公开(公告)号：US09382490B2

公开(公告)日：2016-07-05

申请号：US14134382

申请日：2013-12-19

Applicant: Shell Oil Company

Inventor： Mark Lawrence Brewer ,  Roger Francis Cracknell ,  Tor Kit Goh

IPC: C10L10/12 ,  C10L1/183 ,  C10L1/182 ,  C10L1/10 ,  C10L1/08 ,  C10L1/18 ,  C10M145/40 ,  C10M161/00 ,  C10L1/198 ,  C10L1/223 ,  C10L1/232 ,  C10L1/23

CPC classification number: C10L1/1802 ,  C10L1/1826 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/1988 ,  C10L1/223 ,  C10L1/23 ,  C10L1/232 ,  C10L10/12 ,  C10L2230/081 ,  C10L2230/14 ,  C10L2270/023 ,  C10L2270/026 ,  C10M145/40 ,  C10M161/00 ,  C10M2207/026 ,  C10M2209/12 ,  C10N2230/02 ,  C10N2230/10 ,  C10N2250/16

Abstract: Additive composition for use in a fuel or lubricant formulation, comprising an active substance in an inclusion complex with a modified cyclodextrin of formula (I): wherein n is an integer from 6 to 20, and R1, R2 and R3 are each independently selected from hydrogen, optionally substituted alkyl, optionally substituted aryl and carbonyl, provided that R1, R2 and R3 are not all hydrogen. Also provided is a fuel or lubricant formulation comprising the additive composition, a premix for use in preparing the additive composition, and the use of a modified cyclodextrin (I) as a vehicle for an active substance in an additive composition or in a fuel or lubricant formulation.

Abstract translation: 用于燃料或润滑剂制剂的添加剂组合物，其包含与式（I）的改性环糊精的包合络合物中的活性物质：其中n为6至20的整数，并且R 1，R 2和R 3各自独立地选自 氢，任选取代的烷基，任选取代的芳基和羰基，条件是R 1，R 2和R 3不全部为氢。 还提供了包含添加剂组合物的燃料或润滑剂制剂，用于制备添加剂组合物的预混物，以及改性环糊精（I）作为添加剂组合物或燃料或润滑剂中的活性物质载体的用途 公式。

公开(公告)号：US20130000184A1

公开(公告)日：2013-01-03

申请号：US13515376

申请日：2010-12-07

Applicant: Matthias Krull ,  Werner Reimann ,  Stefan Dilsky ,  Sabine Goetzke ,  Dirk Leinweber

Inventor： Matthias Krull ,  Werner Reimann ,  Stefan Dilsky ,  Sabine Goetzke ,  Dirk Leinweber

IPC: C10L1/188 ,  C10M169/04

CPC classification number: C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1641 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1983 ,  C10L1/1985 ,  C10L1/224 ,  C10L10/14 ,  C10L10/16

Abstract: The present invention relates to cooling additives for middle distillates, containing A) at least one comb polymer carrying hydroxyl groups, which can be produced by polycondensation of a polyol that contains two primary OH groups and at least one secondary OH group with a dicarboxylic acid or the anhydride or ester thereof, which carries a C16-C40 alkyl radical or a C16-C40 alkenyl radical, characterized in that the OH number of the comb polymer is at least 40 mg KOH/g, B) at least one copolymer of ethylene and of at least one ethylenically unsaturated ester, and C) at least one organic solvent.

Abstract translation: 本发明涉及用于中间馏分的冷却添加剂，其包含A）至少一个带有羟基的梳形聚合物，其可以通过将含有两个伯OH基和至少一个仲OH基的多元醇与二羧酸缩聚制备，或 其具有C 16 -C 40烷基或C 16 -C 40烯基的酸酐或酯，其特征在于梳状聚合物的OH值为至少40mg KOH / g，B）至少一种乙烯和 的至少一种烯属不饱和酯，和C）至少一种有机溶剂。

公开(公告)号：US08293690B2

公开(公告)日：2012-10-23

申请号：US12520358

申请日：2007-06-28

Applicant: Michael Feustel ,  Matthias Krull ,  Christoph Kayser ,  Mario Loew

Inventor： Michael Feustel ,  Matthias Krull ,  Christoph Kayser ,  Mario Loew

IPC: C10M173/00 ,  C10M161/00

CPC classification number: C10L1/10 ,  C10L1/125 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1641 ,  C10L1/1824 ,  C10L1/1826 ,  C10L1/1855 ,  C10L1/1857 ,  C10L1/1885 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/19 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/198 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/2225 ,  C10L1/2335 ,  C10L10/16 ,  C10M169/044 ,  C10M173/02 ,  C10M2205/02 ,  C10M2205/022 ,  C10M2205/028 ,  C10M2207/021 ,  C10M2207/022 ,  C10M2207/08 ,  C10M2207/16 ,  C10M2207/18 ,  C10M2207/20 ,  C10M2207/281 ,  C10M2209/101 ,  C10M2209/103 ,  C10N2220/023 ,  C10N2230/04 ,  C10N2230/08 ,  C10N2250/12 ,  C10M2209/062 ,  C10M2209/084 ,  C10M2209/08

