POLYCARBONATE POLYOL COMPOSITIONS AND METHODS
    145.
    发明申请
    POLYCARBONATE POLYOL COMPOSITIONS AND METHODS 有权
    聚碳酸酯多元醇组合物和方法

    公开(公告)号:US20170051106A1

    公开(公告)日:2017-02-23

    申请号:US15191901

    申请日:2016-06-24

    Applicant: Novomer, Inc.

    Inventor: Jay J. Farmer

    Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO2, wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.

    Abstract translation: 一方面,本公开内容涵盖用于CO 2和环氧化物共聚的聚合体系,其包括1)包含具有永久性配体组的金属配位化合物和至少一种作为聚合引发剂的配体的催化剂,和2)链转移剂 具有能够引发环氧化物和CO 2共聚的一个或多个位点,其中链转移剂含有一个或多个掩蔽的羟基。 在第二方面,本发明包括使用本发明聚合体系合成聚碳酸酯多元醇的方法。 在第三方面,本公开内容包括聚碳酸酯多元醇组合物,其特征在于聚合物链具有高百分比的-OH端基,高百分比的碳酸酯键,并且基本上所有具有羟基端基的聚碳酸酯链都没有嵌入链转移剂 。

    Catalyst components for the polymerization of olefins
    147.
    发明授权
    Catalyst components for the polymerization of olefins 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号:US09453088B2

    公开(公告)日:2016-09-27

    申请号:US12735278

    申请日:2008-12-22

    Abstract: Prepolymerized catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, having average particle size equal to or lower than 30 μm comprising a solid catalyst component comprising magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other one being selected from esters of aromatic mono or dicarboxylic acids, said solid catalyst component being prepolymerized with an olefin, having from 2 to 10 carbon atoms, to such an extent that the amount of the olefin prepolymer is equal to or lower than 50 g per g of solid catalyst component.

    Abstract translation: 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分,其中R是氢或具有1-12个碳原子的烃基,平均粒度等于或小于30μm,包括包含卤化镁的固体催化剂组分,钛化合物 具有至少一个Ti-卤键和至少两个电子给体化合物,其中一个选自1,3-二醚,另一个选自芳族单或二羧酸的酯,所述固体催化剂组分与烯烃预聚合 具有2至10个碳原子的烯烃预聚物的量等于或低于每克固体催化剂组分50克的程度。

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