，吸附剂催化纳米颗粒可用于从用于生物柴油的原料中选择性除去脂肪酸，并加氢处理分离的脂肪酸。

公开(公告)号：US20160221908A1

公开(公告)日：2016-08-04

申请号：US14915564

申请日：2014-08-28

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： JIN KU CHO ,  SANG YONG KIM ,  DO HOON LEE ,  JAE WON JEONG

IPC: C07C51/00 ,  B01J31/02 ,  B01J31/08 ,  B01J21/18

CPC classification number: C07C51/00 ,  B01J21/18 ,  B01J31/0229 ,  B01J31/04 ,  B01J31/08 ,  B01J31/10 ,  B01J2231/76 ,  B01J2231/766 ,  B01J2531/002 ,  C07C51/573 ,  C07C53/126 ,  Y02E50/343

Abstract: Provided is a method for preparing levulinic acid using a solid acid catalyst in the presence of an ethylene glycol-based compound. The levulinic acid according to the present invention can be prepared by using a linear or cyclic ethylene glycol-based compound as a solvent and preparing the levulinic acid from fructose in the presence of the solid acid catalyst at a reaction temperature of 100 to 200° C., thereby reducing the dependency on petroleum in response to greenhouse gas emission regulations. Also, a high yield of levulinic acid can be obtained from fructose, and the solvent and the catalyst can be efficiently separated, collected, and reused after the reaction has completed.

Abstract translation: 本发明提供一种在乙二醇类化合物的存在下使用固体酸催化剂制备乙酰丙酸的方法。 根据本发明的乙酰丙酸可以通过使用直链或环状的基于乙二醇的化合物作为溶剂并在固体酸催化剂存在下，在100-200℃的反应温度下从果糖制备乙酰丙酸 ，从而减少对温室气体排放法规对石油的依赖。 此外，可以从果糖获得高产量的乙酰丙酸，并且可以在反应完成后有效地分离，收集和再利用溶剂和催化剂。

公开(公告)号：US09302259B2

公开(公告)日：2016-04-05

申请号：US13684136

申请日：2012-11-21

Applicant: Jiangsu Sinorgchem Technology Co., Ltd.

Inventor： Xinmin Chen ,  Jianliang Zhu

IPC: B01J31/26 ,  C07C209/38 ,  C07C209/26 ,  B01J31/06 ,  B01J23/04 ,  B01J31/02 ,  B01J31/08 ,  C07C209/36 ,  C07C209/60 ,  B01J31/00 ,  B01J37/02

CPC classification number: B01J31/26 ,  B01J23/04 ,  B01J31/00 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0271 ,  B01J31/06 ,  B01J31/08 ,  B01J37/0209 ,  C07C209/26 ,  C07C209/36 ,  C07C209/38 ,  C07C209/60 ,  C07C211/56 ,  C07C211/55

Abstract: A solid base catalyst having a carrier, an organic base, and an inorganic base. Both of the organic base and inorganic base are loaded on the carrier. The solid base catalyst is especially suitable for the synthesis of 4-Aminodiphenylamine (4-ADPA).

Abstract translation: 具有载体，有机碱和无机碱的固体碱催化剂。 有机碱和无机碱均载于载体上。 固体碱催化剂特别适用于4-氨基二苯胺（4-ADPA）的合成。

公开(公告)号：US09266804B2

公开(公告)日：2016-02-23

申请号：US14040982

申请日：2013-09-30

Applicant: CPC Corporation, Taiwan

Inventor： Wei-Bin Su ,  Karl Tze-Tang Chuang ,  Tzong-Bin Lin ,  Cheng-Tsung Hong ,  Hung-Chung Shen ,  Yung-Sheng Ho

IPC: C07C41/09 ,  B01J8/04 ,  B01D3/00 ,  B01J35/00 ,  B01J27/053 ,  B01J27/12 ,  B01J29/40 ,  B01J29/70 ,  B01J31/08

CPC classification number: C07C41/09 ,  B01D3/009 ,  B01J8/0453 ,  B01J27/053 ,  B01J27/12 ,  B01J29/40 ,  B01J29/7007 ,  B01J31/08 ,  B01J35/0006 ,  B01J2208/00265 ,  B01J2208/00274 ,  B01J2208/00283 ,  B01J2208/00539 ,  B01J2208/025 ,  B01J2219/00006 ,  Y02P20/127 ,  C07C43/043

Abstract: A dual-bed catalytic distillation tower has a catalytic column having an upper catalytic bed filled with low temperature dehydration catalysts and a lower catalytic bed filled with high temperature dehydration catalysts. When using the dual-bed catalytic distillation tower, the feeding may be fed to the tower at the top of the upper catalytic bed, between the upper and lower catalytic beds, or at the bottom of the lower catalytic bed for dehydration to obtain DME. The dual-bed catalytic distillation tower has the advantage of flexible set-up depending on various feedings such as anhydrous or crude methanol and on different grades of DME to be obtained.