Abstract: The invention relates to dispersions comprising I) at least one polymer that is effective for mineral oils as a cold extrusion improver and is soluble in oil, II) at least one organic solvent that cannot be mixed with water, III) water, IV) at least one alkanolamine salt of a polycyclic carboxylic acid as a dispersing agent, and V) possibly at least one organic solvent that can be mixed with water.

Abstract translation: 本发明涉及分散体，其包括I）至少一种对矿物油作为冷挤出改进剂有效并且可溶于油的聚合物，II）至少一种不能与水混合的有机溶剂，III）水，IV）在 作为分散剂的多环羧酸的至少一种链烷醇胺盐，以及V）可能与水混合的至少一种有机溶剂。

公开(公告)号：US08283298B2

公开(公告)日：2012-10-09

申请号：US11494951

申请日：2006-07-28

Applicant: Matthias Krull ,  Werner Reimann

Inventor： Matthias Krull ,  Werner Reimann

IPC: C09K15/08 ,  C08K5/13 ,  C07C309/62 ,  C10L1/18 ,  C10L1/22

CPC classification number: C10L1/143 ,  C10L1/1641 ,  C10L1/1835 ,  C10L1/195 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/2383 ,  C10L1/2475 ,  C10L10/14

Abstract: Mineral oil distillates having an aromatics content of less than 21% by weight, a water content of less than 150 ppm and a conductivity of at least 50 pS/m, and comprising from 0.1 to 200 ppm of at least one alkylphenol-aldehyde resin (constituent I) which includes a structural element of the formula in which R5 is C1-C200-alkyl or C2-C200-alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or C2-C200-alkenyl and n is from 2 to 100, and from 0.1 to 200 ppm of at least one polar oil-soluble nitrogen compound (constituent II), excluding those mineral oil distillates in which between 0.001 and 10 ppm of an oil-soluble, organic sulfonic acid-ammonium salt are present.

Abstract translation: 芳族化合物含量小于21重量％，含水量小于150ppm，电导率至少为50pS / m的矿物油馏分，并且包含0.1至200ppm的至少一种烷基酚醛树脂（ 组分I），其包括其中R 5是C 1 -C 20 - 烷基或C 2 -C 20 - 烯基，O-R 6或O-C（O）-R 6的下式的结构元件，R 6是C 1 -C 20 - 烷基或C 2 -C 20 - C 200 - 烯基，n为2〜100，和0.1〜200ppm的至少一种极性油溶性氮化合物（成分II），不包括那些矿物油馏分，其中0.001〜10ppm的油溶性， 有机磺酸铵盐存在。

公开(公告)号：US08153567B2

公开(公告)日：2012-04-10

申请号：US11644228

申请日：2006-12-22

Applicant: Matthias Krull ,  Robert Janssen ,  Werner Reimann

Inventor： Matthias Krull ,  Robert Janssen ,  Werner Reimann

IPC: C10L1/18 ,  C10M133/56

CPC classification number: C10L1/143 ,  C10L1/146 ,  C10L1/1641 ,  C10L1/196 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

Abstract: The invention provides for the use of at least one oil-soluble polyoxyalkylene compound,this polyoxyalkylene compound being an oil-soluble ester, ether or ether/ester of alkoxylated polyols having at least three repeat alkoxy units derived from alkylene oxides having from 2 to 5 carbon atoms per OH group of the polyol which bears at least two aliphatic hydrocarbon radicals having from 12 to 30 carbon atoms for improving the response behavior of mineral oil cold flow improvers in middle distillates which comprise at least one ashless, nitrogen-containing detergent additive which is an oil-soluble amphiphilic compound which comprises at least one alkyl or alkenyl radical which is bonded to a polar group, the alkyl or alkenyl radical comprising from 10 to 500 carbon atoms and the polar group comprising 2 or more nitrogen atoms.

