Abstract:
A gas reactor system may be configured for facilitating chemical reactions of gases using shockwaves produced in a supersonic gaseous vortex. The system may include a gas source to provide a gas to a heater and/or a reactor. The reactor may be configured to facilitate chemical reactions of gases using shockwaves created in a supersonic gaseous vortex. The reactor may be arranged with a gas inlet to introduce a high-velocity steam of gas into a chamber of the reactor. The gas inlet may effectuate a vortex of supersonic circulating gas within the chamber. The vortex may rotate at supersonic speed about the longitudinal axis of the chamber. The system may be configured to store an output product of the reactor in a storage tank in fluid communication with the reactor.
Abstract:
A mixing reactor (1), the reactor comprising a body (2) having a first inlet (3), a second inlet (5) and an outlet (4), in which there is an inner passage (6) through the body (2) from the first inlet (3) at a first end (12) of the body (2) to the outlet (4) at a second end of the body (2) along a length of the body (2), the inner passage (6) having a side wall (17) along the length, and an outer passage (7) closer to a surface (14) of the body (2) than the inner passage (6), the outer passage (7) running from the second inlet (5) at the second end, travelling through the body (2) along the length and meeting the inner passage (6) at a junction (11) at the first end, the outer passage (7) joining the inner passage (6) through the side wall (17) at the junction (11). Such a mixing reactor can be used for producing particles such as nanoparticles or Metal-Organic frameworks. Furthermore, we disclose a cascade of such reactors and a method of using such reactors to mix fluids, typically but non-exclusively so as to produce such particles.
Abstract:
A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.
Abstract:
A process to reduce the acidity of acidic crude oils for preventing corrosion during processing of the crude oils, including transferring through pipe lines, tanker ships and tank vehicles. Crude oil having substantial amount of organic acid, in particular, naphthenic acid compounds is contacted with supercritical water and a catalyst for deacidification. A treated crude oil product has lower amounts of organic acid compounds than the original crude oil.
Abstract:
Systems and methods for reducing or eliminating corrosion of components of a reactor system, including a supercritical water gasification system, are described. Corrosion protection layers may be configured to provide a physical barrier between component surfaces and subcritical fluid present in one or more subcritical zones during operation of the reactor system. The corrosion protection layers may include glass and silicon carbide, and may be positioned within the one or more subcritical zones to prevent the subcritical fluid from contacting component surfaces susceptible to corrosion from corrosive ions present in the subcritical fluid.
Abstract:
Technologies are presented for reducing corrosion M supercritical water gasification through seeded sacrificial metal particles. The metal panicles may be seeded into one or more material input streams through high pressure injection. Once distributed in the SCWG reactor, the metal particles may corrode preferentially to the metal SCWG reactor walls and convert into metal oxides that precipitate out above the supercritical point of water. The precipitated metal oxides may then be collected downstream of the SCWG reactor to be reprocessed back into seed metal at a smelter. The seeded metal particles may complete a process material cycle with limited net additional waste.
Abstract:
An equipment assembly for preparing, harvesting and collecting particles is disclosed. The assembly comprises a tandem filter system with one or more high pressure filters, one or more low pressure filters and one or more collection vessel. Particles can be prepared, harvested and collected continuously, semi-continuously or in a batch-type operation. A tandem filter system and its method of use are also disclosed. Particles made with the assembly and according the instant methods are also disclosed. The assembly provides improved particle harvesting and collection over other systems and permits continuous particle formation, in particular by dispersion of a solute-containing process fluid within a supercritical anti-solvent.
Abstract:
An equipment assembly for preparing, harvesting and collecting particles is disclosed. The assembly comprises a tandem filter system with one or more high pressure filters, one or more low pressure filters and one or more collection vessel. Particles can be prepared, harvested and collected continuously, semi-continuously or in a batch-type operation. A tandem filter system and its method of use are also disclosed. Particles made with the assembly and according the instant methods are also disclosed. The assembly provides improved particle harvesting and collection over other systems and permits continuous particle formation, in particular by dispersion of a solute-containing process fluid within a supercritical anti-solvent.
Abstract:
A hydrothermal oxidation device for treatment of a material in a supercritical medium includes a main body, an internal tube installed inside the main body to form an annular zone along the main body, a stirring mechanism installed in an internal zone of the internal tube and actuated by a rotating shaft, a cooling mechanism to cool the treated material located in the internal zone of the internal tube, an inlet for water and oxidant mix, an effluents outlet, an inlet for material to be treated, located at one end of the main body, this inlet opening up into the internal tube. The oxidation device includes an inlet for a diluted effluent, located in the flange and connected to a preheating coil arranged along an internal wall of the main body and extending from its first end to its second end, the preheating coil opening up into the internal tube.
Abstract:
A method of hydrothermal processing of highly toxic substances, wastes and metal powders, comprises a batch processing cycle of at least following steps i. to viii: i. preparing a batch of highly toxic waste, substances and metal powders for processing; ii. applying precision dozing to the batch to obtain a mixture of the batch with water and at least one additional reagent in preset proportions; iii. feeding the mixture into a reactor; iv. spraying the mixture inside the reactor with a mechanical spray nozzle; v. supplying an additional oxidizing agent inside the reactor; vi. adjusting a temperature inside the reactor to above 374.2° C.; vii. adjusting a pressure inside the reactor to above 21.8 MPa, thereby driving the water into supercritical condition and initiating a supercritical hydrothermal oxidation process; and viii. keeping the mixture in the reactor for a preset amount of time, and at the same time. The method further comprises removing a produced steam and hydrogen mixture from the reactor via a steam-gas unit and droplet separator into a wastewater condenser unit and a gas drainage pipe, and venting suspended solids through a bottom part of the reactor into a solids collector unit. The method then provides the steps of repeating the batch processing cycle after it has terminated; and monitoring and controlling the temperature and pressure inside the reactor via an Automatic Process Control System (APCS) during all steps.