Abstract translation: 双床催化蒸馏塔具有催化塔，其具有填充有低温脱水催化剂的上催化床和装有高温脱水催化剂的下催化床。 当使用双床催化蒸馏塔时，进料可以在上催化床的顶部，上下催化床的顶部或下催化床的底部进料到塔中，用于脱水以获得DME。 双床催化蒸馏塔具有取决于各种进料如无水或粗甲醇和不同等级的DME的灵活设置的优点。

公开(公告)号：US09206148B2

公开(公告)日：2015-12-08

申请号：US14383439

申请日：2012-07-26

Applicant: Jin Ku Cho ,  Jaewon Jeong ,  Sangyong Kim ,  Bora Kim ,  Baek-Jin Kim ,  Seunghan Shin ,  Dohoon Lee

Inventor： Jin Ku Cho ,  Jaewon Jeong ,  Sangyong Kim ,  Bora Kim ,  Baek-Jin Kim ,  Seunghan Shin ,  Dohoon Lee

IPC: C07D307/50 ,  B01J31/08 ,  C07D307/48

CPC classification number: C07D307/50 ,  B01J31/08 ,  C07D307/48 ,  Y02P20/582

Abstract: Provided herein is a method for producing 5-hydroxymethyl-2-furfural (HMF) from maize syrup containing fructose including a conversion step in which a reaction product containing the 5-hydroxymethyl-2-furfural is produced by mixing and heating the maize syrup, a dioxane solvent and a solid acid catalyst, thus providing an advantage that the solvent can be easily isolated and the isolated solvent can be reused because dioxane is used as the solvent, and an advantage that the catalyst can be easily isolated and the isolated catalyst can be easily reused because a nonuniform solid acid catalyst is used.

Abstract translation: 本文提供了含有果糖的玉米糖浆中的5-羟甲基-2-糠醛（HMF）的制备方法，包括转化步骤，其中通过混合和加热玉米糖浆产生含有5-羟甲基-2-糠醛的反应产物， 二恶烷溶剂和固体酸催化剂，从而提供了可以容易地分离溶剂并且由于使用二恶烷作为溶剂可以重复使用分离的溶剂的优点，以及可以容易地分离催化剂并且分离的催化剂可以 由于使用不均匀的固体酸催化剂，容易重复使用。

公开(公告)号：US20140349837A1

公开(公告)日：2014-11-27

申请号：US14148802

申请日：2014-01-07

Applicant: GUNITECH CORP.

Inventor： Hsin-Yi Kao ,  Tsai-Hsin Cheng ,  Po-Kuei Chou ,  Ssu-Tai Lin

IPC: B01J31/08

CPC classification number: B01J31/08 ,  B01J23/40 ,  B01J23/48 ,  B01J23/56 ,  B01J35/06 ,  B01J37/036 ,  B01J37/32 ,  D01D5/06 ,  D01F1/10 ,  D01F9/04 ,  D01F11/00 ,  H01M4/8605 ,  H01M4/8663 ,  H01M4/8814 ,  H01M4/8825 ,  H01M4/8875 ,  H01M4/9041 ,  H01M4/92 ,  H01M2008/1095

Abstract: A method of producing a plurality of fiber catalyst is disclosed, the method includes the steps of: mixing a plurality of fiber material and a solvent to form a solution; putting the solution into a modeling container, to form at least one specific shape fiber body; applying a shaping process to the specific shape fiber body; and cutting or milling the specific shape fiber body to form a plurality of fiber catalyst.

Abstract translation: 公开了一种制备多种纤维催化剂的方法，该方法包括以下步骤：将多种纤维材料和溶剂混合以形成溶液; 将溶液放入造型容器中，形成至少一个特定形状的纤维体; 对特定形状的纤维体进行成形加工; 切割或研磨特定形状的纤维体以形成多个纤维催化剂。

公开(公告)号：US08552223B2

公开(公告)日：2013-10-08

申请号：US13168119

申请日：2011-06-24

Applicant: James Tate ,  Jose Antonio Trejo-O'Reilly

Inventor： James Tate ,  Jose Antonio Trejo-O'Reilly

IPC: C07C45/73 ,  B01J31/08 ,  B01J37/04

CPC classification number: B01J23/44 ,  B01J23/38 ,  B01J23/72 ,  B01J31/08 ,  B01J31/10 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/16 ,  B01J2231/342 ,  B01J2231/645 ,  C07C45/73 ,  C07C49/04

Abstract: A method of making a heterogeneous catalyst, the catalyst produced therefrom, and the use of the catalyst, comprising mixing a dried ion exchange resin with a solution of a ketone and a metal, swelling the ion exchange resin, distributing the metal in the resin, and transforming without reducing agents the metal to zero valent at a temperature below 120° C.