Abstract translation: 本发明提供至少一种油溶性聚氧化烯化合物的用途，该聚氧化烯化合物是具有至少三个衍生自具有2至5个碳原子的氧化烯的重复烷氧基单元的油溶性酯，醚或醚/ 含有至少两个具有12至30个碳原子的脂族烃基的多元醇OH基团的碳原子，用于改善中间馏分中矿物油冷流改进剂在至少一种无灰含氮洗涤剂添加剂中的响应行为， 是一种油溶性两亲化合物，其包含至少一个与极性基团键合的烷基或烯基，所述烷基或烯基包含10至500个碳原子，极性基团包含2个或更多个氮原子。

公开(公告)号：US08123930B2

公开(公告)日：2012-02-28

申请号：US11525881

申请日：2006-09-22

Applicant: Carsten Cohrs ,  Matthias Krull ,  Michael Feustel ,  Heidi Rausch

Inventor： Carsten Cohrs ,  Matthias Krull ,  Michael Feustel ,  Heidi Rausch

IPC: C10G71/00

CPC classification number: C10L1/1985 ,  B01D17/047 ,  C09K8/524 ,  C10L1/1981 ,  C10L10/16 ,  C10L10/18 ,  C10M2209/101 ,  C10N2230/04 ,  C10N2230/08 ,  C10N2230/24

Abstract: The invention thus provides crude oils and products which have been produced therefrom and comprise distillation residues, comprising at least one alkylphenol-aldehyde resin having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radical or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2, the use of the alkylphenol-aldehyde resin for splitting emulsions of water and crude oils or products derived therefrom, the use of the alkylphenol-aldehyde resin for improving the cold flowability of crude oils and products derived therefrom, and the use of the alkylphenol-aldehyde resin as an asphaltene dispersant in crude oils and products derived therefrom.

Abstract translation: 因此，本发明提供了由其生产并包含蒸馏残余物的原油和产品，其包含至少一种具有下式重复结构单元的烷基酚醛树脂，其中R 1是具有10至40个碳原子的支链烷基或烯基 原子并具有至少一个羧基，羧酸酯和/或酯基团，R 2是氢或R 1 R 3是氢或式 - （AO）m -H的烷氧基，A是C 2 -C 4亚烷基，m 为1〜100，R 4为氢，C 1至C 11 - 烷基或羧基，R 5为C 1 -C 20 - 烷基或 - 烯基，O-R 6或O-C（O）-R 6，R 6为C 1 -C 200 - 烷基或 - 烯基，n为1〜100，k为1或2，使用烷基酚 - 醛树脂分解水和原油或其衍生产物的乳液，使用烷基酚醛树脂 用于改善原油及其衍生物的冷流动性，以及使用烷基苯酚 - 醛树脂作为沥青 原油中的分散剂和由其衍生的产物。

公开(公告)号：US07951758B2

公开(公告)日：2011-05-31

申请号：US12140481

申请日：2008-06-17

Applicant: Corina L. Sandu ,  Lawrence N. Kremer ,  Christine Ann Blundell ,  Lee Michael Howard ,  Joseph L. Stark

Inventor： Corina L. Sandu ,  Lawrence N. Kremer ,  Christine Ann Blundell ,  Lee Michael Howard ,  Joseph L. Stark

IPC: C10M159/12 ,  C10M159/24 ,  C10L1/24

CPC classification number: C10L1/14 ,  C10L1/1883 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2493 ,  C10L1/301 ,  C10L10/04 ,  C10L10/18 ,  C10M159/20 ,  C10M2207/123 ,  C10M2207/127 ,  C10M2209/101 ,  C10M2215/04

Abstract: The hydrolytic stability of magnesium overbased products is significantly improved by the addition or inclusion of a mixture or reaction product of an alkylphenol resin with a mixture of an alkenyl succinic anhydride and the acid thereof, and an alkyl amine. These magnesium overbased products are useful additives to fuel oils to improve their corrosion-causing tendencies. In one non-limiting embodiment, the alkylphenol resin is nonylphenol resin and the succinic anhydride is a partially hydrolyzed succinic anhydride having from 14 to 26 carbon atoms, along with the acid thereof. The mixtures and reaction products also serve as asphaltene inhibitors in the fuel oils.

Abstract translation: 通过添加或包含烷基酚树脂与烯基琥珀酸酐及其酸的混合物和烷基胺的混合物或反应产物，镁高碱性产物的水解稳定性显着提高。 这些镁高碱性产品是燃料油的有用添加剂，以改善其腐蚀倾向。 在一个非限制性实施方案中，烷基酚树脂是壬基酚树脂，琥珀酸酐是具有14至26个碳原子的部分水解琥珀酸酐及其酸。 混合物和反应产物也用作燃料油中的沥青质抑制剂。

公开(公告)号：US20100154294A1

公开(公告)日：2010-06-24

申请号：US12630863

申请日：2009-12-04

Applicant: Robert D. Tack

Inventor： Robert D. Tack

IPC: C10L1/18 ,  C10L1/22

CPC classification number: C10L1/221 ,  C07C217/28 ,  C10L1/143 ,  C10L1/1658 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/2225 ,  C10L1/238 ,  C10L1/2383 ,  C10L10/14

Abstract: A fuel oil composition comprising a major amount of a fuel oil and a minor amount of a compound being the product of the reaction between (i) a primary or secondary hydrocarbyl-substituted amine or a mixture thereof and (ii) a species containing two or more epoxy groups being: a glycidyl ether (a) or (b), a glycidyl amine (c), a glycidyl ester (d) or a poly-epoxy alkane (e).