Abstract translation: 一种制备非均相催化剂的方法，由其制备的催化剂和催化剂的用途，包括将干燥的离子交换树脂与酮和金属溶液混合，使离子交换树脂溶胀，将金属分散在树脂中， 并在低于120℃的温度下将金属转化成零价。

公开(公告)号：US20120004468A1

公开(公告)日：2012-01-05

申请号：US13168119

申请日：2011-06-24

Applicant: James Tate ,  Jose Antonio Trejo-O'Reilly

Inventor： James Tate ,  Jose Antonio Trejo-O'Reilly

IPC: B01J31/08 ,  C07C45/73 ,  B01J37/04

CPC classification number: B01J23/44 ,  B01J23/38 ,  B01J23/72 ,  B01J31/08 ,  B01J31/10 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/16 ,  B01J2231/342 ,  B01J2231/645 ,  C07C45/73 ,  C07C49/04

Abstract: A method of making a heterogeneous catalyst, the catalyst produced therefrom, and the use of the catalyst, comprising mixing a dried ion exchange resin with a solution of a ketone and a metal, swelling the ion exchange resin, distributing the metal in the resin, and transforming without reducing agents the metal to zero valent at a temperature below 120° C.

Abstract translation: 一种制备非均相催化剂的方法，由其制备的催化剂和催化剂的用途，包括将干燥的离子交换树脂与酮和金属溶液混合，使离子交换树脂溶胀，将金属分散在树脂中， 并在低于120℃的温度下将金属转化成零价。

公开(公告)号：US20110124922A1

公开(公告)日：2011-05-26

申请号：US12953894

申请日：2010-11-24

Applicant: Jose Antonio Trejo ,  Eric J. Langenmayr

Inventor： Jose Antonio Trejo ,  Eric J. Langenmayr

IPC: C07C45/00 ,  B01J31/08

CPC classification number: B01J31/10 ,  B01J21/18 ,  B01J35/0006 ,  B01J35/006 ,  B01J37/086 ,  B01J37/18 ,  B01J2231/321 ,  B01J2231/342 ,  B01J2231/4211 ,  B01J2231/4261 ,  B01J2231/641 ,  B01J2231/645 ,  B01J2231/70 ,  B01J2531/0211 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/26 ,  B01J2531/31 ,  B01J2531/62 ,  B01J2531/824 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C45/73 ,  C07C49/04

Abstract: This invention relates to the composition of metal alloy-doped heterogeneous catalysts and their method of use. In particular the present invention relates to the composition and use of cost-effective metal alloy-doped ion exchange resin catalysts which provide for comparable yield and selectivity compared to the catalysts previously used.

Abstract translation: 本发明涉及掺杂金属的非均相催化剂的组成及其使用方法。 特别地，本发明涉及具有成本效益的金属合金掺杂的离子交换树脂催化剂的组合物和用途，其提供与先前使用的催化剂相当的产率和选择性。

公开(公告)号：US20080319237A1

公开(公告)日：2008-12-25

申请号：US11792935

申请日：2006-01-24

Applicant: James Richard Stahlbush ,  Katherine H. Stahlbush ,  Harlan Robert Goltz ,  Thomas Caldwell Young ,  Edward Alan Fraini

Inventor： James Richard Stahlbush ,  Katherine H. Stahlbush ,  Harlan Robert Goltz ,  Thomas Caldwell Young ,  Edward Alan Fraini

IPC: C07C39/16 ,  B01J31/08

CPC classification number: C07C37/20 ,  B01J31/10 ,  B01J2231/32 ,  B01J2231/347 ,  C07C39/16 ,  Y02P20/52

Abstract: A method for preventing the degradation of a catalyst during storage of the catalyst and prior to using the catalyst in a chemical process comprising treating the catalyst with an antioxidant and storing the treated catalyst until further use. The stabilized treated catalyst may be used in a process for producing organic chemicals such as in a process for producing bisphenol A.

Abstract translation: 一种用于在化学方法中防止催化剂储存期间和使用催化剂之前催化剂降解的方法，包括用抗氧化剂处理催化剂并将经处理的催化剂储存直至进一步使用。 稳定处理的催化剂可以用于生产有机化学品的方法，例如在双酚A的生产方法中。