Abstract translation: 一种燃料油组合物，其包含主要量的燃料油和少量的化合物，其为（i）伯或仲烃基取代的胺或其混合物之间的反应的产物，和（ii）含有两个或 更多的环氧基是：缩水甘油醚（a）或（b），缩水甘油胺（c），缩水甘油酯（d）或聚环氧烷烃（e）。

公开(公告)号：US07713316B2

公开(公告)日：2010-05-11

申请号：US10735490

申请日：2003-12-12

Applicant: Matthias Krull ,  Markus Kupetz ,  Raimund Wildfang

Inventor： Matthias Krull ,  Markus Kupetz ,  Raimund Wildfang

IPC: C10L1/18 ,  C10L1/22

CPC classification number: C10L1/143 ,  C08F210/02 ,  C10L1/195 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/224 ,  C08F4/34 ,  C08F218/08 ,  C08F218/02 ,  C08F2500/17

Abstract: The invention relates to fuel oils comprising a larger proportion of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight, and also a smaller proportion of at least one copolymer of ethylene and vinyl esters, said copolymer containing a) bivalent structural units derived from ethylene of the formula 1 —CH2—CH2—  (1) b) from 5 to 12 mol % of bivalent structural units of the formula 2 where R1 is saturated, branched C5-C18-alkyl, and c) from 4 to 13 mol % of bivalent structural units of the formula 3 and the sum of the molar proportions of structural units of the formulae 2 and 3 being between 12 and 16 mol %, to the corresponding polymers, and also to their use for improving the cold flow behavior of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight.

Abstract translation: 本发明涉及燃料油，其包含较大比例的硫含量至多为350ppm，芳烃含量至多为22重量％的中间馏分，以及乙烯和乙烯基酯的至少一种共聚物的较小比例， 所述共聚物含有a）衍生自式1 -CH 2 -CH 2 - （1）的乙烯的二价结构单元b）5至12mol％的式2的二价结构单元，其中R 1是饱和的，支链C 5 -C 18 - 烷基 ，和c）4至13摩尔％的式3的2价结构单元和式2和3的结构单元的摩尔比例之和为12至16摩尔％，相应的聚合物，以及 它们用于改善硫含量至多为350ppm且芳族化合物含量至多为22重量％的中间馏分的冷流行为。

公开(公告)号：US07563291B2

公开(公告)日：2009-07-21

申请号：US11132413

申请日：2005-05-18

Applicant: Bettina Siggelkow ,  Dirk Leinweber ,  Werner Reimann ,  Ulrike Neuhaus ,  Renate Braun

Inventor： Bettina Siggelkow ,  Dirk Leinweber ,  Werner Reimann ,  Ulrike Neuhaus ,  Renate Braun

IPC: C10L1/18 ,  C10L1/22

CPC classification number: B01D17/047 ,  C10L1/143 ,  C10L1/1641 ,  C10L1/19 ,  C10L1/191 ,  C10L1/195 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387

Abstract: The present invention relates to the preparation of Ω-(dimethylisopropenylbenzylurethane) polyalkylene glycols with α-alkoxy or α-dihydroxy groups and to the use thereof as hydrolysis-stable macromonomers for the dispersion and crosslinking of polymers in which, A is C2-C4-alkylene, m is an integer from 5 to 900, and R is C1-C20-alkyl, C6-C18-aryl or a radical according to formula 2a, 2b, 2c, 3a, 3b or 3c which is bonded to the terminal oxygen atom of the alkoxy group (A-O) in formula 1 via the valence denoted by *, and in which A is not exclusively C3- or C4-alkylene.

Abstract translation: 本发明涉及具有α-烷氧基或α-二羟基的ω-（二甲基异丙烯基苄基氨基甲酸酯）聚亚烷基二醇的制备及其作为用于分散和交联聚合物的水解稳定性大分子单体的用途，其中A是C 2 -C 4 - 亚烷基，m为5至900的整数，R为C 1 -C 20烷基，C 6 -C 18芳基或与末端氧原子键合的根据式2a，2b，2c，3a，3b或3c的基团 的式1中的烷氧基（AO）经由以*表示的化合价，其中A不仅仅是C3-或C4-亚烷基。